4.6 Article

The ageing and de-ageing behaviour of (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 lead-free piezoelectric ceramics

期刊

JOURNAL OF APPLIED PHYSICS
卷 118, 期 12, 页码 -

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AMER INST PHYSICS
DOI: 10.1063/1.4931892

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资金

  1. Australian Research Council [DP0988182, DE120102644]
  2. University of New South Wales
  3. United States National Science Foundation [DMR 0805022]

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Ageing behaviour usually occurs in acceptor-doped piezoelectric materials (e.g., hard lead zirconate titanate) and exhibits the development of a pinched or shifted hysteresis loop over time. Although no pinched hysteresis loop was observed for lead-free (Ba0.85Ca0.15)(Ti0.9Zr0.1)O-3 material, this study showed that the piezoelectric properties change over time in the poled state. The shift of the hysteresis loop along the electric field axis and the development of asymmetry in strain and permittivity hysteresis loop were observed during the ageing process. The origin of this ageing behaviour is proposed to be local defect dipoles and the migration of the charged defects to the grain boundaries. The reorientation of the defect dipole contributes to a fast but unstable ageing mechanism in this material while the migration of the charged defects contributes to a slow but more stable mechanism. (C) 2015 AIP Publishing LLC.

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