期刊
APPLIED PHYSICS LETTERS
卷 96, 期 7, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3319508
关键词
cerium compounds; doping; high-temperature superconductors; hydrogen; iron compounds; lanthanum compounds; lattice constants; oxygen compounds; praseodymium compounds; proton magnetic resonance; superconducting transition temperature
资金
- The Ministry of Education, Culture, Sports, Science and Technology (MEXT) [20001004]
- Mitsubishi Foundation
- JST
We report that the incorporation of hydroxide ions (OH)(-) significantly enhances the superconducting transition temperature (T-c) in the LnFeAsO-based superconductors (Ln1111: Ln=La, Ce, and Pr). For La1111, T-c of the (OH)(-) incorporated sample synthesized using high-pressure technique becomes 35 K, which is higher by 7 K than the typical optimally doped La1111 superconductors. Similar enhancement in T-c is also observed for Ce1111 and Pr1111. H-1-NMR measurement have confirmed the existence of hydrogen atoms in the samples. Accompanying the (OH)(-) incorporation, the lattice parameters are largely contracted, down to the values which have never been attained by any other dopings/substitutions.
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