Article
Engineering, Chemical
Ndumiso Vukile Mdlovu, Kuen-Song Lin, Chi -Jung Chang, You-Sheng Lin, Syeda Fareesa Hassan
Summary: In this study, tungsten-doped titania nanotubes were synthesized to enhance their reactivity in the photodegradation of various dyes under UV radiation. The W-doped TNs exhibited a high specific surface area and the presence of W6+ species, as confirmed by XPS spectra. The photodegradation of the dyes involved two-step reactions, and the W-doped TNs showed optimal photocatalytic efficiencies for the degradation of each dye.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2023)
Review
Engineering, Environmental
J. Ambigadevi, P. Senthil Kumar, Dai-Viet N. Vo, S. Hari Haran, T. N. Srinivasa Raghavan
Summary: The textile industry plays a significant role in the Indian economy, however, the synthetic dyes used in this industry pose a serious threat to the environment. Heterogeneous photocatalysis using semiconductor-based nanoparticles has emerged as an effective solution for treating textile effluent and various nanostructures have shown promising results in degrading harmful pollutants.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Environmental Sciences
Ernesto Valadez-Renteria, Jorge Oliva, Nayeli E. Navarro-Garcia, Vicente Rodriguez-Gonzalez
Summary: W-doped sodium nanotube titanate nanoparticles were used for the photocatalytic degradation of bromophenol blue dye. The study showed that the nanoparticles can be mixed with car's tire powder or supported on recycled car's air filters to enhance their performance. Additionally, the research demonstrated that the use of wasted car's air filters as a support for photocatalytic powders can effectively degrade the BPB dye.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Review
Engineering, Environmental
Alam S. M. Nur, Marzia Sultana, Atol Mondal, Sumon Islam, Fataha Nur Robel, Aminul Islam, Mst Sumaia Aktar Sumi
Summary: Dye-contaminated water poses a global problem due to its negative impact on human health and the aquatic environment. Photocatalysis using TiO2 as the prime choice catalyst shows promise for dye pollution remediation, but its low quantum efficiency under solar radiation limits commercialization. Research has focused on increasing TiO2's efficiency through doping and morphological modifications to enhance dye degradation under UV-Vis irradiation.
JOURNAL OF WATER PROCESS ENGINEERING
(2022)
Article
Biochemistry & Molecular Biology
Dan-Dan Ren, Xiaoyan Lu, Li-Ping Zhou, Huanghongjun Tian, Shuang Wang, Lu-Fang Ma, Dong-Sheng Li
Summary: The treatment of organic dyes in industrial wastewaters is a significant environmental concern. In this study, the degradation of the organic dye gentian violet was efficiently achieved using a specific catalyst and oxidant at room temperature, providing an effective approach for the treatment of dyeing wastewater.
Article
Environmental Sciences
Yadala Venkata Divyasri, Nagappagari Lakshmana Reddy, Kiyoung Lee, M. Sakar, Vempuluru Navakoteswara Rao, Vemula Venkatramu, Muthukonda Venkatakrishnan Shankar, Nallagondu Chinna Gangi Reddy
Summary: This study optimized nitrogen doping in TiO2 nanotubes to achieve enhanced photocatalytic efficiency for dye degradation and hydrogen production under solar light exposure. By controlling the nitrogen doping concentration, the N-doped TiO2 nanotubes showed efficient photocatalytic performance and stable recyclability.
ENVIRONMENTAL POLLUTION
(2021)
Article
Chemistry, Applied
Ndumiso Vukile Mdlovu, Nien-Che Yang, Kuen-Song Lin, Chi-Jung Chang, Khanh Toan Dinh, Yan-Gu Lin
Summary: In this study, tungsten-doped titania nanotubes (TNs) were prepared and showed enhanced reactivity towards the degradation of methylene blue and basic violet 3 under UV radiation. The doped TNs exhibited high surface areas and mesoporous fractions. The XPS and XANES/EXAFS spectra confirmed the presence of tungsten ions and titanium-oxygen-tungsten bonds in the doped TNs. Photodegradation experiments revealed that the 5% tungsten-doped TNs achieved optimal photocatalytic efficiencies for both methylene blue and basic violet 3.
Article
Environmental Sciences
Lin Zhao, Lei Huang, Zhigang Zheng, Jing Wei, Zhaoguo Qiu, Dechang Zeng
Summary: This study investigates the decolorization performance of Fe75B12.5Si12.5 amorphous alloy ribbons. The results show that these ribbons can effectively degrade AO II azo dyes and have significant potential in the field of wastewater treatment.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Materials Science, Ceramics
Petronela Pascariu, Corneliu Cojocaru, Mihaela Homocianu, Petrisor Samoila, Cosmin Romanitan, Djourelov Nikolay
Summary: A series of tin (Sn)-doped titania (TiO2) composites were prepared by electrospinning and calcination. The effect of dopant amounts and calcination temperatures on the composition, morphology, and photocatalytic activity of the composites was evaluated. The ([1.5%]Sn:TiO2) composite sintered at 500°C showed remarkable photocatalytic activity with a removal efficiency of about 100% and a rate constant of 9.685 x 10-2 min-1. Structural investigations were conducted to explain the photocatalytic activity towards water decontamination.
CERAMICS INTERNATIONAL
(2023)
Review
Chemistry, Physical
Azayez Mansour, Chetioui Souheyla, Megrouss Youcef, Boukabcha Nourdine, Djedouani Amel, Guerroudj Ahlam Roufieda, Meddah Araibi Noureddine, Chouaih Abdelkader
Summary: The organic crystal, (E)-1-[(2,4,6-tribromophenyl) diazenyl]-naphthalen-2-ol azo dye, was fully characterized using reliable spectroscopic techniques. The density functional theory calculations were employed to predict molecular structure, physico-chemical properties, and spectroscopic spectra. The results showed that the compound exhibited stability and nonlinear optical properties in high polar media.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Inorganic & Nuclear
Xiaoqiang Feng, Xiaofang Li, Hao Luo, Bitao Su, Jiantai Ma
Summary: This study investigated the photocatalytic performance of Ni-based LDHs in degrading TC, a model antibiotic pollutant. The prepared LDHs showed superior efficiency in eliminating TC from aqueous solution under UV-vis light irradiation, depending on catalyst dosage and TC concentration. The proposed photocatalytic degradation mechanism suggests that superoxide and hydroxyl radicals play a major role in the process.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Environmental Sciences
Gloria Elena de la Huerta-Hernandez, Jose Chavez-Carvayar, Tatiana Rodriguez-Flores, Ivan Castro-Cisneros, Armando Reyes-Montero, Isaias Hernandez-Perez
Summary: The photocatalytic efficiency of semiconductors can be modified by varying the calcination temperature, which affects their morphological, optical, and structural properties. In this study, the effect of calcination temperature on the properties of a AA'BB'O-3 perovskite material was evaluated, showing a clear relationship between the photoactivity and heat treatment.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Engineering, Environmental
Tayeb Bouarroudj, Lamine Aoudjit, Lerari Djahida, Beddiaf Zaidi, Maamar Ouraghi, Djamila Zioui, Sarah Mahidine, Chander Shekhar, Khaldoun Bachari
Summary: In this study, pure and (Ce, Ag) co-doped ZnO were successfully synthesized via a solvothermal process and characterized using various techniques. The (Ce, Ag) co-doped ZnO showed excellent photocatalytic ability, with a higher degradation rate of tartrazine compared to pure ZnO. Operating parameters were optimized for tartrazine degradation, and the reusability of the catalysts was also confirmed after 6 cycles. The proposed mechanism of photocatalytic activity provides insight into the degradation process.
WATER SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Physical
Ithiara Dalponte Dallabona, Alvaro Luiz Mathias, Regina Maria Matos Jorge
Summary: The study demonstrated the preparation and performance of floating TiO2-NaOB/CaAlg beads, which exhibited excellent adsorption and photocatalytic activity for the removal of dye solutions, achieving significant removal rates. The beads also maintained high discoloration capacity even after multiple reuse cycles.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Nanoscience & Nanotechnology
Yu Zhao, Ran Lu, Xin Wang, Xiaochen Huai, Caiyun Wang, Yuji Wang, Su Chen
Summary: The study successfully fabricated the H-TNTs/f-Ti composite with enhanced visible light-induced photoelectric response and more hydroxyl functional groups, which can improve the biocompatibility of dental implants and inhibit bacterial growth effectively.
