Article
Chemistry, Inorganic & Nuclear
Prasenjit Mandal, Rostam Ali Molla, Asoke P. Chattopadhyay, Sandeep Poddar, Hari Shankar Biswas
Summary: In this study, a simple and robust method was used to prepare a 3-Aminopropyltriethoxysilane (APTES) immobilized graphene oxide nanocomposite with a grafted Cu (II) Schiff base complex. The chemical nature and structure of the final product were characterized using various techniques. The final product demonstrated excellent catalytic activity as a heterogeneous catalyst for the selective aerobic decarboxylation reaction of phenylacetic acid to benzaldehyde under ambient conditions. The catalyst could be reused multiple times without significant loss in activity.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Biochemistry & Molecular Biology
Jyoti Prabha Kujur, Pritish Rajkumar Moon, Devendra Deo Pathak
Summary: A new biocomposite of chitosan-supported di(pyridine-2-yl)methanone-Ni(II) complex was synthesized and applied as a heterogeneous catalyst in an intermolecular catalytical coupling reaction. The catalyst exhibited good catalytic activity, recyclability, and high yields.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Inorganic & Nuclear
Susheela Kumari, Aishwarya Ramesh, Bidisa Das, Saumi Ray
Summary: Planar cobalt(ii) Schiff-base complexes exhibit modified structural and functional properties when encapsulated in zeolite-Y. Encapsulation alters the electron density around the metal center and enhances reactivity for reactions like dye degradation and CO2 transformation. Comparative studies of structural and catalytic modifications provide a rational explanation for the improved reactivity of zeolite encapsulated metal complexes.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Inorganic & Nuclear
Samahe Sadjadi, Neda Abedian-Dehaghani, Fatemeh Koohestani, Majid M. Heravi
Summary: A novel copper Schiff base complex catalyst was successfully prepared in the study, which exhibited high efficiency and recyclability in one-pot reactions, and was applicable to various aldehydes with different electron densities.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Neha Karanwal, Rizky Gilang Kurniawan, Jaeyong Park, Deepak Verma, Suryun Oh, Seung Min Kim, Sang Kyu Kwak, Jaehoon Kim
Summary: In this study, a new catalyst for the continuous conversion of cellulose to γ-valerolactone (GVL) was explored. High yields of the reaction were achieved at low temperature and pressure under supercritical methanol conditions using bimetallic Ru-Cu/Z catalyst. The catalyst showed good activity even after multiple reactions.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Applied
Zhongyuan Zhang, Youlin Liu, Yongji Hu, Sasa Gu, Jianhai Wang, Yuesong Shen, Peiwen Li
Summary: Cuprous oxides were synthesized within the pores of zeolite Y using ion exchange and liquid reduction strategy combined with the confined effect of micropores. The resulting Cu(I)-Y adsorbent exhibited excellent adsorption desulfurization performance due to its unique pore structure, proper pore sizes, and n-complexation interaction with aromatic sulfur compounds. Additionally, the confined effect of pores played a crucial role in stabilizing Cu(I) sites. This facile fabrication strategy, along with the size and confined effect of micropores, provides a new approach for the synthesis of composite porous materials with various active sites.
MICROPOROUS AND MESOPOROUS MATERIALS
(2023)
Article
Chemistry, Applied
Mauro Alvarez, Pablo Marin, Salvador Ordonez
Summary: In this study, a Cu/Y zeolite catalyst was prepared by solid-state ion exchange and was found to be a promising alternative to the traditional CuCl aqueous catalyst for the oxidative carbonylation of methanol. The reaction conditions were optimized and a rigorous kinetic model for the reaction was proposed.
FUEL PROCESSING TECHNOLOGY
(2023)
Article
Energy & Fuels
Chengda Li, Yueli Wen, Bin Wang, Maohong Fan, Wenlong Liu, Zheng Cui, Wei Huang
Summary: Activation and desorption of hydrogen in toluene methyl is the rate-limiting step for side-chain alkylation of toluene with methanol. In this study, two dehydrogenation strategies were employed to enhance catalytic performance by introducing Cu as a dehydrogenation component in PAl-NaX catalyst and adjusting the acid-base properties through varying NaOH loading. The relationship between the percentage of acid-base sites, low valence Cu species, and catalytic performance was investigated using various characterization techniques and ternary regression analysis. The results showed that Cu, especially low valence Cu species, promoted the selectivity of side-chain alkylation products to some extent, but base sites played a more critical role in enhancing selectivity.
Article
Chemistry, Multidisciplinary
Nora S. Abdel-Kader, Hussein Moustafa, Aida L. El-Ansary, Omaima E. Sherif, Aya M. Farghaly
Summary: In this study, a Schiff base and its silver and copper complexes were synthesized and characterized through elemental and spectral analyses. The antimicrobial, antifungal, and cytotoxic activities of these compounds were evaluated. The Ag-Sbat complex showed the highest antimicrobial activity against both Gram-positive and Gram-negative bacteria, as well as antifungal activity against two fungal species.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Wenzhe Ma, Yanjing Yang, Yuxin Jia, Dongxiao Fu, Fengqi Zhao, Kangzhen Xu
Summary: Metal organic complexes, such as Cu(Salen), show promising potential as combustion catalysts for solid rocket propellants. In this study, Cu(Salen) was investigated as a catalyst for HMX-CMDB propellants and was found to significantly enhance the combustion performance by improving burning rate and combustion efficiency, and reducing burning rate pressure index.
Article
Energy & Fuels
Meng Lin, Shunli Zhou, Chengxi Zhang, Yongxiang Li, Chengqiang Wang, Xingtian Shu
Summary: A green and effective treatment method for Y zeolite-based catalyst was proposed, which improved acid accessibility and diffusion performance while maintaining high acidity. The shaped catalyst underwent a pressured treatment to achieve solid state ion exchange, binder bonding, and pore expansion. Characterization results showed that binder bonding protected zeolite structure, leading to improved acid accessibility and diffusion performance through dealumination. The pressured environment promoted zeolite-binder interaction and migration of Al species. The best catalyst, NY-DPA-1, achieved a lifetime of 84 h and increased the alkylation reaction lifetime by 17%.
Article
Energy & Fuels
Bo-Long Jiang, Nan Jiang, You-Xin Chang
Summary: The study demonstrated a bimetal-exchanged NaY zeolite with promising adsorptive desulfurization performance, where Y(III) ions played a promoting role in improving ADS selectivity. The Cu(I)-Y(III)-Y combined the advantages of Cu(I)-Y and Y(III)-Y, showing higher breakthrough loading compared to traditional transition metal Y zeolites.
Article
Chemistry, Applied
Mahshid Sheikh Dastjerdy, Niaz Monadi
Summary: In this study, a new Cu(II) Schiff base complex was immobilized onto the magnetic graphene oxide surface to synthesize the GO/Fe3O4/CuL nanostructure. The synthesized nanocatalyst exhibited excellent catalytic activity in the reduction reactions of 4-nitrophenol, Congo red, and methylene blue, as well as the synthesis of 2-amino-4H-benzopyrans. Furthermore, the catalytic system showed additional advantages such as the use of green solvents, short reaction time, high product yield, and easy separation.
