期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 27, 期 4, 页码 239-244出版社
WILEY-BLACKWELL
DOI: 10.1002/aoc.2968
关键词
asymmetric catalysis; hydrogen peroxide; mechanism; oxidation; sulfides; titanium
资金
- Russian Foundation for Basic Research [12-03-33180]
Titaniumsalan complexes with 3,3'-diphenyl substituents in the salicylidene rings of the salan ligand are efficient sulfoxidation catalysts, capable of catalyzing the asymmetric oxidation of bulky aryl benzyl sulfides with H2O2 with good to high enantioselectivities. In this paper, substituent effects on titanium-salan-catalyzed enantioselective oxidation of sulfides to sulfoxides have been systematically investigated. Titaniumsalan catalysts with halogen substituents at the 5,5'-positions (3,3'-H2dihydrogen substituted) have been found to catalyze the oxidation of both bulky aryl benzyl sulfides and small alkyl phenyl sulfides with good to high enantioselectivities. Kinetic data witness a direct attack of the sulfide to the electrophilic active oxygen species; a consistent reaction mechanism is proposed. Copyright (c) 2013 John Wiley & Sons, Ltd.
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