Article
Chemistry, Physical
Jose Escobar, Maria C. Barrera, Ana W. Gutierrez, Maria A. Cortes-Jacome, Carlos Angeles-Chavez, Jose A. Toledo, Dora A. Solis-Casados
APPLIED CATALYSIS B-ENVIRONMENTAL
(2018)
Article
Chemistry, Applied
E. Lopez-Salinas, J. A. Toledo-Antonio, M. E. Manriquez, M. Sanchez-Cantu, I Cruz Ramos, J. G. Hernandez-Cortez
MICROPOROUS AND MESOPOROUS MATERIALS
(2019)
Article
Materials Science, Multidisciplinary
A. K. Medina-Mendoza, C. Angeles-Chavez, M. A. Cortes-Jacome, J. A. Toledo-Antonio
MATERIALS CHEMISTRY AND PHYSICS
(2019)
Article
Green & Sustainable Science & Technology
Guadalupe Perez, Jorge Islas, Mirna Guevara, Raul Suarez
Article
Chemistry, Applied
D. A. Prado-Chay, M. A. Cortes-Jacome, C. Angeles-Chavez, R. Oviedo-Roa, J. M. Martinez-Magadan, C. Zuriaga-Monroy, I. J. Hernandez-Hernandez, P. Rayo Mayoral, D. R. Gomora-Herrera, J. A. Toledo-Antonio
TOPICS IN CATALYSIS
(2020)
Article
Chemistry, Applied
Luis F. Vazquez-Fuentes, M. A. Cortes-Jacome, E. Lopez-Salinas, Jaime S. Valente, P. Morales Gil, J. G. Hernandez-Cortez, Jose A. Toledo-Antonio
TOPICS IN CATALYSIS
(2020)
Article
Chemistry, Physical
C. Encarnacion-Gomez, M. A. Cortes-Jacome, A. K. Medina-Mendoza, C. Angeles-Chavez, M. G. Hernandez-Cruz, I Cuauhtemoc-Lopez, J. G. Hernandez-Cortez, E. Lopez-Salinas, J. R. Vargas-Garcia, J. A. Toledo-Antonio
APPLIED CATALYSIS A-GENERAL
(2020)
Article
Chemistry, Applied
J. L. Figueroa-Campos, J. A. Toledo-Antonio, L. F. Vazquez-Fuentes, C. Angeles-Chavez, E. Lopez-Salinas, M. L. Mosqueira Mondragon, M. A. Cortes-Jacome
Summary: In this study, a 10 wt% NiO impregnated on mesoporous Y-zeolite catalyst was used for vanillin hydrodeoxygenation. The alkali-treated zeolite with mesoporous structure showed improved catalytic performance, and the synthesis of a bifunctional acid-hydrogenation catalyst was achieved.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Environmental Sciences
S. Orozco, M. Rivero, E. Montiel, J. Espino Valencia
Summary: Heterogeneous photocatalysis is an efficient process for degrading recalcitrant and emerging pollutants. In this study, gallium-based catalysts doped with Fe ions (GOFe) showed improved photocatalytic activity for the degradation of Rhodamine B dye. The presence of Fe ions decreased the bandgap of the gallium oxide matrix, allowing it to activate under visible light. The best discoloration results were observed under acidic conditions (pH = 3.00) for both visible and visible-UV light sources.
FRONTIERS IN ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Applied
Sayra Orozco, Michel Rivero, Raul Suarez-Parra, Mercedes Tellez, Camilo A. Arancibia-Bulnes
Summary: Hybrid photocatalytic reactors (HPR) use both solar and lamp illumination for pollutant degradation with reduced environmental impacts. A method is introduced for HPR design based on simulations calibrated with experimental results, combining a radiative transfer model and a first-order kinetic model to describe pollutant concentration evolution.
TOPICS IN CATALYSIS
(2022)
Article
Crystallography
Vicente Garibay Febles, Dulce Viridiana Melo-Maximo, Isaias Hernandez Perez, Raul Suarez Parra, Julio Cesar Espinoza-Tapia, Ricardo Luna Paz, Lucia Diaz-Barriga Arceo, Jesus Noe Rivera Olvera, Lizbeth Melo-Maximo, Leonardo Gonzalez-Reyes
Summary: This study investigates the thermal decomposition of acetyl acetonates of Ni(II) and Fe(III) under sonochemical treatment. In the absence of magnetic fields, the reactions produce Ni(OH)(2) and FeO(OH) nanoparticles coated with carbon. The catalytic performance of different stoichiometries of Ni-Fe system for dye decolorization was studied and correlated with their structural and optoelectronic properties.
Article
Materials Science, Multidisciplinary
Andres A. Fragoso-Montes de Oca, J. G. Hernandez-Cortez, C. Angeles-Chavez, Jaime S. Valente, J. A. Toledo-Antonio
Summary: Cu/Zn/Al mixed oxide catalysts were synthesized from layered precursors, and the crystalline phase composition of the precursor determined the surface properties of the catalyst. Precursors mainly composed of HTLc phase resulted in a mixed oxide with high Lewis acidity and active hydro/dehydrogenation sites, while precursors mainly composed of Rosasite phase decomposed into Cu-0, ZnO, and Al2O3 during reduction, with Cu-0 acting as the dehydrogenation site.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)