期刊
APPLIED CATALYSIS A-GENERAL
卷 356, 期 1, 页码 99-102出版社
ELSEVIER
DOI: 10.1016/j.apcata.2008.12.026
关键词
Gold; Catalysis; Homogeneous; Selective hydrogenation; Nitro compounds
资金
- Direccion General de Investigacion Cientifica y Tecnica of Spain [MAT2006-14274-C02-01-02]
Nitro groups on different compounds - containing double bonds, carbonyl, nitrile or halide groups - have been successfully hydrogenated with well-defined homogeneous gold and palladium complexes as catalysts using a batch reactor under low H-2 pressure. Gold complexes show high chemoselectivity towards reduction of the nitro group at near-complete conversion of the substrate. The corresponding amino derivatives are isolated in high yields. (C) 2008 Elsevier B.V. All rights reserved.
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