期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 646, 期 -, 页码 990-997出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2015.05.227
关键词
Ni(OH)(2)/CNTs/Ni(OH)(2) nanocomposite; Lamellar-crossing-nanostructure; Supercapacitor; Pseudocapacitor electrode material
资金
- National Natural Science Foundation of China [21171130, 51271132, 51072134, 91122025]
- 973 Project of China [2011CB932404]
Ni(OH)(2)/CNTs/Ni(OH)(2) lamellar-crossing-nanostructure with a single lamellar spacing of similar to 5 nm was effectively constructed through two-phase-interface reaction process followed by the CNTs crossed among the lamellar-nanostructured Ni(OH)(2). The resultant nanocomposite can offer large active surface areas and short diffusion paths for electrons and ions, and is investigated as a potential pseudocapacitor electrode material for electrochemical energy storage applications. Electrochemical data demonstrate that the as-prepared nanocomposite exhibits a high specific capacitance of similar to 1600 F g(-1) at the scan rate of 1 mV s(-1) in 6 M KOH solution at normal pressure and temperature, which is great higher than Ni(OH)(2) (similar to 1200 F g(-1)). Furthermore, Ni(OH)(2)/CNTs/Ni(OH)(2) nanocomposite shows a higher energy density (similar to 125 Wh kg(-1), 2 A g(-1)) and has a slightly decrease of 5% in specific capacitance after 1000 continuous charge/discharge cycles. (C) 2015 Elsevier B.V. All rights reserved.
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