4.7 Article

Superhydrophobicity of silica nanoparticles modified with polystyrene

期刊

APPLIED SURFACE SCIENCE
卷 257, 期 6, 页码 2308-2312

出版社

ELSEVIER
DOI: 10.1016/j.apsusc.2010.09.094

关键词

Superhydrophobic surface; CB relation; Contact angle; Polystyrene; Silica nanoparticles

资金

  1. Youth Scientist Fund of Shandong Province [2007BS04007]
  2. Doctoral Startup Foundation of Shandong Institute of Light Industry, National Natural Science Foundation of China [50772059]
  3. foundation for the author of National Excellent Doctoral Dissertation for PR China [200539]

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Polystyrene/silica nanoparticles were prepared by radical polymerization of silica nanoparticles possessing vinyl groups and styrene with benzoyl peroxide. The resulting vinyl silica nanoparticles, polystyrene/silica nanoparticles were characterized by means of Fourier transformation infrared spectroscopy, scanning electron microscopy and UV-vis absorption spectroscopy. The results indicated that polystyrene had been successfully grafted onto vinyl silica nanoparticles via covalent bond. The morphological structure of polystyrene/silica nanoparticles film, investigated by scanning electron microscopy, showed a characteristic rough structure. Surface wetting properties of the polystyrene/silica nanoparticles film were evaluated by measuring water contact angle and the sliding angle using a contact angle goniometer, which were measured to be 159 degrees and 2 degrees, respectively. The excellent superhydrophobic property enlarges potential applications of the superhydrophobic surfaces. (C) 2010 Elsevier B.V. All rights reserved.

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