期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 8, 页码 2186-2189出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309791
关键词
aromatic substitution; aryl nitriles; cyanation; hypervalent iodine; iron catalysis
资金
- 973 Program [2012CB821600]
- NSFC [21272010, 21172005, 21332002]
A direct oxidative cyanation of arenes under Fe-II catalysis with 3,5-di(trifluoromethyl)phenyl(cyano)iodonium triflate (DFCT) as the cyanating agent has been developed. The reaction is applicable to wide range of aromatic substrates, including polycyclic structures and heteroaromatic compounds.
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