Catalytic Borylation of SCF3-Functionalized Arenes by Rhodium(I) Boryl Complexes: Regioselective CH Activation at theortho-Position

Phosphine-Directed CH Borylation Reactions: Facile and Selective Access to Ambiphilic Phosphine Boronate Esters

(2014) Kristina M. Crawford et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SF and SC Activation of SF6and SF5Derivatives at Rhodium: Conversion of SF6into H2S

(2014) Lada Zámostná et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Catalytic Trifluoromethylthiolation of Boronic Acids and Alkynes Employing Electrophilic Shelf-StableN-(trifluoromethylthio)phthalimide

(2014) Roman Pluta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural Reevaluation of the Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation Supported by the Crystalline Sponge Method for X-ray Analysis

(2014) Ekaterina V. Vinogradova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functional group directed C–H borylation

(2014) A. Ros et al.   CHEMICAL SOCIETY REVIEWS

Versatile reactivity of a rhodium(i) boryl complex towards ketones and imines

(2014) Sabrina I. Kalläne et al.   DALTON TRANSACTIONS

Iridium-Catalyzed C–H Borylation of Heteroarenes: Scope, Regioselectivity, Application to Late-Stage Functionalization, and Mechanism

(2014) Matthew A. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent

(2014) Grégory Danoun et al.   Chemical Science

Formation of CSCF3Bonds through Direct Trifluoromethylthiolation

(2013) Anis Tlili et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Catalyzed Electrophilic Trifluoromethylthiolation of Terminal Alkynes

(2013) Sébastien Alazet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

(2013) Xinxin Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions

(2013) Moritz F. Kuehnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Trifluoromethylthiophthalimide: A Stable Electrophilic SCF3-Reagent and its Application in the Catalytic Asymmetric Trifluoromethylsulfenylation

(2013) Teerawut Bootwicha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Traceless Directing Group for CH Borylation

(2013) Sean M. Preshlock et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amino-Directed RhIII-Catalyzed CH Activation Leading to One-Pot Synthesis of NH Carbazoles

(2013) Qibai Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Trifluoromethyl Thiolation-Mild and Efficient Synthesis of Trifluoromethyl Thioethers

(2013) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Rhodium(I) Boryl Complexes: Catalytic N-H Activation of Anilines and Ammonia

(2013) Michael Teltewskoi et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic hydrodefluorination of fluoroaromatics with silanes as hydrogen source at a binuclear rhodium complex: Characterization of key intermediates

(2013) Lada Zámostná et al.   JOURNAL OF FLUORINE CHEMISTRY

Role of Electron-Withdrawing Remote Substituents in Neutral Nickel(II) Polymerization Catalysts

(2013) Anna Osichow et al.   ORGANOMETALLICS

Rhodium(I) Silyl Complexes for C–F Bond Activation Reactions of Aromatic Compounds: Experimental and Computational Studies

(2013) Anna Lena Raza et al.   ORGANOMETALLICS

Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides

(2012) François Baert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides

(2012) Zhiqiang Weng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur

(2012) Chao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state

(2012) Lena Arnold et al.   CHEMICAL COMMUNICATIONS

Hydrazone as the Directing Group for Ir-Catalyzed Arene Diborylations and Sequential Functionalizations

(2012) Abel Ros et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Outer-Sphere Direction in Iridium C–H Borylation

(2012) Philipp C. Roosen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Promoted Sulfenylation of sp2 C–H Bonds

(2012) Ly Dieu Tran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Syntheses of (4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)arenes through Pd-catalyzed borylation of arylbromides with the successive use of 2,2′-bis(1,3,2-benzodioxaborole) and pinacol

(2012) Jun Takagi et al.   TETRAHEDRON LETTERS

Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions

(2011) Georgiy Teverovskiy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Use of Hemilabile N,N Ligands in Nitrogen-Directed Iridium-Catalyzed Borylations of Arenes

(2011) Abel Ros et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselectivity of the borylation of alkanes and arenes

(2011) John F. Hartwig   CHEMICAL SOCIETY REVIEWS

C-F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalysis

(2011) Thomas Braun et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Selective Sulfoxidation of Thioethers and Thioaryl Boranes with Nitrate, Promoted by a Molybdenum–Copper Catalytic System

(2011) Hanit Marom et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh-CatalyzedOrtho-Selective C–H Borylation ofN-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands

(2011) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Oxidative ortho-C–H Borylation of Arenes

(2011) Hui-Xiong Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Synthesis of Aryl Trifluoromethyl Sulfides at Room Temperature

(2011) Cheng-Pan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-flask preparation of polyazatriaryl ligands by sequential borylation/Suzuki–Miyaura coupling

(2011) Bertoldo Avitia et al.   TETRAHEDRON LETTERS

A Highly Reactive Rhodium(I)-Boryl Complex as a Useful Tool for CH Bond Activation and Catalytic CF Bond Borylation

(2010) Michael Teltewskoi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation

(2010) Vladimir N Boiko   Beilstein Journal of Organic Chemistry

Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex

(2010) Soichiro Kawamorita et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed, Silyl-Directed Borylation of Nitrogen-Containing Heterocycles

(2010) Daniel W. Robbins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex

(2010) Kenji Yamazaki et al.   ORGANIC LETTERS

Selective Activation of theorthoC−F Bond in Pentafluoropyridine by Zerovalent Nickel: Reaction via a Metallophosphorane Intermediate Stabilized by Neighboring Group Assistance from the Pyridyl Nitrogen

(2010) Ainara Nova et al.   ORGANOMETALLICS

CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene

(2009) Thomas Braun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ortho-C–H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium–phosphine complexes

(2009) Tatsuo Ishiyama et al.   CHEMICAL COMMUNICATIONS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Directed Ortho Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine−Iridium System

(2009) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C−H Borylation of Isoindolines

(2009) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The unique role of halogen substituents in the design of modern agrochemicals

(2009) Peter Jeschke   PEST MANAGEMENT SCIENCE

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Computational Study of the Reaction of C6F6with [IrMe(PEt3)3]: Identification of a Phosphine-Assisted C−F Activation Pathway via a Metallophosphorane Intermediate

(2008) Stefan Erhardt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silyl-Directed, Iridium-Catalyzedortho-Borylation of Arenes. A One-Potortho-Borylation of Phenols, Arylamines, and Alkylarenes

(2008) Timothy A. Boebel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Competing C−F Activation Pathways in the Reaction of Pt(0) with Fluoropyridines: Phosphine-Assistance versus Oxidative Addition

(2008) Ainara Nova et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY