Controlling the Molecular Topology of Vinylogous Iminium Ions by Logical Substrate Design: Highly Regio- and Stereoselective Aminocatalytic 1,6-Addition to Linear 2,4-Dienals

Control of Remote Stereochemistry in the Synthesis of Spirocyclic Oxindoles: Vinylogous Organocascade Catalysis

(2013) Xu Tian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic asymmetric remote aziridination of 2,4-dienals

(2013) Kim Søholm Halskov et al.   CHEMICAL COMMUNICATIONS

When asymmetric aminocatalysis meets the vinylogy principle

(2013) Igor D. Jurberg et al.   CHEMICAL COMMUNICATIONS

Prediction of Catalyst and Substrate Performance in the Enantioselective Propargylation of Aliphatic Ketones by a Multidimensional Model of Steric Effects

(2013) Kaid C. Harper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Beyond Classical Reactivity Patterns: Shifting from 1,4- to 1,6-Additions in Regio- and Enantioselective Organocatalyzed Vinylogous Reactions of Olefinic Lactones with Enals and 2,4-Dienals

(2013) Luca Dell’Amico et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aminocatalytic remote functionalization strategies

(2013) Hao Jiang et al.   Chemical Science

Asymmetric Catalysis for the Synthesis of Spirocyclic Compounds

(2013) Annaliese K. Franz et al.   ACS Catalysis

Aminocatalytic Enantioselective 1,6 Additions of Alkyl Thiols to Cyclic Dienones: Vinylogous Iminium Ion Activation

(2012) Xu Tian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Oxidative Macrolactonization: Total Synthesis of (+)-Dactylolide

(2012) Kiyoun Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic 1,4-Addition Reaction of α,β-γ,δ-Diunsaturated Aldehydes versus 1,6-Addition Reaction

(2012) Yujiro Hayashi et al.   ChemCatChem

Dioxindole in asymmetric catalytic synthesis: direct access to 3-substituted 3-hydroxy-2-oxindoles via 1,4-additions to nitroalkenes

(2012) Michele Retini et al.   CHEMICAL COMMUNICATIONS

Secondary Amine-Catalyzed Asymmetricγ-Alkylation ofα-Branched EnalsviaDienamine Activation

(2012) Mattia Silvi et al.   HELVETICA CHIMICA ACTA

Highly Regio-, Diastereo-, and Enantioselective 1,6- and 1,8-Additions of Azlactones to Di- and Trienyl N-Acylpyrroles

(2012) Daisuke Uraguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinuclear Zinc Catalyzed Asymmetric Spirannulation Reaction: An Umpolung Strategy for Formation of α-Alkylated-α-Hydroxyoxindoles

(2012) Barry M. Trost et al.   ORGANIC LETTERS

The Diarylprolinol Silyl Ether System: A General Organocatalyst

(2011) Kim L. Jensen et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Novel Entry to Spirofurooxindoles Involving Tandem Dearomatization of Furan Ring and Intramolecular Friedel- Crafts Reaction

(2011) Biao-Lin Yin et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Organocatalytic 1,6-Conjugate Addition of Aldehydes to Dienic Sulfones

(2011) John J. Murphy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric [3+2] Annulation of Allylsilanes with Isatins: Synthesis of Spirooxindoles

(2011) Nadine V. Hanhan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dioxindole in Asymmetric Catalytic Synthesis: Routes to Enantioenriched 3-Substituted 3-Hydroxyoxindoles and the Preparation of Maremycin A

(2011) Giulia Bergonzini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery of XEN907, a spirooxindole blocker of NaV1.7 for the treatment of pain

(2011) Sultan Chowdhury et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Highly Efficient Hydrogen-Bonding Catalysis of the Diels–Alder Reaction of 3-Vinylindoles and Methyleneindolinones Provides Carbazolespirooxindole Skeletons

(2011) Bin Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalysis of Diels–Alder Reactions with in Situ Generated Heterocyclicortho-Quinodimethanes

(2011) Yankai Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trienamines in Asymmetric Organocatalysis: Diels−Alder and Tandem Reactions

(2011) Zhi-Jun Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Three-Dimensional Correlation of Steric and Electronic Free Energy Relationships Guides Asymmetric Propargylation

(2011) K. C. Harper et al.   SCIENCE

Distinct conformational preferences of prolinol and prolinol ether enamines in solution revealed by NMR

(2011) Markus B. Schmid et al.   Chemical Science

Catalytic Asymmetric Synthesis of Oxindoles Bearing a Tetrasubstituted Stereocenter at the C-3 Position

(2010) Feng Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

Fluoro-Organocatalysts: Conformer Equivalents as a Tool for Mechanistic Studies

(2010) Christof Sparr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereochemical Models for Discussing Additions toα,β-Unsaturated Aldehydes Organocatalyzed by Diarylprolinol or Imidazolidinone Derivatives - Is There an‘(E)/(Z)-Dilemma’?

(2010) Dieter Seebach et al.   HELVETICA CHIMICA ACTA

Organocatalytic cascade reactions as a new tool in total synthesis

(2010) Christoph Grondal et al.   Nature Chemistry

Targeting Structural and Stereochemical Complexity by Organocascade Catalysis: Construction of Spirocyclic Oxindoles Having Multiple Stereocenters

(2009) Giorgio Bencivenni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Syntheses of Oxindole and Indole Spirocyclic Alkaloid Natural Products

(2009) Barry Trost et al.   SYNTHESIS-STUTTGART

Transmission of stereochemical information over nanometre distances in chemical reactions

(2008) Jonathan Clayden   CHEMICAL SOCIETY REVIEWS