4.6 Article

Microstructure of bilayer manganite PrCa2Mn2O7 showing charge/orbital ordering

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APPLIED PHYSICS LETTERS
卷 102, 期 21, 页码 -

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AMER INST PHYSICS
DOI: 10.1063/1.4807758

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  1. European Research Council under the Seventh Framework Program (FP7), ERC [246791-COUNTATOMS]

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The microstructure of the charge/orbital ordering Ruddleden-Popper phase PrCa2Mn2O7 was studied by transmission electron microscopy along both the [001] and the [110] orientation. Three coexisting charge/orbital ordering phases CO1, CO2, and CO3 were observed along the [001] orientation at room temperature. Different from the one-dimensional modulation in the CO1 and CO2 phase, the CO3 phase is characterized by two sets of mutually perpendicular structural modulations. From [110] high angle annular dark field-scanning transmission electron microscopy, we found that the Pr atoms locate in-between the bilayer MnO6 octahedra, which is different from the previous reports. (C) 2013 AIP Publishing LLC.

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