期刊
APPLIED SURFACE SCIENCE
卷 258, 期 15, 页码 5733-5738出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2012.02.079
关键词
Semiconductors; Nanostructures; Optical properties; Electrical properties; Spray pyrolysis
Copper sulphide (CuS) thin films have been deposited on glass substrates by spray pyrolysis method using an aqueous solutions of copper (II) acetate and thiourea with different Cu to S molar ratios (0.33 and 0.43) at various substrate temperatures of 260, 285 and 310 degrees C. The structural, optical and electrical characterizations have been carried out using XRD, UV-Vis. transmittance/reflectance, PL spectra and Hall effect measurements. These characterizations indicated the formation of a CuS single phase (covellite) with polycrystalline nature with preferred orientation along (1 0 2) plane, except one with amorphous nature. Optical studies showed that the deposited layers have a relatively high absorption coefficient (5 x 10(4) to 1 x 10(5) cm(-1)) in the visible range, with an effective optical band gap of similar to 2.4-2.6 eV. The Hall effect data showed that all the grown samples have a degenerate p-type conductivity with a hole concentration of similar to 1.8 x 10(20) to 1.7 x 10(21) cm(-3). (C) 2012 Elsevier B.V. All rights reserved.
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