Article
Chemistry, Analytical
Jiahong Tang, Hao Wang, Xiaoxia Wang, Changsheng Xie, Dawen Zeng
Summary: Different sizes of alpha-Fe2O3 hollow cubic structures were prepared by calcination of Prussian blue templates, with the transformation mechanism investigated. The gas-sensing performance of pure phase alpha-Fe2O3 hollow cubes to H2S gas demonstrated high sensitivity. Through characterizations, it was found that the optimized sensitivity of 800 nm alpha-Fe2O3 cube was influenced by specific surface area and oxygen vacancy density.
SENSORS AND ACTUATORS B-CHEMICAL
(2022)
Article
Chemistry, Physical
Yury Turkulets, Ilan Shalish
Summary: The previous exponential decay of surface photovoltage needs further accurate modeling, the new model can expand the applicability of Kelvin probe method, solving the issue that was previously restricted to slow-responding semiconductors.
SURFACES AND INTERFACES
(2021)
Article
Engineering, Chemical
Marin Tadic, Matjaz Panjan, Yoann Lalatone, Irena Milosevic, Biljana Vucetic Tadic, Jelena Lazovic
Summary: This study investigates the synthesis, phase evolution, crystal structure, magnetic properties, and potential biomedical applications of QUAIPH and hematite nanostructures synthesized by annealing beta-FeOOH nanorods. The results show the relationship between annealing temperature, crystal structure, morphology, and magnetic properties of the synthesized materials, as well as their low cytotoxicity and high MRI relaxivity.
ADVANCED POWDER TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Cuihua Zhao, Baishi Li, Xi Zhou, Jianhua Chen, Hongqun Tang
Summary: The study shows that the crystal structure of alpha-Fe2O3 changes after Ag and S doping, leading to a slight shift of the optical absorption peak towards shorter wavelengths. Additionally, optical absorption in the visible range is significantly enhanced after Ag and S doping.
Article
Materials Science, Multidisciplinary
Farshid Khosravi Maleki, Mahyuddin K. M. Nasution, Mustafa Sabri Gok, Vahid Arab Maleki
Summary: This study investigated the effects of different weight fractions and microparticle sizes on the mechanical properties of the composite material, showing that increasing weight fraction and particle size improved Young's modulus but reduced tensile strength. It was also found that larger microparticles had a smaller effect on the mechanical properties of the composite material.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Chemistry, Analytical
Shuaijun Hao, Hong Wang, Ruisong Yang, Di Liu, Jiawei Wan, Xiaohua Liu, Qiang Zhang, Xinkuan Chen
Summary: Dandelion-like SiO2@SnO2/alpha-Fe2O3 hollow microspheres were successfully synthesized with mesoporous structure and catalytic effect, showing excellent sensitivity to acetone gas.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Chemistry, Analytical
Wenjing Pan, Yong Zhang, Sujing Yu, Xiaohua Liu, Dongzhi Zhang
Summary: The alpha-Fe2O3/MoSe2 composite fabricated via a simple hydrothermal route shows high response to H2S gas sensing, with a faster response/recovery rate, outstanding repeatability, and anti-humidity interference at room temperature, as well as excellent selectivity for H2S compared to other potentially interfering gases. This improved performance is attributed to the increased active sites and specific surface area, as well as the formation of n-n heterojunctions at the interface between alpha-Fe2O3 hollow nanospheres and MoSe2 nanoflowers.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Chemistry, Analytical
Ping Wang, Lili Sui, Haixia Yu, Xianfa Zhang, Xiaoli Cheng, Shan Gao, Hui Zhao, Lihua Huo, Yingming Xu, Hongyuan Wu
Summary: Monodisperse alpha-Fe2O3 hollow ellipsoids were successfully fabricated with the addition of [C(12)mim][PF6] (IL) using a simple one-pot method, revealing the significant influence of calcination temperature and IL content on the structures. Gas sensors based on IL-loaded alpha-Fe2O3 hollow ellipsoids exhibited high response, sensitivity, and low detection limit to n-butanol, showing their potential as promising candidates for highly sensitive gas sensors.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Polymer Science
Shaoshuai Zhang, Peng Deng, Lulu Yu, Yun Ni, Chen Ling, Ziye Zhu, Ruijiang Liu
