期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 46, 页码 15272-15275出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201809983
关键词
boryl anion; cyclic (alkyl)(amino) carbene; diborane; nucleophilic boron; reduction
资金
- Deutsche Forschungsgemeinschaft
- University of Sussex (A.V.)
While the one-electron reduction of (CAAC(Me))BH2Br (CAAC(Me) = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene) yields a hydride-shift isomer of the corresponding tetrahydrodiborane, a further reversible reduction leads to the first stable parent boryl anion, [(CAAC(Me))BH2](-), which acts as a powerful boron nucleophile.
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