Zintl Ions, Cage Compounds, and Intermetalloid Clusters of Group 14 and Group 15 Elements

[(MesCu)2(η3-Si4)]4−: A Mesitylcopper-Stabilized Tetrasilicide Tetraanion

(2010) Markus Waibel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Eu@Sn6Bi8]4−: A Mini-Fullerane-Type Zintl Anion Containing a Lanthanide Ion

(2010) Felicitas Lips et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Ag(Sn9Sn9)]5−: A Homoleptic Silver Complex of A Dimeric Sn9 Zintl Anion

(2010) Jian-Qiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Step-by-Step Synthesis of the Endohedral Stannaspherene [Ir@Sn12]3−via the Capped Cluster Anion [Sn9Ir(cod)]3−

(2010) Jian-Qiang Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Thecloso-[Sn9Ir(cod)]3-and [Pb9Ir(cod)]3-Zintl Ions: Isostructural IrIDerivatives of thenido-E94-Anions (E = Sn, Pb)

(2010) Domonique O. Downing et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Varying Bonding Modes of the Zintl Ion [Ge9]4-in CuIComplexes: Syntheses and Structures of [Cu(η4-Ge9)(PR3)]3-(R =iPr, Cy) and [Cu(η4-Ge9)(η1-Ge9)]7-

(2010) Sandra Scharfe et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The Elusivecloso-Ge102−Zintl Ion: Finally “Captured” as a Ligand in the Complex [Ge10Mn(CO)4]3−

(2010) Daniel Rios et al.   INORGANIC CHEMISTRY

Polyhedral nine-atom clusters of tetrel elements and intermetalloid derivatives

(2010) S. Scharfe et al.   PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

[Zn6Sn3Bi8]4−: Expanding the Intermetalloid Zintl Anion Concept to Ternary Systems

(2009) Felicitas Lips et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemistry with Bare Silicon Clusters in Solution: A Transition-Metal Complex of a Polysilicide Anion

(2009) Stefanie Joseph et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Co@Ge10]3−: An Intermetalloid Cluster with Archimedean Pentagonal Prismatic Structure

(2009) Jian-Qiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Pb9CdCdPb9]6−: A Zintl cluster anion with an unsupported cadmium–cadmium bond

(2009) Binbin Zhou et al.   CHEMICAL COMMUNICATIONS

Substituent-dependent exchange mechanisms in highly fluxional RSn93− anions

(2009) F. Sanem Kocak et al.   CHEMICAL COMMUNICATIONS

{Ge9R3Cr(CO)5}− and {Ge9R3Cr(CO)3}−: a metalloid cluster (Ge9R3−) as a flexible ligand in coordination chemistry [R = Si(SiMe3)3]

(2009) Christian Schenk et al.   CHEMICAL COMMUNICATIONS

Reductive cleavage of Zn–C bonds by group 14 Zintl anions: synthesis and characterisation of [E9ZnR]3− (E = Ge, Sn, Pb; R = Mes, iPr)

(2009) Binbin Zhou et al.   DALTON TRANSACTIONS

[Si(SiMe3)3]6Ge18M (M = Zn, Cd, Hg): neutral metalloid cluster compounds of germanium as highly soluble building blocks for supramolecular chemistry

(2009) Florian Henke et al.   DALTON TRANSACTIONS

The formation of a metalloid Sn10[Si(SiMe3)3]6cluster compound and its relation to the α↔β tin phase transition

(2009) Claudio Schrenk et al.   DALTON TRANSACTIONS

Reactivity studies of group 15 Zintl ions towards homoleptic post-transition metal organometallics: a ‘bottom-up’ approach to bimetallic molecular clusters

(2009) Caroline Knapp et al.   DALTON TRANSACTIONS

Synthesis of the Clathrate-II K8.6(4)Ge136by Oxidation of K4Ge9in an Ionic Liquid

(2009) Arnold M. Guloy et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Si94-Anions in Solution - Structures of the Solvates Rb4Si9·4.75NH3and [Rb(18-crown-6)]Rb3Si9·4NH3, and Chemical Bonding in Si94-

(2009) Stefanie Joseph et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Hydrogen Polyphosphides P3H23−and P3H32−: Synthesis and Crystal Structure of K3(P3H2)·2.3NH3, Rb3(P3H2)·NH3, [Rb(18-crown-6)]2(P3H3)·7.5NH3, and [Cs(18-crown-6)]2(P3H3)·7NH3

(2009) Florian Kraus et al.   INORGANIC CHEMISTRY

{[Ga(en)3]2(Ge2Te15)}n: A Polymeric Semiconducting Polytelluride with Boat-Shaped Te84−Rings and Cross-Shaped Te56−Units

(2009) Qichun Zhang et al.   INORGANIC CHEMISTRY

Heteroatomic Deltahedral Zintl Ions of Group 14 and their Alkenylation

(2009) Miriam M. Gillett-Kunnath et al.   INORGANIC CHEMISTRY

Diversity of Functionalized Germanium Zintl Clusters: Syntheses and Theoretical Studies of [Ge9PdPPh3]3− and [Ni@(Ge9PdPPh3)]2−

