Catalyst-Controlled Stereoselective Olefin Metathesis as a Principal Strategy in Multistep Synthesis Design: A Concise Route to (+)-Neopeltolide

Catalytic, Enantioselective Synthesis of 1,2-anti-Diols by Asymmetric Ring-Opening/Cross-Metathesis

(2014) John Hartung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Boron-Substituted Quaternary Carbon Stereogenic Centers through NHC-Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones

(2014) Suttipol Radomkit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Broadly ApplicableZ- and Diastereoselective Ring-Opening/Cross-Metathesis Catalyzed by a Dithiolate Ru Complex

(2014) Ming Joo Koh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis-Based Total Synthesis of Putative Mandelalide A

(2014) Jens Willwacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evolution of Catalytic Stereoselective Olefin Metathesis: From Ancillary Transformation to Purveyor of Stereochemical Identity

(2014) Amir H. Hoveyda   JOURNAL OF ORGANIC CHEMISTRY

Multifunctional organoboron compounds for scalable natural product synthesis

(2014) Fanke Meng et al.   NATURE

Molybdenum-Based Complexes with Two Aryloxides and a Pentafluoroimido Ligand: Catalysts for EfficientZ-Selective Synthesis of a Macrocyclic Trisubstituted Alkene by Ring-Closing Metathesis

(2013) Chenbo Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CatalyticZ-Selective Cross-Metathesis with Secondary Silyl- and Benzyl-Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis

(2013) Tyler J. Mann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient and Selective Formation of Macrocyclic Disubstituted Z Alkenes by Ring-Closing Metathesis (RCM) Reactions Catalyzed by Mo- or W-Based Monoaryloxide Pyrrolide (MAP) Complexes: Applications to Total Syntheses of Epilachnene, Yuzu Lactone, Ambretto

(2013) Chenbo Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Z-Selective and Enantioselective Ring-Opening/Cross-Metathesis Catalyzed by a Resolved Stereogenic-at-Ru Complex

(2013) John Hartung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Active Ruthenium Metathesis Catalysts Exhibiting Unprecedented Activity and Z-Selectivity

(2013) Lauren E. Rosebrugh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Readily Accessible and Easily Modifiable Ru-Based Catalysts for Efficient and Z-Selective Ring-Opening Metathesis Polymerization and Ring-Opening/Cross-Metathesis

(2013) R. Kashif M. Khan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Z-(Pinacolato)allylboron and Z-(Pinacolato)alkenylboron Compounds through Stereoselective Catalytic Cross-Metathesis

(2013) Elizabeth T. Kiesewetter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes

(2013) Erik M. Townsend et al.   ORGANOMETALLICS

Teaching Metathesis "Simple" Stereochemistry

(2013) A. Furstner   SCIENCE

Ruthenium-catalysed Z-selective cross metathesis of allylic-substituted olefins

(2013) Brendan L. Quigley et al.   Chemical Science

Concise Syntheses of Insect Pheromones UsingZ-Selective Cross Metathesis

(2012) Myles B. Herbert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Z- and Enantioselective Ring-Opening/Cross-Metathesis with Enol Ethers Catalyzed by Stereogenic-at-Ru Carbenes: Reactivity, Selectivity, and Curtin–Hammett Kinetics

(2012) R. Kashif M. Khan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enol Ethers as Substrates for Efficient Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes: Utility in Chemical Synthesis and Mechanistic Attributes

(2012) Miao Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes

(2012) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Evans-Tishchenko Reaction: Scope and Applications

(2012) Alison Hulme et al.   SYNTHESIS-STUTTGART

Formal Asymmetric Synthesis of Echinopine A and B

(2011) Philippe A. Peixoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis

(2011) Miao Yu et al.   NATURE

Collective synthesis of natural products by means of organocascade catalysis

(2011) Spencer B. Jones et al.   NATURE

Catalytic Z-selective olefin cross-metathesis for natural product synthesis

(2011) Simon J. Meek et al.   NATURE

Concise Formal Synthesis of (+)-Neopeltolide

(2011) Zhen Yang et al.   ORGANIC LETTERS

A Concise Total Synthesis of (+)-Neopeltolide

(2010) Haruhiko Fuwa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isoquinoline-based chiral monodentate N-heterocyclic carbenes

(2010) Dimitri Hirsch-Weil et al.   CHEMICAL COMMUNICATIONS

Catalytic Enantioselective Olefin Metathesis in Natural Product Synthesis. Chiral Metal-Based Complexes that Deliver High Enantioselectivity and More

(2009) Amir H. Hoveyda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

HighlyZ- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Catalyzed by Stereogenic-at-Mo Adamantylimido Complexes

(2009) Ismail Ibrahem et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of the Antiproliferative Macrolide (+)-Neopeltolide

(2009) Xavier Guinchard et al.   ORGANIC LETTERS

Total Synthesis of (+)-Neopeltolide

(2008) Haruhiko Fuwa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (+)-Neopeltolide by a Prins Macrocyclization

(2008) Sang Kook Woo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Suzuki–Miyaura Cross-Coupling Reactions of Alkylboronic Acid Derivatives or Alkyltrifluoroborates with Aryl, Alkenyl or Alkyl Halides and Triflates

(2008) Henri Doucet   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis

(2008) Steven J. Malcolmson et al.   NATURE

Asymmetric total synthesis of the myxobacteria metabolites crocacins A–D

(2008) John T. Feutrill et al.   TETRAHEDRON

Total Synthesis and Structural Revision of the Marine Macrolide Neopeltolide

(2007) Daniel W. Custar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY