期刊
APPLIED ENERGY
卷 88, 期 12, 页码 4366-4375出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.apenergy.2011.05.017
关键词
Hydrogen production; Ethanol steam-reforming reaction; Ni/Mg/Zeolite Y; Ni(10)/Ga(30)/Mg(30)/Zeolite Y
资金
- New & Renewable Energy of the Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Korea government Ministry of Knowledge Economy [2010T100100622]
In order to reduce the coke formation over a conventional Ni/gamma-Al2O4 catalyst and increase the activity at low temperature, we used the impregnation approach to synthesize MgO (30.0 wt.%)/Zeolite Y catalysts loaded with bimetallic Ni(10.0 wt.%)/Ga(10.0-30.0 wt.%) and study the steam-reforming reactions of ethanol. The Ga-loaded catalyst impregnated between the Ni and Mg components exhibits significantly higher reforming reactivity compared to the conventional Ni/Mg/Zeolite Y catalyst. The main products from steam reforming over the Ni/Ga/Mg/Zeolite Y catalyst are only H-2 and CH4 at above 550 degrees C, and the catalytic performances differ according to the amount of Ga. The H-2 production and ethanol conversion are maximized at 87% and 100%, respectively, over Ni(10)/Ga(30)/Mg(30)/Zeolite Y at 700 degrees C for 1 h at CH3CH2OH:H2O = 1:3 and a gas hourly space velocity (GHSV) of 6740 h(-1), and the high performance is maintained for up to 59 h. (C) 2011 Elsevier Ltd. All rights reserved.
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