Article
Physics, Applied
P. Riederer, C. Eckel, R. T. Weitz, R. Kersting
Summary: Terahertz electromodulation spectroscopy is used to investigate charge transport in PDPP3T. Both electrons and holes exhibit band transport along the polymer chain. In devices with oriented thin-films, electron and hole mobilities of 2.0 and 12.8 cm^2/V s are measured, respectively. Temperature-resolved and long-time measurements suggest that only a fraction of the injected charge carriers participate in band transport, and carrier trapping into localized states is identified as the major factor limiting overall mobilities. The observed mobilities are expected to be significantly lower than the material's inherent mobilities according to the Ioffe-Regel criterion.
APPLIED PHYSICS LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Panpan Yu, Yang Li, Huijuan Zhao, Lingyun Zhu, Yongshuai Wang, Wei Xu, Yonggang Zhen, Xinran Wang, Huanli Dong, Daoben Zhu, Wenping Hu
Summary: The study focuses on organic ambipolar semiconductors and successfully synthesizes four 1D mixed-stack cocrystals using electron donor-acceptor alternative stacking. These cocrystals exhibit high electron mobility and balanced hole mobility, showing potential for the development of organic ambipolar semiconductors.
Article
Chemistry, Physical
Sungmin On, Young-Joon Kim, Han-Koo Lee, Hocheon Yoo
Summary: The study systematically investigated the chemical and morphological structure of small-molecule organic semiconductor heterostructures, demonstrating ambipolar and anti-ambipolar transistors with unique applications.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Arulmozhi Velusamy, Yen-Yu Chen, Meng-Hao Lin, Shakil N. Afraj, Jia-Hao Liu, Ming-Chou Chen, Cheng-Liang Liu
Summary: This work presents a series of novel quinoidal organic semiconductors based on DSpDST conjugated cores with various side-chain lengths. The research aims to develop solution-processable organic semiconductors for OFET applications. The physical, electrochemical, and electrical properties of these semiconductors are systematically studied, along with their performance in OFETs and thin film morphologies. The compound with the shortest thioalkyl chain, DSpDSTQ-6, shows ambipolar carrier transport with high electron and hole mobility.
Article
Materials Science, Multidisciplinary
Xu Zhou, Zi Wang, Ruxin Song, Yadan Zhang, Lunan Zhu, Di Xue, Lizhen Huang, Lifeng Chi
Summary: Research on organic semiconductor gas sensors based on ambipolar transistors shows higher sensitivity and stability in gas sensing, enabling easier discrimination of target gases.
JOURNAL OF MATERIALS CHEMISTRY C
(2021)
Article
Chemistry, Multidisciplinary
Xiaofei Guo, Yihan Zhang, Yongxu Hu, Jiaxin Yang, Yang Li, Zhenjie Ni, Huanli Dong, Wenping Hu
Summary: This study demonstrates the potential of mesopolymers with high solubility, free of structural defects, and tunable molecular weights in organic optoelectronics, particularly in the construction of organic light emitting transistors with strong emission and ambipolar carrier mobility.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Nanoscience & Nanotechnology
Junyi Zhu, Takehiko Mori
Summary: This study offers a quantitative analysis of organic AATs depending on the different operation regions, and demonstrates the recombination of carriers in the lateral p-n junction region through the extraction of transistor parameters from experimentally observed characteristics.
ADVANCED ELECTRONIC MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Liangliang Chen, Zhengsheng Qin, Han Huang, Jing Zhang, Zheng Yin, Xiaobo Yu, Xi-sha Zhang, Cheng Li, Guanxin Zhang, Miaofei Huang, Huanli Dong, Yuanping Yi, Lang Jiang, Hongbing Fu, Deqing Zhang
Summary: A new design strategy is reported for highly emissive ambipolar and n-type organic semiconductors by introducing perfluorophenyl groups into polycyclic aromatic hydrocarbons. The results show that 3,9-diperfluorophenyl perylene exhibits ambipolar semiconducting property and a photoluminescence quantum yield of 55%. Crystals of 5FDPP also display blue emission and the highest electron mobility among reported organic emissive n-type semiconductors. Furthermore, OLETs fabricated using 5FDPP crystals achieve high electroluminescence efficiency and current density.
Article
Multidisciplinary Sciences
Reem B. Rashid, Weiyuan Du, Sophie Griggs, Iuliana P. Maria, Iain McCulloch, Jonathan Rivnay
Summary: The study introduces an active sensing node and inverter based on OECTs for signal amplification in bioelectronic sensing, providing new opportunities to improve signal quality and reduce the burden of signal transmission, while also demonstrating compatibility with nontraditional fabrication methods.
Article
Chemistry, Multidisciplinary
Hao Hu, Guohao Wen, Jiamin Wen, Long-Biao Huang, Meng Zhao, Honglei Wu, Zhenhua Sun
Summary: The research focuses on studying the charge storage ability of type-I InP/ZnS core/shell quantum dots in a pentacene-based organic transistor. The quantum dots can directly confine either holes or electrons in the core, and can be charged by electrons using light illumination.
Article
Chemistry, Multidisciplinary
Jibin J. Samuel, Ashutosh Garudapalli, Aiswarya Abhisek Mohapatra, Chandrasekhar Gangadharappa, Satish Patil, Naga Phani B. Aetukuri
Summary: The study proposes the use of triethylene glycol-functionalized DPP-based polymer as an ideal channel material for ambipolar OECTs, showing high performance in both n- and p-type operations and demonstrating logic operations with complementary circuits. This research represents an important step towards developing sophisticated logic circuits using single-component OECTs.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Review
Polymer Science
Xin Zhu, Shi-Rui Zhang, Ye Zhou, Su-Ting Han
Summary: This mini-review mainly focuses on recent progress in polymeric semiconductors for ambipolar organic field-effect transistors, highlighting the significant influence of thin film microstructure, molecular design, and processing conditions on device performance through examples of popular polymers.
POLYMER INTERNATIONAL
(2021)
Review
Chemistry, Organic
Li Min, Lv Aifeng
Summary: This review reports on the key requirements, electrical properties, and factors correlating with the performance of ambipolar OFETs based on organic bilayer.
CHINESE JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Peng Wei, Xudong Wang, Xianglong Li, Songyu Han, Nan Qiao, Peng Zhang, Yunfeng Deng, Wei Zhang, Laju Bu, Guanghao Lu
Summary: This study significantly improves the switching-off capability of polymer ambipolar transistors by introducing non-uniformly distributed compensation potentials, achieving high mobility and high on/off ratio for both n-type and p-type operations. This method endows the device with diverse device characteristics and reconfigurable multi-functionalities, promoting the application of ambipolar transistors in various emerging electronics fields.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Gergely Tarsoly, Youngill Choi, Young Gyu You, Sung Ho Jhang, Seungmoon Pyo
Summary: Most organic thin film-based phototransistors exhibit increased current under illumination due to trapped photogenerated minority charge carriers, but with a unique active layer structure, abnormal photoresponse behaviors can occur: hole-dominated current decreases under illumination and shows an anomalous dependence on irradiance. The current decreases with increasing irradiance, until a moderate current increase is observed. Under a constant negative bias, turning on a discrete light pulse sharply decreases the current, which slowly increases to saturation before rising again when illumination ceases. These anomalies are modeled using a mathematical model based on trapping and releasing photogenerated holes and electrons simultaneously.
ADVANCED ELECTRONIC MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Toshiki Higashino, Satoru Inoue, Yuichi Sadamitsu, Shunto Arai, Sachio Horiuchi, Tatsuo Hasegawa
Article
Chemistry, Multidisciplinary
Toshiki Higashino, Kazunori Kuribara, Naoya Toda, Sei Uemura, Hiroaki Tachibana, Reiko Azumi
Article
Multidisciplinary Sciences
Gyo Kitahara, Satoru Inoue, Toshiki Higashino, Mitsuhiro Ikawa, Taichi Hayashi, Satoshi Matsuoka, Shunto Arai, Tatsuo Hasegawa
Article
Chemistry, Physical
Toshiki Higashino, Satoru Inoue, Shunto Arai, Hiroyuki Matsui, Naoya Toda, Sachio Horiuchi, Reiko Azumi, Tatsuo Hasegawa
Summary: This study demonstrates that engineered end-cap substitution can achieve well-ordered two-dimensional molecular packing for high-performance organic semiconductors. By developing phenyl- and decyl-substituted compounds, layered single-crystalline thin-film transistors with high hole mobility were successfully fabricated.
CHEMISTRY OF MATERIALS
(2021)
Article
Crystallography
Tomofumi Kadoya, Shiori Sugiura, Toshiki Higashino, Keishiro Tahara, Kazuya Kubo, Takahiko Sasaki, Kazuo Takimiya, Jun-ichi Yamada
Summary: This study reports the structural and physical properties of a new organic Mott insulator (BEDT-BDT)AsF6, revealing that at low temperatures, the AsF6 salt causes an increase in angle between BEDT-BDT molecules, leading to a significant change in the electronic structure.
