期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 51, 页码 14051-14054出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201407723
关键词
green chemistry; Lindlar reductions; micelles; nanoparticles; semihydrogenation
资金
- NIH [GM 86485]
The addition of NaBH4 to Pd(OAc)(2) in water containing nanomicelles leads to the generation of H-2 and Pd nanoparticles. Subsequent reduction of disubstituted alkynes affords Z-alkenes in high yields. These reactions are general, take place in water at ambient temperatures, and offer recycling of the aqueous reaction mixture along with low overall E Factors.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据