4.3 Article

Hyperspectral imaging spectroscopy: a promising method for the biogeochemical analysis of lake sediments

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SPIE-SOC PHOTO-OPTICAL INSTRUMENTATION ENGINEERS
DOI: 10.1117/1.JRS.9.096031

关键词

hyperspectral imaging; image acquisition/recording; reflectance; nondestructive testing; sedimentary pigments; bacteriopheophytin

资金

  1. Oeschger Centre
  2. Swiss [PSRP-086/2010]
  3. Swiss National Science Foundation [200020-134945/1]
  4. Swiss National Science Foundation (SNF) [200020_134945] Funding Source: Swiss National Science Foundation (SNF)

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We investigate the potential of hyperspectral imaging spectrometry for the analysis of fresh sediment cores. A sediment-core-scanning system equipped with a camera working in the visual to near-infrared range (400 to 1000 nm) is described and a general methodology for processing and calibrating spectral data from sediments is proposed. We present an application from organic sediments of Lake Jaczno, a freshwater lake with biochemical varves in northern Poland. The sedimentary pigment bacteriopheophytin a (BPhe a) is diagnostic for anoxia in lakes and, therefore, an important ecological indicator. Calibration of the spectral data (BPhe a absorption similar to 800 to 900 nm) to absolute BPhe a concentrations, as measured by high-performance-liquid-chromatography, reveals that sedimentary BPhe a concentrations can be estimated from spectral data with a model uncertainty of similar to 10%. Based on this calibration model, we use the hyperspectral data from the sediment core to produce high-resolution intensity maps and time series of relative BPhe a concentrations (similar to 10 to 20 data points per year, pixel resolution 70 x 70 mu m(2)). We conclude that hyperspectral imaging is a very cost-and time-efficient method for the analysis of lake sediments and provides insight into the spatiotemporal structures of biogeochemical species at a degree of detail that is not possible with wet chemical analyses. (C) 2015 Society of Photo-Optical Instrumentation Engineers (SPIE)

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