Summary: A simple process for the fabrication of hollow-structure supermagnetic alpha-Fe2O3/Fe3O4 heterogeneous nanospindles was introduced using beta-FeOOH as precursors fabricated by the hydrolysis method. The effects of Fe3+ concentration, hydrolysis conditions, reducing agent, and calcination conditions on the morphology, phase composition, and magnetic property of the nanospindles were investigated. The prepared hollow-structure alpha-Fe2O3/Fe3O4 heterogeneous nanospindles with controlled magnetic properties are a type of very promising material.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2022)
Article
Materials Science, Ceramics
Manal A. Mahdy, Sayed H. Kenawy, Esmat M. A. Hamzawy, Gehan T. El-Bassyouni, I. K. El Zawawi
Summary: In this study, the influence of adding different molar ratios of silicon carbide to wollastonite/Fe2O3 composites was investigated. The X-ray diffraction and high resolution transmission electron microscope were utilized to study the crystal structure and properties of the composites, revealing the formation of nanocomposites with improved magnetic properties and promising applications.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Erhuan Zhang, Qianhong Zhu, Junheng Huang, Jia Liu, Guoqiang Tan, Chengjun Sun, Tao Li, Shan Liu, Yuemei Li, Hongzhi Wang, Xiaodong Wan, Zhenhai Wen, Fengtao Fan, Jiatao Zhang, Katsuhiko Ariga
Summary: The study successfully constructed CdS@ZnIn2S4 hierarchical hollow photocatalysts with a highly efficient direct Z-scheme system, enabling the conversion of pure water into H2 and H2O2. This work provides an effective approach for building efficient sulfide-only photocatalysts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Nanoscience & Nanotechnology
Gaojie Li, Zhiheng Ma, Qingmin Hu, Dan Zhang, Yu Fan, Xiaohong Wang, Xiangfeng Chu, Jiaqiang Xu
Summary: Bimetal decoration is an effective strategy to increase the sensitivity of metal oxide semiconductor sensors, and PdPt/α-Fe2O3 shows high catalytic activity towards TEA, demonstrating superior sensing performance.
ACS APPLIED NANO MATERIALS
(2021)
Article
Engineering, Chemical
Md Shahadat Hossain, Takeshi Furusawa, Masahide Sato
Summary: A simple and cost-effective hydrothermal technique was used to fabricate hollow α-Fe2O3 microspheres, which were characterized by various methods. The microspheres exhibited a shell composed of aggregated α-Fe2O3 nanoparticles with a hollow interior. This material shows potential applications in drug delivery, gas sensing, and lithium storage.
ADVANCED POWDER TECHNOLOGY
(2022)
Article
Chemistry, Physical
Leilei Wang, Haihang Cui, Lei Wang, Xu Han, Xudong Wang
Summary: The translation discusses the challenges between high performance of photocatalysis and difficulty in recycling micro/nano photocatalysts, proposing a method using visible-light photocatalysts ZnIn2S4 grafted on floating hollow glass microspheres to address this issue. By employing different pretreatment methods on the hollow glass microspheres, the structure pattern, morphology, and photocatalytic activities of the composite microspheres were altered. The study also presents the growth mechanism of the formation process of the composite microspheres, showing enhanced degradation efficiency of Rhodamine B under visible light irradiation compared to ZIS powder, indicating promising potential for efficient recycling of micro/nano photocatalysts.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Materials Science, Ceramics
Qianxing Huang, Taoyong Liu, Xuefeng Shen, Xiuying Li, Anxian Lu, Yi Gu
Summary: In this study, Fe2O3-doped magnesium aluminosilicate-based glasses were prepared by the traditional melt quenching method, and the effects of Fe2O3 doping on the structure and properties of the glasses were analyzed. The results indicate that Fe2O3 doping disrupts the glass network structure, reduces the thermal stability, and alters the optical properties of the glasses.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2021)
Article
Environmental Sciences
Guoqiang Gan, Shiying Fan, Xinyong Li, Zhongshen Zhang, Zhengping Hao
Summary: Volatile organic compounds (VOCs) are significant pollutants in the environment due to their toxicity, volatility, and poor degradability. Controlling their emission is urgent, and efficient technologies for removal and recovery are of great importance. Adsorption and membrane separation processes have been extensively studied and favored for their industrial prospects.
