期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 42, 页码 13922-13926出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201808436
关键词
allenes; boron; dimerization; rearrangements; reaction mechanisms
资金
- European Research Council
- Deutsche Forschungsgemeinschaft
A series of arylallenes react with HB(C6F5)(2) in a 2:1 molar ratio to give the tail-to-tail 1,6-diaryl-2-boryl-hexa-1,5-diene coupling products. The reaction of the phenylallene substrate with HB(C6F5)(2) was shown to initially give the 2-boryl-3,4-diphenyl-1,5-hexadiene head-to-head coupling product which then rearranged, by a thermally induced Cope rearrangement, into the final product.
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