期刊
APPLIED SURFACE SCIENCE
卷 258, 期 22, 页码 8448-8454出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2012.03.012
关键词
Carbon nanotubes; Graphite; Vacuum ultraviolet photochemistry; Surface functionalization; Amino groups; Hydroxyl; Derivatization
类别
资金
- Adolf Martens Fellowship Program of BAM
- Fonds Quebecois de la Recherche sur la Nature et les Technologies (FQRNT)
- BESSY II synchrotron radiation facility
Graphite and multiwall carbon nanotube surfaces were functionalized by vacuum-ultraviolet induced photochemistry in NH3 or O-2, in order to introduce amino-(NH2) or hydroxyl (OH) functionalities, respectively. Modified surfaces were characterized by X-ray photoelectron spectroscopy (XPS), which showed significant incorporation of nitrogen (N) and oxygen (O) at the materials' surface. While high-resolution XP spectra did not yield much specific information about the incorporated functional groups, chemical derivatization with 4-trifluoromethyl benzaldehyde and trifluoroacetic anhydride accompanied by XPS enabled quantification of NH2 and OH groups, respectively. Using near edge X-ray absorption fine structure spectroscopy, we assessed the conservation of the aromatic structure following functionalization treatments. (C) 2012 Elsevier B. V. All rights reserved.
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