期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 111, 期 -, 页码 165-177出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2011.09.031
关键词
HC-SCR; Ag/Al2O3; Emissions; Modelling
资金
- Engineering and Physical Science Research Council (EPSRC)
- Johnson Matthey Plc
- Royal Thai Government
- EPSRC [EP/G038139/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G038139/1] Funding Source: researchfish
A numerical simulation is designed in order to better understand the selective catalytic reduction of NO2 by propane (C3H8-SCR) in the presence of hydrogen. The simulation was designed for a single channel of a monolith typical for automotive catalytic converters, coated with a silver alumina catalyst (Ag/Al2O3). The complicated physical and chemical processes occurring during the reactions are solved by computational fluid dynamics (CFD) coupled with a surface-reaction mechanism. This mechanism is developed based on detailed microkinetic analysis. The elementary-step-like surface reaction mechanism (consisting of 94 reactions, 24 gas-phase species and 24 adsorbed surface species) is applied to investigate the effect on the conversion of NO2 to N-2 Of Chemical kinetic Steps, such as intermediate species. Results from the modelling emphatically agree with the experimental data. The modelling can predict the NO2 conversion at various operating conditions. Furthermore, the modelling can also provide information that is difficult to measure, for example predicts the channel wall temperature and surface coverage of surface species. (C) 2011 Elsevier B.V. All rights reserved.
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