期刊
APPLIED CATALYSIS A-GENERAL
卷 366, 期 1, 页码 212-219出版社
ELSEVIER
DOI: 10.1016/j.apcata.2009.07.007
关键词
Alcohols; Aldehydes; Ketones; Catalytic oxidation; Molecular oxygen; Heterogeneous RuMnCe catalysts
The combination of ruthenium, manganese as well as cerium oxides formed an active catalytic system for the oxidation of 2-octanol and other alcohols. The addition of manganese species as promotors resulted in more active catalysts than comparable cobalt-doped oxidic materials. The application of RuMnCe oxides on redox-active supports, such as TiO2 or CeO2, by deposition-precipitation caused a further improvement of catalytic activity. A tolerance to nitrogen-containing substrates was observed. (C) 2009 Elsevier B.V. All rights reserved.
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