Article
Nanoscience & Nanotechnology
M. Perzanowski, O. Polit, J. Chojenka, W. Sas, A. Zarzycki, M. Marszalek
Summary: In this study, the effect of laser interference patterning on the magnetic properties of Pd/CoO/Co/Pd multilayers was investigated. It was found that laser treatment caused magnetic softening of the structure edges while the centers exhibited the exchange bias effect. The study focused on the shape and configurational magnetic anisotropies induced by patterning and showed that the magnetic properties varied depending on the angle of the external magnetic field.
Article
Nanoscience & Nanotechnology
Jeotikanta Mohapatra, Meiying Xing, Rui Wu, Jinbo Yang, Ping Liu
Summary: This report investigates the exchange-bias effect of Co/CoO core/shell nanoparticles with an amorphous CoO shell. The spin-glass state in the CoO shell at low temperatures creates a unidirectional anisotropy in the Co core, resulting in a large exchange bias field of up to 3.6 kOe. By improving the crystallinity of the CoO shell, the spin-glass ordering is suppressed, leading to a significantly lower exchange-bias field (2.2 kOe) and a prominent training effect due to multiple easy axes in the multi-crystalline CoO shell. Theoretical studies confirm the significant impact of the emerging spin-glass state on the exchange bias of the system. These findings offer a new approach for manipulating and fine-tuning exchange bias effects in nanoscale systems for spintronics applications.
SCRIPTA MATERIALIA
(2023)
Article
Biochemistry & Molecular Biology
Venkatesha Narayanaswamy, Jayalakshmi Jagal, Hafsa Khurshid, Imaddin A. A. Al-Omari, Mohamed Haider, Alexander S. S. Kamzin, Ihab M. M. Obaidat, Bashar Issa
Summary: Magnetically soft-soft MnFe2O4-Fe3O4 core-shell nanoparticles were synthesized and their magnetic and thermal properties were studied. The results showed that the shell thickness had no significant effect on the magnetic properties, while the interface spin freezing between the shell and core played an important role. These nanoparticles have potential applications in cancer treatment.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Multidisciplinary
Suchandra Goswami, Pushpendra Gupta, Sagarika Nayak, Subhankar Bedanta, Oscar Iglesias, Manashi Chakraborty, Debajyoti De
Summary: This study reports the method of controlling the exchange bias effect by manipulating the interparticle interactions in nanocrystalline core/shell structures. The results indicate that the interparticle interactions have a significant impact on the magnetic properties, with a more pronounced collective behavior observed in concentrated assemblies. This finding contributes to a better understanding of the magnetic behavior in nanoparticle systems.
Article
Materials Science, Multidisciplinary
A. L. Danilyuk, E. S. Nazarenka, S. A. Vorobyova, J. A. Fedotova, S. L. Prischepa
Summary: This study investigates the magnetic behavior of cobalt/cobalt oxide nanoparticles deposited onto a copper surface at liquid helium temperature. It reveals the long-range correlation and oscillating character of magnetic anisotropy axes, suggesting the importance of the interplay between exchange bias, random anisotropy, indirect exchange coupling via conducting electrons, and magnetic dipole interaction.
CURRENT APPLIED PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Venkatesha Narayanaswamy, Imaddin A. Al-Omari, Aleksandr S. Kamzin, Bashar Issa, Ihab M. Obaidat
Summary: Magnetically hard-soft core-shell ferrite nanoparticles were synthesized using an organometallic decomposition method. The magnetic properties and magnetic heating efficiency for magnetic hyperthermia applications were investigated, and it was found that the core-shell structure exhibited superior performance.
