期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 25, 期 7, 页码 497-501出版社
WILEY-BLACKWELL
DOI: 10.1002/aoc.1792
关键词
N-heterocyclic carbene; proline; palladium; coupling reaction; synthetic methods
资金
- National Natural Science Foundation of China [21002072]
- Department of Education of Zhejiang Province [Y200907072]
- Wenzhou University
Cleavage of a C-N bond of imidazolium salt derived from N-phenyl-substituted proline was observed in this laboratory. A novel imidazole-coordinated monodentate NHC-Pd(II) complex 5 was obtained as the sole product in good yield in the reaction of imidazolium salt 4 with Pd(OAc)(2) in refluxing THF. The structure of complex 5 was determined unambiguously by an X-ray diffraction. The complex was found to be a good catalyst in the cross-coupling reaction of arylboronic acids with carboxylic acid anhydrides in water at room temperature. Copyright (C) 2011 John Wiley & Sons, Ltd.
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