Chemical Tricks To Stabilize Silanones and Their Heavier Homologues with EO Bonds (E=Si-Pb): From Elusive Species to Isolable Building Blocks

Donor–acceptor stabilized silaformyl chloride

(2012) Rajendra S. Ghadwal et al.   CHEMICAL COMMUNICATIONS

Synthesis and Tunable Reactivity of N-Heterocyclic Germylene

(2012) Yun Xiong et al.   Chemistry-An Asian Journal

A stable germanone as the first isolated heavy ketone with a terminal oxygen atom

(2012) Liangchun Li et al.   Nature Chemistry

Synthesis, Structure, and Reactivity of a Pyridine-Stabilized Germanone

(2011) Shenglai Yao et al.   CHEMISTRY-A EUROPEAN JOURNAL

From a Stable Silanone Complex to Isolable, Donor-Supported Silicoxonium Halides [LSi(dmap)OSiMe3]+X−

(2011) Yun Xiong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactions of Stable Amidinate Chlorosilylene and [1+4]-Oxidative Addition of N-Heterocyclic Silylene with N-Benzylideneaniline

(2011) Anukul Jana et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of a Base-Stabilized Silanone-Coordinated Complex by Oxygenation of a (Silyl)(silylene)tungsten Complex

(2011) Takako Muraoka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride

(2011) Rajendra S. Ghadwal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Chemistry of functionalized silylenes

(2011) Sakya S. Sen et al.   Chemical Science

Silicon Analogues of Carboxylic Acids: Synthesis of Isolable Silanoic Acids by Donor-Acceptor Stabilization

(2010) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of a Stable Disilyne Bisphosphine Adduct and Its Non-Metal-Mediated CO2 Reduction to CO

(2010) David Gau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Coordination of a SiO subunit to metals: complexes of donor-stabilized silanone featuring a terminal SiO→M coordination (M = Zn, Al)

(2010) Yun Xiong et al.   DALTON TRANSACTIONS

Activation of Ammonia by a Si═O Double Bond and Formation of a Unique Pair of Sila-Hemiaminal and Silanoic Amide Tautomers

(2010) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Si═X Multiple Bonding with Four-Coordinate Silicon? Insights into the Nature of the Si═O and Si═S Double Bonds in Stable Silanoic Esters and Related Thioesters: A Combined NMR Spectroscopic and Computational Study

(2010) Jan. D. Epping et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature

(2010) Yun Xiong et al.   Nature Chemistry

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From NHC→germylenes to stable NHC→germanone complexes

(2009) Shenglai Yao et al.   CHEMICAL COMMUNICATIONS

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene (NHC)-Stabilized Silanechalcogenones: NHC→Si(R2)E (E=O, S, Se, Te)

(2009) Shenglai Yao et al.   CHEMISTRY-A EUROPEAN JOURNAL

The effect of local environment on photoluminescence: A time-dependent density functional theory study of silanone groups on the surface of silica nanostructures

(2009) M. A. Zwijnenburg et al.   JOURNAL OF CHEMICAL PHYSICS

An Isolable NHC-Supported Silanone

(2009) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trapping of Tin(II) and Lead(II) Homologues of Carbon Monoxide by a Benzannulated Lutidine-Bridged Bisstannylene

(2008) Alexander V. Zabula et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CHEMISTRY: Soluble Allotropes of Main-Group Elements

(2008) C. A. Dyker et al.   SCIENCE

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE