期刊
AUSTRALIAN JOURNAL OF CHEMISTRY
卷 62, 期 11, 页码 1479-1483出版社
CSIRO PUBLISHING
DOI: 10.1071/CH09269
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资金
- Australian Research Council
High level ab initio molecular orbital calculations are used to study the addition-fragmentation equilibrium constants of S-S'-bis(methyl-2-propionate)-trithiocarbonate mediated polymerization of methyl acrylate in toluene at -30 degrees C. The results, which show strong solvent and chain length effects, are in good order of magnitude agreement with recent experimental results for a closely related system.
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