Article
Chemistry, Physical
Mario Avila-Gutierrez, Arthur Moisset, Anh-Tu Ngo, Salvatore Costanzo, Guilhem Simon, Philippe Colomban, Marc Petit, Christophe Petit, Isabelle Lisiecki
Summary: This study compares the magnetic properties of core/shell nanoparticles made of cobalt (Co) and cobalt oxide (CoO), and analyzes the variations in their crystalline structure. It is found that the crystalline structure of the core/shell nanoparticle has a significant impact on interfacial magnetic coupling, resulting in exchange bias in Cohcp/CoO particles. The measured exchange bias field (655 mT) exceeds previous reports for similar nanoparticles, and this enhancement is attributed to the high-quality Co/CoO interface, the disparate magnetic anisotropy between the core (Co hcp) and the shell (CoO), and the optimal ratio between the core and shell.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Materials Science, Multidisciplinary
C. R. D. de Freitas, R. B. da Silva, J. M. Soares, P. R. T. Ribeiro, F. L. A. Machado, J. M. Sasaki
Summary: In this work, the structure and magnetic properties of bimagnetic core-shell CoO@MnFe2O4 nanoparticles were studied. It was found that the coercivity and the exchange-bias effect were enhanced at low temperatures, and these phenomena were explained by a model based on the exchange-coupling of the magnetic moments at the core-shell interface.
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Eduard Monaico, Vadim Morari, Veaceslav V. Ursaki, Kornelius Nielsch, Ion M. Tiginyanu
Summary: This study reports the preparation of GaAs nanowire templates using cost-effective electrochemical etching of (001) and (111)B GaAs substrates, and the fabrication of core-shell GaAs-Fe nanowire arrays by galvanostatic Fe deposition. The fabricated arrays were characterized and their magnetic properties were analyzed.
Article
Physics, Applied
Artem Talantsev, Maxim Bakhmetiev, Roman Morgunov
Summary: The magnetization reversal behavior in NiFe/IrMn exchange-biased thin films was investigated under thermal cycling, and the thermal hysteresis of magnetization and polarity changes were observed. This effect occurs when the thermally induced variations in exchange bias exceed the variations in coercivity.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2022)
Article
Immunology
A. D. Talantsev, M. Bahmetiev, R. B. Morgunov
Summary: The study reveals that a deviation in magnetic field as small as 2 degrees could result in a 50% change in coercivity in NiFe/IrMn films. To accurately measure the coercivity values of the easy axis, it is important to avoid errors caused by inhomogeneous magnetic fields and manual installation during measurements.
FRONTIERS IN IMMUNOLOGY
(2021)
Article
Physics, Applied
Zekun Chen, Xin Yang, Yukai Chen, Haobin Zheng
Summary: The prediction of losses in giant magnetostrictive material is challenging. This paper proposes a concise parameter identification procedure and verifies its effectiveness through experiments, showing that the iron losses can be accurately estimated.
JOURNAL OF APPLIED PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Wen Xu, Yuan Ma, Xinjia Wei, Honghui Gong, Xiuge Zhao, Yuxi Qin, Qingpo Peng, Zhenshan Hou
Summary: A new strategy has been proposed for synthesizing Co@CoO core-shell nanoparticles with a core-shell structure, which showed good activity and stability for the hydroformylation of olefins. The metal Co(0) species played an important role in the reaction, and the CoO layer suppressed the loss of active Co species. Moreover, the core-shell nano-catalysts exhibited good recyclability and easy separability.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Engineering, Multidisciplinary
A. D. Talantsev, M. V. Bahmetiev, R. B. Morgunov
Summary: Accurate measurement of coercivity in thin magnetic films is crucial for the sensor industry. The coercivity of coupled ferromagnetic layers in exchange biased multilayers heavily depends on the orientation of the easy axis relative to the field. We demonstrate that a 2-degree misalignment in a NiFe/IrMn film with a high HB/HC ratio can result in a 50% change in coercivity. Inhomogeneous magnetic field during film deposition and manual sample installation introduce significant errors in coercivity measurement. Our proposed measurement and analysis protocol overcomes this uncertainty and allows for the evaluation of easy axis coercivity values from tilted angle measurements over a wide temperature range, using a single reference value measured at room temperature.
Article
Chemistry, Multidisciplinary
Chuan Gang, Jiayi Chen, Xu Li, Bo Ma, Xudong Zhao, Yantao Chen
Summary: A novel core-shell heterostructure composed of Cu3P nanowires with supported CoO nanosheets was synthesized. The as-prepared Cu3P@CoO exhibited high efficiency for hydrogen evolution due to numerous active sites and synergistic effect. The theoretical calculations showed that Cu3P@CoO had a zero bandgap and optimized adsorption free energy of intermediates, leading to enhanced charge transfer and intrinsic activity.