期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 38, 页码 12275-12279出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201807435
关键词
amine boranes; boron; hydrogen transfer; hydrogenation; main-group elements
The first spontaneous, metal-free, room-temperature hydrogen transfer from ammonia borane to an iminoborane is reported. Mechanistic studies of the reaction indicate a concerted transfer of H+ and H- from donor to acceptor with an activation energy far below those of comparable concerted transfer hydrogenations. This reaction was employed in the syntheses and isolation of new B,N-disubstituted aminoboranes, a comparatively rare subset within the aminoborane family. This successful transfer hydrogenation to a highly dehydrogenated BN system may serve as a starting point for the design of new systems capable of reversible dehydrogenation/rehydrogenation.
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