APPLIED ORGANOMETALLIC CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Samaneh Mahmoudi-Gom Yek, Mahmoud Nasrollahzadeh, Davood Azarifar, Akbar Rostami-Vartooni, Masoumeh Ghaemi, Mohammadreza Shokouhimehr
Summary: A magnetically separable and reusable catalyst was prepared and used in a multi-component reaction under solvent-free conditions, showing good catalytic efficiency and environmental friendliness.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Chemistry, Inorganic & Nuclear
Mahrokh Razzaghi Kamroudi, Gholamhossein Grivani
Summary: The new ionic Schiff base macrocycle and its Cu(II) complex were successfully synthesized and characterized. The catalytic activity of the Cu(II) complex in the click reaction was investigated and optimized. Efficient synthesis of 1,2,3-Triazoles was achieved under optimal conditions.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Ming-Yi Chen, Ngoc Thanh Thuy Tran, Ahmed Abubakar Alao, Wen-Dung Hsu
Summary: This study demonstrates the significance of surface Pt atom arrangement for the efficiency of ORR in PEMFCs and reveals the correlation between Pt-Pt average distance and O2 dissociation barrier. Furthermore, the study discovers a robust correlation between the level of the catalyst's d-band center and O2 adsorption energy. High-entropy alloy substrates provide potential for controlling Pt arrangement and O2 dissociation barrier.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Eduardo C. Atayde Jr, Babasaheb M. Matsagar, Yu-Cheng Wang, Kevin C. -W. Wu
Summary: This study presents the first application of an acidic MOF, Sulfated MOF-808, in catalyzing the HAA reactions of furan oligomers for the production of biofuel precursors. The catalyst showed high yield, selectivity, and recyclability, making it versatile for different starting materials.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Maria do Carmo Rangel, Francieli Martins Mayer, Soraia Jesus de Oliveira, Sergio Gustavo Marchetti, Fabricio Luiz Faita, Doris Ruiz, Giovanni Saboia, Mariana Kieling Dagostini, Jonder Morais, Maria do Carmo Martins Alves
Summary: This study developed a new catalyst by investigating the effect of magnesium on the catalytic properties of hematite in ethylbenzene dehydrogenation. The catalyst showed important differences in activity, selectivity, and stability, making it a promising candidate for commercial applications.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Yanjun Li, Qian Wang, Hui Tian, Mingyuan Zhu, Yuanyuan Liu
Summary: A novel strategy using microwave-assisted precipitation was proposed to prepare defective CsH3PMo11VO40 catalyst for the oxidation of methacrolein to methacrylic acid. Microwave treatment accelerates crystallization, increases vanadyl species content, and forms defective Keggin structures, thereby enhancing the oxidation capacity of the catalyst.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Rajeshwari Athavale, Sailee Gardi, Fatima Choudhary, Dayanand Patil, Nandkishor Chandan, Paresh More
Summary: In this study, a novel acidic ionic liquid catalyst was prepared and used for the synthesis of bis-indolyl methane derivatives. The catalyst exhibited short reaction times, easy purification, and reusability.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Masatomo Hattori, Takato Hattori, Masakuni Ozawa
Summary: Cu-added gamma-Al2O3 catalysts were prepared with varying Cu loadings and the effects of copper oxidation states on catalytic activity were investigated. The results showed that the addition of copper increased the catalyst activity, but excessive copper loading decreased catalytic activity. XRD and TEM analysis indicated the formation of a solid solution of copper oxide species on the surface of gamma-Al2O3. XAS and TPR data demonstrated variations in copper oxidation states among the catalysts.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Liwei Fang, Shiyang Niu, Shengsen Wang, Yiqing Lu, Yuanhui Cheng
Summary: In this study, PtNi alloy on nitrogen-doped carbon and SnO2 dual-support was designed to modulate the metal-support interaction, resulting in improved catalytic activity and stability for oxygen reduction reaction. The SnO2/PtNi/NC catalyst exhibited a strongly coupled interface, enhanced electron transfer, and higher half-wave potential compared to PtNi/NC and commercial Pt/C.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Shohei Harada, Duanxing Li, Kenta Iyoki, Masaru Ogura
