期刊
APPLIED CATALYSIS A-GENERAL
卷 390, 期 1-2, 页码 19-25出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2010.09.032
关键词
Nanoparticle; Template; Heterogeneous catalyst; Surface structure; Pt-Re; Naphtha reforming
The need for naphtha reforming to produce high quality reformate for gasoline blend stocks with increased yield has become more urgent due to dwindling crude oil reserves and stringent air pollution regulations Reforming catalysts prepared using polyacrylic acid (PM) as a metal ion template exhibited 1 4-24% improvement in reformate yield and 1 0-2 0 wt% lower aromatic production compared to commercially available catalysts prepared using traditional metal salt coimpregnation methods while maintaining a comparably high octane number The catalyst prepared using the PM template also showed higher liquid recovery with less coke deposition and longer projected catalyst lifetime Characterization using infrared spectroscopy following the adsorption of CO revealed that catalysts made using the PAA method contained platinum particle surfaces with reduced atom coordination numbers (C) 2010 Elsevier B V All rights reserved
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