期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 4, 页码 1289-1292出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410067
关键词
azo coupling; CH activation; dyes; carbenes; nitrous oxide
资金
- Ecole Polytechnique Federale de Lausanne (EPFL)
- Swiss National Science Foundation
A new method for the synthesis of industrially important azoimidazolium dyes is presented. The procedure is based on a reagent which is rarely used in the context of synthetic organic chemistry: nitrous oxide (laughing gas). N2O is first coupled to N-heterocyclic carbenes. Subsequent reaction with aromatic compounds through an AlCl3-induced CH activation process provides azoimidazolium dyes in good yields.
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