[FeFe]-Hydrogenase Mimetic Metallopolymers with Enhanced Catalytic Activity for Hydrogen Production in Water

Reversing the Tradeoff between Rate and Overpotential in Molecular Electrocatalysts for H2 Production

(2018) Christina M. Klug et al.   ACS Catalysis

Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts

(2017) Katherine J. Lee et al.   Nature Reviews Chemistry

A Poly(cobaloxime)/Carbon Nanotube Electrode: Freestanding Buckypaper with Polymer-Enhanced H2 -Evolution Performance

(2016) Bertrand Reuillard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular engineered nanomaterials for catalytic hydrogen evolution and oxidation

(2016) Nathan Coutard et al.   CHEMICAL COMMUNICATIONS

Polymers functionalized with 1,2-benzenedithiolate-bridged model compound of [FeFe]-hydrogenase: Synthesis, characterization and their catalytic activity

(2016) Xinglong Zhu et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Artificial hydrogenases: biohybrid and supramolecular systems for catalytic hydrogen production or uptake

(2015) Giorgio Caserta et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Oxygen-tolerant proton reduction catalysis: much O2 about nothing?

(2015) David W. Wakerley et al.   Energy & Environmental Science

Introducing polyethyleneimine (PEI) into the electrospun fibrous membranes containing diiron mimics of [FeFe]-hydrogenase: Membrane electrodes and their electrocatalysis on proton reduction in aqueous media

(2015) Diyang Zhu et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Benchmarking of Homogeneous Electrocatalysts: Overpotential, Turnover Frequency, Limiting Turnover Number

(2015) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Electrochemical and Photoelectrochemical H2 Production from Water by a Cobalt Dithiolene One-Dimensional Metal–Organic Surface

(2015) Courtney A. Downes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toward a tunable synthetic [FeFe] hydrogenase mimic: single-chain nanoparticles functionalized with a single diiron cluster

(2015) C. A. Tooley et al.   Polymer Chemistry

Cover Picture: Kinetic Passivation Effect of Localized Differential Aeration on Brass (ChemPlusChem 1/2016)

(2015) Volodymyr Kuznetsov et al.   ChemPlusChem

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Electrocatalytic O2 Reduction by [Fe-Fe]-Hydrogenase Active Site Models

(2014) Subal Dey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The oxidative inactivation of FeFe hydrogenase reveals the flexibility of the H-cluster

(2014) Vincent Fourmond et al.   Nature Chemistry

Electrochemical, Spectroscopic, and Computational Study of Bis(μ-methylthiolato)diironhexacarbonyl: Homoassociative Stabilization of the Dianion and a Chemically Reversible Reduction/Reoxidation Cycle

(2014) Orrasa In-noi et al.   ORGANOMETALLICS

Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts

(2014) Cyrille Costentin et al.   ChemElectroChem

Exceptional Poly(acrylic acid)-Based Artificial [FeFe]-Hydrogenases for Photocatalytic H2Production in Water

(2013) Feng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides

(2013) R. Morris Bullock et al.   CHEMICAL COMMUNICATIONS

Controlled radical polymerization of styrene-based models of the active site of the [FeFe]-hydrogenase

(2013) Daniel Heine et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Biomimetic assembly and activation of [FeFe]-hydrogenases

(2013) G. Berggren et al.   NATURE

An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen

(2013) Tianbiao Liu et al.   Nature Chemistry

Earth-abundant hydrogen evolution electrocatalysts

(2013) James R. McKone et al.   Chemical Science

Electrochemical hydrogen production in aqueous micellar solution by a diiron benzenedithiolate complex relevant to [FeFe] hydrogenases

(2012) François Quentel et al.   Energy & Environmental Science

[FeFe]-hydrogenase-inspired membrane electrode and its catalytic evolution of hydrogen in water

(2012) Enbin Xu et al.   RSC Advances

Sulfonated Diiron Complexes as Water-Soluble Models of the [Fe–Fe]-Hydrogenase Enzyme Active Site

(2011) Michael L. Singleton et al.   INORGANIC CHEMISTRY

A Discussion of the pH-Dependent Protonation Behaviors of Poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) and Poly(ethylenimine-ran-2-ethyl-2-oxazoline) (P(EI-r-EOz))

(2011) Hoyoung Lee et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Catalytic Turnover of [FeFe]-Hydrogenase Based on Single-Molecule Imaging

(2011) Christopher Madden et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functional soft materials from metallopolymers and metallosupramolecular polymers

(2011) George R. Whittell et al.   NATURE MATERIALS

Reversibility and efficiency in electrocatalytic energy conversion and lessons from enzymes

(2011) F. A. Armstrong et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Enable PVC plastic for a novel role: its functionalisation with diiron models of the sub-unit of [FeFe]–hydrogenase, assembly of film electrodes, and electrochemical investigations

(2011) Lianjie Wang et al.   RSC Advances

Synthesis and characterisation of polymeric materials consisting of {Fe2(CO)5}-unit and their relevance to the diiron sub-unit of [FeFe]-hydrogenase

(2010) Caixia Zhan et al.   DALTON TRANSACTIONS

Bioinspired polymer functionalized with a diiron carbonyl model complex and its assembly onto the surface of a gold electrode via “click” chemistry

(2010) Xiang Ru et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Synthesis of Diiron Hydrogenase Mimics Bearing Hydroquinone and Related Ligands. Electrochemical and Computational Studies of the Mechanism of Hydrogen Production and the Role of O−H···S Hydrogen Bonding†

(2010) Jinzhu Chen et al.   ORGANOMETALLICS

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

Review of electrochemical studies of complexes containing the Fe2S2 core characteristic of [FeFe]-hydrogenases including catalysis by these complexes of the reduction of acids to form dihydrogen

(2009) Greg A.N. Felton et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

[Ni(PPh2NAr2)2(NCMe)][BF4]2 as an electrocatalyst for H2 production: PPh2NAr2=1,5-(di(4-(thiophene-3-yl)phenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane)

(2009) Douglas H. Pool et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Erratum: Powering the planet with solar fuel

(2009) Harry B. Gray   Nature Chemistry

Small molecule mimics of hydrogenases: hydrides and redox

(2008) Frédéric Gloaguen et al.   CHEMICAL SOCIETY REVIEWS