4.7 Article

N-doped TiO2 photo-catalyst for the degradation of 1,2-dichloroethane under fluorescent light

期刊

APPLIED SURFACE SCIENCE
卷 258, 期 4, 页码 1581-1586

出版社

ELSEVIER
DOI: 10.1016/j.apsusc.2011.09.138

关键词

Photo-degradation; Titanium dioxide; Nitrogen-doped TiO2; Visible-light; 1,2-dichloroethane

资金

  1. National Science Council, Republic of China [NSC 96-2211-E-006-028]

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The photo-catalytic degradation of 1,2-dichloroethane (1, 2-DCE) using nitrogen-doped TiO2 photocatalysts under fluorescent light irradiation was investigated. Highly pure TiO2 and nitrogen-doped TiO2 were prepared by a sol-gel method and characterized by thermo-gravimetric/differential-thermal analysis (TG/DTA), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared (FTIR) spectroscopy. The results indicate that the photo-catalysts were mainly nano-size with an anatase-phase structure. The degradation reaction of 1,2-DCE was operated under visible-light irradiation, and the photo-catalytic oxidation was conducted in a batch photo-reactor with various nitrogen doping ratios (N/Ti = 0-25 mol%). The relative humidity (RH) was controlled at 0-20% and the oxygen concentration was controlled at 0-21%. The photo-degradation with nitrogen-doped TiO2 showed superior photo-catalytic activity compared to that for pure TiO2. TiO2 doped with 15 mol% nitrogen exhibited the best photo-catalytic efficiency under the tested conditions. The products from the 1,2-DCE photocatalytic oxidation were CO2 and water; the by-products included dichloromethane, methyl chloride, ethyl chloride, carbon monoxide, and hydrogen chloride. The reaction pathway of 1,2-DCE indicates that oxygen molecules are the major factor that causes the degradation of 1,2-DCE in the gas phase. (C) 2011 Elsevier B.V. All rights reserved.

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