Investigation of the use of filter packs to measure the sulphur isotopic composition of volcanic sulphur dioxide and the sulphur and oxygen isotopic composition of volcanic sulphate aerosol

Filter packs have been used to collect sulphur and oxygen from air for isotope analysis from many areas of the world. Here we discuss their use to determine the sulphur isotope systematics of SO2 and the sulphur and oxygen systematics of sulphate particles from volcanic vents. Our field data suggest that fractionation of sulphur isotopes occurs during the collection of SO2 from concentrated volcanic gas plumes on alkali-impregnated filter papers. The collection of volcanogenic HCl on the same filters may play a role in this fractionation. Comparison with previous studies, which sampled areas of cleaner atmosphere, suggests that isotopic fractionation only becomes significant where elevated filter loadings occur (e.g., when sampling gas streams with SO2 concentrations greater than similar to 1 mu mol m(-3)), although this requires further investigation. Previous studies also suggest that for volcanic sulphate particle samples collected at the same time, oxygen isotopes are fractionated while sulphur isotopes are not. Minimising the filter loading reduces these effects, but there is a trade-off with the amount of SO2 or SO42- required for isotopic measurements. Despite the convenience of the filter pack technique these fractionation effects limit the use of filter packs for determining delta S-34 for SO2 in volcanic gases and delta O-18 and delta O-17 for the sulphate in volcanic particles, and they will certainly not be useful for determining small variations in the source isotopic signature of the sulphur in the SO2 or the oxygen in the SO42- being measured. This highlights the importance of collecting SO2 quantitatively for isotopic analysis. These effects may also have implications if using similar methods to collect SO2 in other environments, especially where concentrations are high. (C) 2008 Elsevier Ltd. All rights reserved.