JOURNAL OF ENVIRONMENTAL SCIENCES
(2023)
Article
Engineering, Chemical
Shuang Qiu, Yonghou Xiao, Haoran Wu, Shengnan Lu, Qidong Zhao, Gaohong He
Summary: NH3 selective catalytic reduction (SCR) is a promising technique for reducing nitrogen oxides from diesel vehicle exhausts. In this study, bimetallic CeCu-SAPO-34 molecular sieves were synthesized and showed improved catalytic activity at low temperatures. The introduction of cerium species enhanced the catalyst's stability and promoted the NH3-SCR reaction through the formation of weak Bronsted acid centers and the synergy between CuO grains and isolated Cu2+. This work provides a facile synthesis method for high-efficiency SCR denitration catalysts.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Nanoscience & Nanotechnology
Guoqiang Gan, Fengquan Xu, Xinyong Li, Shiying Fan, Chunpeng Bai, Qidong Zhao, Moses O. Tade, Shaomin Liu, Wenjun Zhang
Summary: The influence of crystal phase on the electrocatalytic performance and active sites of CuFe2O4 spinel for the electrochemical dechlorination of 1,2-dichloroethane is studied. A higher activity and ethylene selectivity are observed for the cubic phase compared to the tetragonal phase, indicating the significant enhancement of electrocatalytic performance by the cubic crystal structure. The octahedral Fe atom on the surface of cubic CuFe2O4(311) is identified as the active site responsible for ethylene production with an energy barrier of 0.40 eV. This work highlights the importance of crystal phase engineering for optimizing electrocatalytic performance and provides an efficient strategy for the development of advanced electrocatalysts.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Energy & Fuels
Yushan Li, Xu Liu, Hao Zhou, Qidong Zhao, Yonghou Xiao
Summary: In this study, a novel integrated process for the treatment of polymer-flooding sewage is proposed, which includes air flotation-(anaerobic-anoxic-aerobic)-ozone catalytic oxidation-dual media filtration-multimedia filtration. The process effectively addresses the low pollutant removal efficiency caused by the high viscosity of polymer and achieves efficient removal of suspended solids, oil, and other biochemical indexes. Moreover, more than 70% of the polymer is retained in the effluent. This research provides an efficient approach for the reuse of polymer-flooding sewage.
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
(2023)
Article
Energy & Fuels
You Zhao, Wenkai Zhao, Yonghou Xiao, Qidong Zhao, Chengbin Li, Xiaoying Dong, Shengnan Lu
Summary: A novel super microporous silica material (SMS) with a bimodal micro-mesoporous pore size distribution has been successfully synthesized. The SMS demonstrates improved adsorption desulfurization performance by reducing diffusion resistance and enhancing shape selectivity compared to traditional microporous and mesoporous silicon oxide materials. The SMS exhibits high desulfurization capacity, easy regeneration, and satisfactory performance for practical applications.
Article
Engineering, Chemical
Zhiyuan Liu, Shiying Fan, Xinyong Li, Zhaodong Niu, Jing Wang, Chunpeng Bai, Jun Duan, Moses O. Tade, Shaomin Liu
Summary: We demonstrate a composite photocatalyst for nitric oxide conversion with a Cu-Fe alloy, graphitic carbon nitride (g-C3N4), and ZnIn2S4. The superior photocatalytic performance of 6.45-fold that of g-C3N4 was confirmed. The delay effect on charge recombination was observed through time-resolved photoluminescence, and heterojunction establishment was attributed to the hole-trapping ability of ZnIn2S4. The combined effects of the Cu-Fe alloy were confirmed by NO-specific adsorption and conversion experiments, and the active species involved were examined via electron spin resonance. Density functional theory calculations revealed the molecular mechanisms of photocatalytic conversion of NO to NO3-. Therefore, g-C3N4|ZnIn2S4|CuFe has potential for sustainable and efficient pollutant conversion.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Engineering, Chemical
Shengnan Lu, Yonghou Xiao, Qidong Zhao, Wenkai Zhao, Gaohong He
Summary: Deep desulfurization of fuel is an important research topic in response to increasing environmental protection requirements. This study proposes a strategy to construct defective CPO-27-Ni with a micro-mesoporous structure using N, N-dimethyloctadecylamine (DMA18) as a template, aiming to improve diffusion efficiency. The introduction of mesopores effectively enhances the adsorption desulfurization performance of CPO-27-Ni, providing valuable insights for preparing high-efficiency desulfurization adsorbents.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Yanan Zhu, Yuanfu Deng, Guohua Chen
Summary: In this study, heteroatom-doped carbon nanosheets were successfully synthesized using crosslinked triazine frameworks and g-C3N4 nanosheets as a template. The nanosheets exhibited high crinkling and interconnectivity, along with a large surface area (1060 m(2) g(-1)) and pore volume (2.14 cm(3) g(-1)), with highly dispersed N, O and S. When coated on commercial Celgard separators, the modified batteries showed low self-discharge and improved rate performance, even at 4 C. Excellent cycling performances were achieved at different rates, with an initial discharge capacity of 1240 mA h g(-1) and a capacity decay of only 0.059% per cycle for over 1000 cycles at 0.5 C.
