☆ 4.8 Article

A Compartmental borromean weave coordination polymer exhibiting saturated hydrogen bonding to anions and water cluster inclusion

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

期刊

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

卷 47, 期 31, 页码 5761-5764

出版社

WILEY-V C H VERLAG GMBH

DOI: 10.1002/anie.200801556

关键词

anion binding; coordination modes; coordination polymers; crystal engineering; secondary building units

类别

Chemistry, Multidisciplinary

向作者/读者索取更多资源

Protocol

Reagent

作者

我是这篇论文的作者

点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8

评分不足

次要评分

新颖性

-

重要性

-

科学严谨性

-

评价这篇论文

推荐

Article Chemistry, Inorganic & Nuclear

Integration of Trinuclear Triangle Copper(II) Secondary Building Units in Octacyanidometallates(IV)-Based Frameworks

Olaf Stefanczyk, Kunal Kumar, TingYun Pai, Guanping Li, Shin-ichi Ohkoshi

Summary: The design and synthesis of high-dimensional materials based on secondary building blocks (SBUs) are crucial for the development of functional molecular materials. This study presents the synthesis of two new isostructural three-dimensional systems and investigates their magnetic and optical properties.

INORGANIC CHEMISTRY (2022)

添加到收藏夹

Review Chemistry, Physical

Metal-organic frameworks based on infinite secondary building units: recent progress and future outlooks

Jun Guo, Xiaomin Xue, Haibin Yu, Yulong Duan, Fangfang Li, Ye Lian, Yi Liu, Meiting Zhao

Summary: Metal-organic frameworks (MOFs) are inorganic-organic hybrids composed of organic ligands and discrete metal ions/metallic secondary building units (SBUs). MOFs based on infinite SBUs (ISBUs) have shown unique physical and chemical properties. This review summarizes the synthesis methods and crystallographic structures of various ISBU MOFs, compares their properties with traditional MOFs, and highlights recent progress in gas adsorption and separation, energy conversion, photocatalysis, etc.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Pyrogallate-Based Metal-Organic Framework with a Two-Dimensional Secondary Building Unit

Stavroula Kampouri, Mingxuan Zhang, Tianyang Chen, Julius J. Oppenheim, Alexandra C. Brown, Michael T. Payne, Justin L. Andrews, Junliang Sun, Mircea Dinca

Summary: This study presents a metal-organic framework with a rare two-dimensional secondary building unit, which demonstrates strong electronic communication and rare topology. These results emphasize the importance of dimensionality control in discovering new topologies in reticular chemistry and improving electronic communication within MOF structures.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Metal-organic frameworks of linear trinuclear cluster secondary building units: structures and applications

Meng-Yao Chao, Qing Li, Wen-Hua Zhang, David J. Young

Summary: Secondary building units in metal-organic frameworks, such as the linear trinuclear SBUs denoted as M-3, are essential both structurally and in terms of performance. While M-3 clusters are common, they are rarely discussed as a class and exhibit unprecedented metal diversity and ligand tolerance. Some M-3-based MOFs are stable under demanding conditions and can be used in applications like flue gas separation.

DALTON TRANSACTIONS (2021)

添加到收藏夹

Article Chemistry, Physical

Metal-organic frameworks with mixed-anion secondary building units as efficient photocatalysts for hydrogen generation

Donglei Bu, Duocheng Bu, Wei Chen, Changgeng Huang, Libo Li, Hao Lei, Shaoming Huang

Summary: Three new Cu-X-bpy (X = Cl/Br, Cl/I or Br/I) photocatalytic materials were synthesized and their hydrogen production performance was systematically investigated. It was found that the hydrogen productivity can be significantly enhanced by varying the anions in the materials.

JOURNAL OF CATALYSIS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Tetravalent Plutonium Organic Framework Containing [Pu2O16] Dimers as Secondary Building Units: Synthesis, Structure, and Radiation Stability

Yugang Zhang, Yingzhe Du, Lili Li, Ye Tao, Kai Li, Hailong Zhang, Yanlong Wang, Lanhua Chen, Yaxing Wang, Zhifang Chai, Shuao Wang

Summary: The second example of tetravalent plutonium carboxyl-based organic framework, PuTPO, is reported in this study. Characterizations such as X-ray crystallography and solid-state UV-Vis-NIR spectroscopy were conducted to elucidate its structure and physicochemical properties. PuTPO is composed of dimers of the plutonium-oxygen subunit of [Pu2O16]. The characteristic peaks around 1100 nm can be considered as the fingerprint peaks of tetravalent plutonium. PuTPO exhibits a radiation-induced swelling effect after self-irradiation, indicating its potential in radiation resistance for metal-organic frameworks.

CHINESE JOURNAL OF CHEMISTRY (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

New Reticular Chemistry of the Rod Secondary Building Unit: Synthesis, Structure, and Natural Gas Storage of a Series of Three-Way Rod Amide-Functionalized Metal-Organic Frameworks

Yu-Feng Zhang, Zong-Hui Zhang, Logan Ritter, Han Fang, Qian Wang, Brian Space, Yue-Biao Zhang, Dong-Xu Xue, Junfeng Bai

Summary: By innovating the structure design of rod MOFs, a complex three-way rod MOF and its variants have been successfully achieved, showing impressive methane storage working capacities due to the presence of favorable pocket sites created by X, ketone, and proximal amide groups.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

The Impact of Secondary Building Units in Metal-Organic Frameworks on Plasmonic Gold-Sensitized Photocatalysis

Qian-Qian Huang, Zhi-Bin Fang, Kuan Pang, Wei-Kang Qin, Tian-Fu Liu, Rong Cao

Summary: This study demonstrates the construction of an advanced visible-light photocatalyst architecture by embedding plasmonic metals in metal-organic frameworks. The optimized catalyst achieved the best activity for visible-light-driven hydrogen production. This research provides significant guidance for the rational design of highly efficient photocatalysts.

ADVANCED FUNCTIONAL MATERIALS (2022)

添加到收藏夹

Article Biochemistry & Molecular Biology

2D Porphyrinic Metal-Organic Frameworks Featuring Rod-Shaped Secondary Building Units

Rory Elliott, Aoife A. Ryan, Aviral Aggarwal, Nianyong Zhu, Friedrich W. Steuber, Mathias O. Senge, Wolfgang Schmitt

Summary: Metal-organic frameworks (MOFs) are a rapidly expanding class of materials with diverse potential applications, with 'rod MOFs' representing an underexplored subclass. In this study, two new 2D porphyrinic rod MOFs, PROD-1 and PROD-2, were prepared using a Cu-II complex, showcasing promising structural attributes for future photocatalytic investigations.

MOLECULES (2021)

添加到收藏夹

Editorial Material Chemistry, Multidisciplinary

Enhanced Host-Guest Association and Fluorescence in Copolymers from Copper Salphen Complexes by Supramolecular Internalization of Anions

Paulina Hernandez-Pacheco, Gustavo A. Zelada-Guillen, