期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 3, 页码 875-878出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201308816
关键词
cobalamins; drug delivery; energy transfer; fluorescence; photochemistry
资金
- National Institutes of Health [RO1 CA79954]
Although the corrin ring of vitamin B-12 is unable to efficiently absorb light beyond 550 nm, it is shown that commercially available fluorophores can be used as antennas to capture long-wavelength light to promote scission of the Co-C bond at wavelengths up to 800 nm. The ability to control the molecular properties of bioactive species with long visible and near-IR light has implications for drug delivery, nanotechnology, and the spatiotemporal control of cellular behavior.
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