MATERIALS CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Physical
Zhaodong Niu, Shiying Fan, Xinyong Li, Jun Duan, Aicheng Chen
Summary: In this study, a new catalyst was developed for efficient wastewater treatment and high-value ammonia generation. The catalyst exhibited high Faradaic efficiency and yield at specific potentials, and the reaction was promoted by the interface effect. The experimental results and theoretical calculations provided insights into the catalytic mechanism and product formation.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Physical
Zhiyuan Liu, Shiying Fan, Xinyong Li, Zhaodong Niu, Jing Wang, Chunpeng Bai, Jun Duan, Moses O. Tade, Shaomin Liu
Summary: In this paper, single atom Cu/Ta3N5/CdIn2S4 S-scheme hierarchical polyhedrons (SACu/TN/CIS SHPs) were successfully synthesized and their photocatalytic activity improvement was investigated. The synergistic effect of SACu and S-scheme was confirmed to exhibit excellent charge separation and reduction of energy barriers during ammonium production reaction. The NH3 production rate of SACu/TN/CIS SHPs under light conditions was remarkably 43.6 times higher than that of Ta3N5. This study not only proposes an efficient catalyst under visible light, but also provides an advantageous solution for photocatalytic nitrate reduction.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Review
Chemistry, Multidisciplinary
Cong Lin, Jianyuan Li, Zu-Wei Yin, Weiyuan Huang, Qinghe Zhao, Qingsong Weng, Qiang Liu, Junliang Sun, Guohua Chen, Feng Pan
Summary: This review focuses on the long-term research of the structural understanding of LiCoO2 cathode, uncovering various structural issues and stabilization strategies at different scales. It emphasizes the importance of in-depth knowledge of LiCoO2 structure for future stabilization efforts.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Penglei Wang, Shiying Fan, Xinyong Li, Jun Duan, Dongke Zhang
Summary: The impact of the piezoelectric effect on the photocatalytic production of hydrogen peroxide (H2O2) over graphitic carbon nitride (CN) was investigated by modulating its molecular structure. The results showed that the photocatalytic activity of CN, CN-P, CN-OF was enhanced by approximately 1.40, 1.46, and 1.51 times due to the piezoelectric effect, respectively, while CN-CA exhibited a 6-fold decrease in activity. Various techniques were employed to explore the active sites, piezoelectric polarization, and charge separation, revealing that the piezoelectric effect's influence on photocatalytic H2O2 production over CN is determined by multiple factors.
Article
Nanoscience & Nanotechnology
Yu Qin, Shiying Fan, Jinsuo Gao, Moses O. Tade, Shaomin Liu, Xinyong Li
Summary: Cu-doped CoMn2O4 catalysts showed excellent catalytic performance in NO reduction by CO, with Cu0.3Co0.7Mn2O4 achieving 100% NO conversion and 80% N2 selectivity at 250 degrees C. Structural analysis revealed that the introduced Cu replaces some Co in tetrahedral coordination, resulting in a strong synergistic effect between different metals.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Environmental Sciences
Jinyun Luo, Jincheng Mu, Xinyong Li, Baojun Liu
Summary: With the development of metallurgy, chemical manufacturing, and mining, lead pollution in water, especially from battery industries, has become a serious environmental problem. In this study, a highly efficient removal of Pb2+ from wastewater was achieved using MoO2@N-doped hollow carbon sphere (MoO2@ NHCS) anodes in a capacitive deionization (CDI) process. The MoO2@NHCS electrodes exhibited a high adsorption capacity of 202.14 mg/g for Pb2+ in a 50 ppm solution (pH = 6 and U = 1.2 V). Additionally, the electrodes showed selectivity towards Pb2+ even in the presence of Na+ and other heavy metal ions. The selective removal was attributed to the transformation of octahedral MoO2 into tetrahedral [MoO4]2-, which could effectively trap Pb2+ to form PbMoO4.
Article
Chemistry, Physical
Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou
Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.
APPLIED SURFACE SCIENCE
(2024)
Review
Chemistry, Physical
George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira
Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu
Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata
Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu
Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng
Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong
Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)