Chemoselective Amination of Propargylic C(sp3)H Bonds by Cobalt(II)-Based Metalloradical Catalysis

Unveiling Latent α-Iminocarbene Reactivity for Intermolecular Cascade Reactions through Alkyne Oxidative Amination

(2013) Nina Mace et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CuBr for KA2 reaction: en route to propargylic amines bearing a quaternary carbon center

(2013) Xinjun Tang et al.   CHEMICAL COMMUNICATIONS

Asymmetric synthesis of amines using tert-butanesulfinamide

(2013) Hai-Chao Xu et al.   Nature Protocols

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Copper/Titanium Catalysis Forms Fully Substituted Carbon Centers from the Direct Coupling of Acyclic Ketones, Amines, and Alkynes

(2012) Conor J. Pierce et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective intermolecular C–H amination reactions

(2012) Hélène Lebel et al.   CHEMICAL COMMUNICATIONS

A walk around the A3-coupling

(2012) Vsevolod A. Peshkov et al.   CHEMICAL SOCIETY REVIEWS

Copper(ii) catalysis provides cyclohexanone-derived propargylamines free of solvent or excess starting materials: sole by-product is water

(2012) Conor J. Pierce et al.   GREEN CHEMISTRY

Zinc(II)-Catalyzed Redox Cross-Dehydrogenative Coupling of Propargylic Amines and Terminal Alkynes for Synthesis of N-Tethered 1,6-Enynes

(2012) Tsuyuka Sugiishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Radical Amination of Electron-Deficient C(sp3)–H Bonds by Co(II)-Based Metalloradical Catalysis: Direct Synthesis of α-Amino Acid Derivatives via α-C–H Amination

(2012) Hongjian Lu et al.   ORGANIC LETTERS

Gold-Catalyzed Direct Intermolecular Coupling of Ketones, Secondary Amines, and Alkynes: A Facile and Versatile Access to Propargylic Amines Containing a Quaternary Carbon Center

(2011) Ming Cheng et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Asymmetric Propargylation

(2011) Chang-Hua Ding et al.   CHEMICAL REVIEWS

Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts

(2011) Chi-Ming Che et al.   CHEMICAL SOCIETY REVIEWS

Catalytic C–H amination: the stereoselectivity issue

(2011) Florence Collet et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups

(2011) Thomas A. Ramirez et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Copper-Catalysed Propargylic Substitution: Synthetic Scope Study and Application in Formal Total Syntheses of (+)-Anisomycin and (−)-Cytoxazone

(2011) Remko J. Detz et al.   CHEMISTRY-A EUROPEAN JOURNAL

The radical mechanism of cobalt(ii) porphyrin-catalyzed olefin aziridination and the importance of cooperative H-bonding

(2011) Alma I. Olivos Suarez et al.   DALTON TRANSACTIONS

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation

(2011) Hongjian Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Propargylic and Allenic Carbamates via the C–H Amination of Alkynes

(2011) R. David Grigg et al.   ORGANIC LETTERS

Rhodium-Catalyzed C–H Amination. An Enabling Method for Chemical Synthesis

(2011) J. Du Bois   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Characterization of Tunable Radical Metal–Carbenes: Key Intermediates in Catalytic Cyclopropanation

(2011) Jonathan L. Belof et al.   ORGANOMETALLICS

Chemoselective intramolecular allylic C–H amination versus CC aziridination through Co(ii)-based metalloradical catalysis

(2011) Hongjian Lu et al.   Chemical Science

Mechanism of Cobalt-Porphyrin–Catalyzed Aziridination

(2011) Kathrin H. Hopmann et al.   ACS Catalysis

The Development of Catalytic Nucleophilic Additions of Terminal Alkynes in Water†

(2010) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Selective Intramolecular CH Amination through the Metalloradical Activation of Azides: Synthesis of 1,3-Diamines under Neutral and Nonoxidative Conditions

(2010) Hongjian Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions

(2010) Hongjian Lu et al.   CHEMICAL SOCIETY REVIEWS

‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation

(2010) Wojciech I. Dzik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in transition metal-catalyzed N-atom transfer reactions of azides

(2010) Tom G. Driver   ORGANIC & BIOMOLECULAR CHEMISTRY

Cobalt(II)-Catalyzed Intramolecular C−H Amination with Phosphoryl Azides: Formation of 6- and 7-Membered Cyclophosphoramidates

(2010) Hongjian Lu et al.   ORGANIC LETTERS

Unprecedented Cu(I)-Catalyzed Microwave-Assisted Three-Component Coupling of a Ketone, an Alkyne, and a Primary Amine

(2010) Olga P. Pereshivko et al.   ORGANIC LETTERS

Synthesis of 1,3-Diamines Through Rhodium-Catalyzed CH Insertion

(2009) Toshiki Kurokawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C–H amination: recent progress and future directions

(2009) Florence Collet et al.   CHEMICAL COMMUNICATIONS

The role of sulfamide derivatives in medicinal chemistry: a patent review (2006 – 2008)

(2009) Allen B Reitz et al.   EXPERT OPINION ON THERAPEUTIC PATENTS

π-Nucleophile Traps for Metallonitrene/Alkyne Cascade Reactions: A Versatile Process for the Synthesis of α-Aminocyclopropanes and β-Aminostyrenes

(2009) Aaron R. Thornton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt(II)-Catalyzed Intermolecular Benzylic C−H Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)

(2009) Hongjian Lu et al.   ORGANOMETALLICS

Copper-Catalyzed Coupling of Tertiary Aliphatic Amines with Terminal Alkynes to Propargylamines via C−H Activation

(2008) Mingyu Niu et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Metallonitrene/Alkyne Metathesis: A Powerful Cascade Process for the Synthesis of Nitrogen-Containing Molecules

(2008) Aaron R. Thornton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

A Highly Effective Cobalt Catalyst for Olefin Aziridination with Azides: Hydrogen Bonding Guided Catalyst Design

(2008) Joshua V. Ruppel et al.   ORGANIC LETTERS

Recent Developments in Three-Component Grignard-Barbier-Type Reactions

(2008) Vladimir Kouznetsov et al.   SYNTHESIS-STUTTGART