期刊
ASIAN JOURNAL OF CHEMISTRY
卷 26, 期 2, 页码 407-410出版社
ASIAN JOURNAL OF CHEMISTRY
DOI: 10.14233/ajchem.2014.15416
关键词
Selective catalytic reduction; CeO2; NO; NH3
资金
- Scientific Problem Tackling Program of Science and Technology Commission of Shanghai Municipality [11dz2281700, 10dz1201401, 10dz1201402]
- Fifth Key Subject of Shanghai Education Commission [J51034]
- Innovation Program of Shanghai Municipal Education Commission [10YZ155]
- Choose and Cultivation of Excellent Young Teachers Program of Shanghai Municipal Education Commission [sd109008]
- Talent Induction Program of Shanghai University of Electric Power [K-2009-03]
Ceria was investigated as a catalyst for selective catalytic reduction of NO by NH3. The ceria catalysts were prepared by citric acid method with different calcination temperature. Experimental results showed that the selective catalytic reduction activity of ceria catalyst decreases with increasing calcination temperature within the reaction temperature range of 150-350 degrees C. As can be seen from the characterization I results of BET, XRD, temperature programmed reduction, total programmed desorption and XPS, the best selective catalytic reduction performance of ceria catalyst calculated at 350 degrees C may be resulted from its large surface area, good redox ability, strong NH3 adsorption capacity and high concentration of active oxygen species on the surface of this catalyst.
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