Summary: This study investigates the catalytic performance of a composite catalyst composed of ZnZrOX and H-zeolite for the hydrogenation of CO2. The deactivation of the composite catalyst is influenced by ion exchange of Zn2+ and/or coke, with their effects differing based on the zeolite structure. Separating the grains of the composite catalyst can prevent deactivation.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Laura Proano, Christopher W. Jones
Summary: In this study, NiGa alloy particles supported on CeO2, ZrO2, and ZrO2-CeO2 solid solutions were prepared and characterized. The nature of the support was found to have a significant influence on the catalyst's activity and selectivity, with the crystalline structure of ZrO2 having the greatest impact. Pure ZrO2 showed the highest methanol selectivity and CO2 conversion at high Zr:Ce ratios. In equimolar and Ce-rich conditions, basic sites and oxygen vacancies were found to be the key parameters affecting methanol production.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Liyan Zhang, Yinze Yang, Leilei Zhou, Fengyu Zhao, Haiyang Cheng
Summary: 1,6-Hexamethylenediamine was successfully synthesized via the reductive amination of 1,6-hexanediol using a Ru/PRL(x)-Al2O3 catalyst. The highly dispersed and anchored Ru species, formed by 1,10-phenanthroline (PRL), played a crucial role in the catalytic reaction. The formation of new acid-base pairs, electron deficient Ru species, and smaller nanoparticles contributed to the improved catalytic performances of the Ru/PRL-Al2O3 catalyst.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Anita Horvath, Miklos Nemeth, Andrea Beck, Gyorgy Safran, Valeria La Parola, Leonarda Francesca Liotta, Gregor Zerjav, Matevz Roskaric, Albin Pintar
Summary: This study investigates the catalytic and structural changes caused by the addition of 0.25 wt% indium in a 3% Ni/CeO2-Al2O3 catalyst prepared by impregnation method. The results show that the addition of indium can decrease the activity of the catalyst, but it improves its stability and reduces coking.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Ankush Kularkar, Vaibhav Vilas Khedekar, Sachin D. Chaudhari, Mudavath Ravi, Sadhana S. Rayalu, Penumaka Nagababu
Summary: Efficiently addressing the challenges of photocatalytic CO2 reduction to CH3OH is crucial. This study developed Zn-BTC MOF and its composites with CaIn2S4, achieving highly efficient and robust photocatalytic CO2 reduction to CH3OH under ambient conditions, using H2O2 as the hydrogen source. Among the composites, ZMCIS4 demonstrated excellent performance with a CH3OH evolution of 49100 μmol/g.cat and a quantum efficiency of approximately 78.41%. The enhanced performance was attributed to the production of nascent hydrogen atoms (H center dot) through the photo-splitting of H2O2 on the ZMCIS surface.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Dan Liu, Yudong Li, Chengyu Wang, Haiyue Yang, Rong Wang, Shujun Li, Xiaohui Yang
Summary: In this study, a self-supporting three-dimensional porous Co3O4 nanobelt array decorated on nickel foam (P-Co3O4 -NBA@NF) electrode with numerous active sites was successfully constructed for the oxidation of 5-Hydroxymethylfurfural (HMF) to 2,5-furan dicarboxylic acid (FDCA). The P-Co3O4 -NBA@NF electrode demonstrated high conversion efficiency, selectivity, and Faraday efficiency, as well as remarkable long-term stability. This research provides a promising electrocatalyst for biomass conversion.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Yimin Li, Enggah Kurniawan, Fumiya Sato, Takayoshi Hara, Yasuhiro Yamada, Satoshi Sato
Summary: In this study, several silica-alumina catalysts modified with Ag were examined for the dehydration of 1,3-butanediol to 1,3-butadiene. Among them, an amorphous silica-alumina catalyst (SAL-3) modified with Ag showed the highest improvement in catalytic activity and stability when operated in H2 flow. The generation of reversible acid sites was found to be the reason behind the enhanced activity and stability of this Ag/SAL-3 catalyst. The effects of various parameters on the catalytic activity of Ag/SAL-3, such as reaction temperature, contact time, Ag content, and carrier gas, were investigated.
APPLIED CATALYSIS A-GENERAL
(2024)