Rhodium-Catalyzed Three-Component Cross-Addition of Silylacetylenes, Alkynyl Esters, and Electron-Deficient Alkenes or Isocyanates

Catalytic [2+2+1] Cross-Cyclotrimerization of Silylacetylenes and Two Alkynyl Esters To Produce Substituted Silylfulvenes

(2011) Yu Shibata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones

(2011) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

Expedient Synthesis ofN-Acyl Anthranilamides and β-Enamine Amides by the Rh(III)-Catalyzed Amidation of Aryl and Vinyl C–H Bonds with Isocyanates

(2011) Kevin D. Hesp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes

(2010) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

Cationic Rhodium(I) Complex-Catalyzed Cotrimerization of Propargyl Esters and Arylacetylenes Leading to Substituted Dihydropentalenes

(2010) Yu Shibata et al.   ORGANIC LETTERS

Highly Chemoselective Nickel-Catalyzed Three-Component Cross-Trimerization between Two Distinct Terminal Alkynes and an Internal Alkyne

(2010) Kenichi Ogata et al.   ORGANIC LETTERS

Rhodium-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes

(2010) Xun-Xiang Guo et al.   TETRAHEDRON-ASYMMETRY

The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups

(2009) Barry M. Trost et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Three-Component 1:2:1 Coupling of Aryl Iodides, Alkynes, and Alkenes to Produce 1,3,5-Hexatriene Derivatives

(2009) Hakaru Horiguchi et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Chemoselective Nickel-Catalyzed Three-Component Cross-Trimerization of Three Distinct Alkynes Leading to 1,3-Dien-5-ynes

(2009) Kenichi Ogata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of β-Alkynyl Aldehydes by Rhodium-Catalyzed Conjugate Alkynylation

(2009) Takahiro Nishimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel- and Rhodium-Catalyzed Addition of Terminal Silylacetylenes to Propargyl Amines: Catalyst-Dependent Complementary Regioselectivity

(2009) Naoto Matsuyama et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Highly Regio- and Stereoselective Cross-Trimerization between Triisopropylsilylacetylene and Internal Alkynes Leading to 1,3-Diene-5-ynes

(2009) Kenichi Ogata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fe(OTf)3-Catalyzed Addition of sp C−H Bonds to Olefins

(2009) Kazufumi Kohno et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed, Regio- and Stereoselective Hydroalkynylation of Methylenecyclopropanes with Retention of the Cyclopropane Ring, Leading to the Synthesis of 1-Methyl-1-Alkynylcyclopropanes

(2009) Masamichi Shirakura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium-Catalyzed Conjugate Alkynylation of 5-Benzylidene Meldrum’s Acids with TMS-acetylene

(2009) Eric Fillion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Regioselective Hydroalkynylation of Styrenes: Improved Catalyst System, Reaction Scope, and Mechanism

(2009) Masamichi Shirakura et al.   ORGANIC LETTERS

Nickel-Catalyzed Highly Chemo-, Regio-, and Stereoselective Three-Component Reaction of Norbornene with Two Alkynes

(2009) Kenichi Ogata et al.   ORGANIC LETTERS

Ligand-Controlled Cross-Dimerization and -Trimerization of Alkynes under Nickel Catalysis

(2008) Naoto Matsuyama et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-catalyzed (E)-selective cross-dimerization of terminal alkynes

(2008) Takashi Katagiri et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Asymmetric Addition of Terminal Alkynes to Diarylphosphinylallenes

(2008) Takahiro Nishimura et al.   Chemistry-An Asian Journal

Nickel-Catalyzed Addition of C−H Bonds of Terminal Alkynes to 1,3-Dienes and Styrenes

(2008) Masamichi Shirakura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Steric Tuning of Silylacetylenes and Chiral Phosphine Ligands for Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones

(2008) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphine-Dependent Selective Cross-Dimerization between Terminal Alkylacetylene and Silylacetylene by Iridium(I) Guanidinate Complex-Phosphine System

(2008) Kenichi Ogata et al.   SYNLETT

Hydroarylation of acetylenes, acrylates, and isocyanates with heteroaromatic compounds under rhenium catalysis

(2008) Yoichiro Kuninobu et al.   TETRAHEDRON