(2009) Zhong-Ming Sun et al.   JOURNAL OF CLUSTER SCIENCE

[{(η5-C5Me5)2Sm}4P8]: A Molecular Polyphosphide of the Rare-Earth Elements

(2009) Sergey N. Konchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Properties and Reactivity Patterns of AsP3: An Experimental and Computational Study of Group 15 Elemental Molecules

(2009) Brandi M. Cossairt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functionalization of Nine-Atom Deltahedral Zintl Ions with Organic Substituents: Detailed Studies of the Reactions

(2009) Michael W. Hull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Isolation of [Fe@Ge10]3−: A Pentagonal Prismatic Zintl Ion Cage Encapsulating an Interstitial Iron Atom

(2009) Binbin Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Synthesis of AsP3

(2009) B. M. Cossairt et al.   SCIENCE

Tetrahedral [Tt4]4-Zintl Anions Through Solution Chemistry: Syntheses and Crystal Structures of the Ammoniates Rb4Sn4·2NH3, Cs4Sn4·2NH3, and Rb4Pb4·2NH3

(2009) Katharina Wiesler et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

High-Surface-Area Mesoporous Germanium from Oxidative Polymerization of the Deltahedral [Ge9]4– Cluster: Electronic Structure Modulation with Donor and Acceptor Molecules

(2008) G. S. Armatas et al.   ADVANCED MATERIALS

[Sn17{GaCl(ddp)}4]: A High-Nuclearity Metalloid Tin Cluster Trapped by Electrophilic Gallium Ligands

(2008) Ganesan Prabusankar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of [Ph2P5]+, [Ph4P6]2+, and [Ph6P7]3+Cationic Clusters by Consecutive Insertions of [Ph2P]+into PP Bonds of the P4Tetrahedron

(2008) Jan J. Weigand et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Polyhedral Structures with Three-, Four-, and Five Fold Symmetry in Metal-Centered Ten-Vertex Germanium Clusters

(2008) R. Bruce King et al.   CHEMISTRY-A EUROPEAN JOURNAL

[Cu@Sn9]3− and [Cu@Pb9]3−: Intermetalloid Clusters with Endohedral Cu Atoms in Spherical Environments

(2008) Sandra Scharfe et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Molecular Cage Clusters of Pb by Encapsulation of Mg

(2008) Sascha Schäfer et al.   CHEMPHYSCHEM

The role of “external” lone pairs in the chemical bonding of bare post-transition element clusters: the Wade–Mingos rules versus the jellium model

(2008) R. B. King et al.   DALTON TRANSACTIONS

[Hg3(Ge9)4]10−: a nanometric molecular rod precursor to polymeric mercury-linked cluster chains

(2008) Mark S. Denning et al.   DALTON TRANSACTIONS

Formation, structure and bonding of metalloid Al and Ga clusters. A challenge for chemical efforts in nanosciences

(2008) Hansgeorg Schnöckel   DALTON TRANSACTIONS

[Si(SiMe3)3]6Ge18M (M = Cu, Ag, Au): metalloid cluster compounds as unusual building blocks for a supramolecular chemistry

(2008) Christian Schenk et al.   DALTON TRANSACTIONS

Metalloid Cluster Compounds of Germanium: Synthesis – Properties – Subsequent Reactions

(2008) Andreas Schnepf   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A4Ge9(A = K, Rb) as Precursors for Hg-Substituted Clathrate-I Synthesis: Crystal Structure of A8Hg3Ge43

(2008) Andreas Kaltzoglou et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Solution Dynamics and Gas-Phase Chemistry of Pd2@Sn184−

(2008) F. Sanem Kocak et al.   INORGANIC CHEMISTRY

Tin-Based Organo-Zintl Ions: Alkylation and Alkenylation of Sn94−

(2008) Donald J. Chapman et al.   INORGANIC CHEMISTRY

Structure and electronic properties of PbnM (M=C, Al, In, Mg, Sr, Ba, and Pb; n=8, 10, 12, and 14) clusters: Theoretical investigations based on first principles calculations

(2008) Chinagandham Rajesh et al.   JOURNAL OF CHEMICAL PHYSICS

Search for lowest-energy structure of Zintl dianion Si122−, Ge122−, and Sn122−

(2008) Nan Shao et al.   JOURNAL OF CHEMICAL PHYSICS

Aerogels from metal chalcogenides and their emerging unique properties

(2008) Santanu Bag et al.   JOURNAL OF MATERIALS CHEMISTRY

Endohedral Nickel, Palladium, and Platinum Atoms in 10-Vertex Germanium Clusters: Competition between Bicapped Square Antiprismatic and Pentagonal Prismatic Structures

(2008) R. B. King et al.   JOURNAL OF PHYSICAL CHEMISTRY A

P2Addition to Terminal Phosphide MP Triple Bonds: A Rational Synthesis ofcyclo-P3Complexes

(2008) Nicholas A. Piro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Reactive Niobium Phosphinidene P8 Cluster Obtained by Reductive Coupling of White Phosphorus

(2007) Brandi M. Cossairt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION