期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 27, 页码 7006-7009出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310923
关键词
bridgehead olefins; crotinsulidanes; EBC-219; natural products; structure eludication
资金
- EcoBiotics Ltd.
- University of Queensland (UQ)
- Australian Research Council
EBC-219 (4), isolated from Croton insularis (Baill), was established by spectroscopic and DFT methods as the first member of a new diterpene skeletal class, uniquely defined by the presence of a bicyclo[10.2.1] bridgehead olefin. The proposed biogenetic pathway to 4 from the co-isolated natural products EBC-131 (1), EBC-180 (2) and EBC-181 (3) is highly likely. EBC-180 (2) and EBC-181 (3) showed moderate to strong cytotoxic activity against various cancer cell lines.
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