4.7 Article

The local distortion and electronic behavior in Mn doped BiFeO3

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 633, 期 -, 页码 216-219

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2015.02.003

关键词

BiFeO3; XANES; Jahn-Teller effect; Magnetism

资金

  1. National Natural Science Foundation of China (NSFC) [11174083]
  2. Fundamental Research Funds for the Central Universities, SCUT [2014ZZ0069]

向作者/读者索取更多资源

Mn substitution provides perfect perturbation on the local structure and electronic behavior of BiFeO3. The crystal structure of BiFe1-xMnxO3 (0 <= x <= 0.3) changes from rhombohedral R3c to orthorhombic Pbnm via a biphasic region with increasing x. It is found that Mn doping leads to the depolarization of the Bi-O configuration, and the Jahn-Teller distortion of Fe/MnO6 octahedra. An enhancement of remanent magnetization of BiFe1-xMnxO3 is observed. (C) 2015 Elsevier B.V. All rights reserved.

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