Article
Chemistry, Physical
Satoru Inoue, Kiyoshi Nikaido, Toshiki Higashino, Shunto Arai, Mutsuo Tanaka, Reiji Kumai, Seiji Tsuzuki, Sachio Horiuchi, Haruki Sugiyama, Yasutomo Segawa, Kiyofumi Takaba, Saori Maki-Yonekura, Koji Yonekura, Tatsuo Hasegawa
Summary: The study develops solution-processable organic semiconductors based on unsymmetric substitution of BTBT, showcasing formation of distinctive solid crystalline phases when substituents are similar, and bilayer-type crystalline phase when substituents are unsymmetrical. Controllable various phases are demonstrated in layered organic semiconductors through correlation and competition among different packing structures.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Tomofumi Kadoya, Masaharu Shishido, Shiori Sugiura, Toshiki Higashino, Keishiro Tahara, Kazuya Kubo, Takahiko Sasaki, Jun-ichi Yamada
Summary: A new organic donor BEDT-BDS with a greater degree of molecular bending compared to BEDT-BDT has been synthesized, forming a quasi-one-dimensional electronic structure in a radical-cation salt.
Article
Chemistry, Multidisciplinary
Kiyoshi Nikaido, Satoru Inoue, Reiji Kumai, Toshiki Higashino, Satoshi Matsuoka, Shunto Arai, Tatsuo Hasegawa
Summary: This study demonstrates the control of long-axis molecular ordering under ambient conditions using unsymmetrically alkylated OSCs with high layered crystallinity, leading to improved hole mobility in transistor characteristics.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Masatoshi Ito, Tomoko Fujino, Lei Zhang, So Yokomori, Toshiki Higashino, Rie Makiura, Kanokwan Jumtee Takeno, Taisuke Ozaki, Hatsumi Mori
Summary: Researchers synthesized planar alkoxy-substituted nickel bis(dithiolene) analogs with good solubility and crystallinity, which exhibited excellent ambipolar semiconductor performance in air. By addressing the molecular structure issue, they achieved high carrier mobility and large on/off ratio.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Review
Chemistry, Multidisciplinary
Tomofumi Kadoya, Toshiki Higashino
Summary: In organic transistors, the contact resistance between the organic semiconductor and electrode is a challenge. By using a buffer layer and high-conductivity organic conductors as electrodes, the depletion layer at the semiconductor surface can be reduced. A self-contact transistor, based on chemically doping organic semiconductors, has been proposed to fabricate specific organic conductor electrodes for each semiconductor, resulting in low contact resistance. Organic conductors based on organic semiconductors are crucial for further development and fabrication of these devices.
Article
Materials Science, Multidisciplinary
Satoshi Matsuoka, Kazuma Ogawa, Ryota Ono, Kiyoshi Nikaido, Satoru Inoue, Toshiki Higashino, Mutsuo Tanaka, Jun'ya Tsutsumi, Ryusuke Kondo, Reiji Kumai, Seiji Tsuzuki, Shunto Arai, Tatsuo Hasegawa
Summary: In this study, we present the common structural features of semiconducting molecular donor-acceptor (DA) compounds based on alkylated fused-ring thienoacenes. Crystal structure analyses and density functional theory calculations were conducted to investigate the intermolecular forces between pi-electron cores along the DA stacks. The dominant intermolecular attraction was found to be dispersion interactions, while the short-range orbit-orbit interaction was always repulsive. These findings provide insights into the search for and exploration of unique combinations of molecules with superior semiconducting characteristics.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Chemistry, Physical
Toshiki Higashino, Takehiko Mori
Summary: Ambipolar transistor properties have been observed in various small-molecule materials, requiring a small energy gap and specific molecular designs. In addition to energy levels, an inert passivation layer plays an important role. Extraordinary π-electron systems and some donor/acceptor cocrystals also exhibit ambipolar transport.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Satoru Inoue, Toshiki Higashino, Shunto Arai, Reiji Kumai, Hiroyuki Matsui, Seiji Tsuzuki, Sachio Horiuchi, Tatsuo Hasegawa
Article
Chemistry, Multidisciplinary
Tomofumi Kadoya, Shiori Sugiura, Keishiro Tahara, Toshiki Higashino, Kazuya Kubo, Takahiko Sasaki, Kazuo Takimiya, Jun-ichi Yamada
Article
Chemistry, Multidisciplinary
Toshiki Higashino, Shunto Arai, Satoru Inoue, Seiji Tsuzuki, Yukihiro Shimoi, Sachio Horiuchi, Tatsuo Hasegawa, Reiko Azumi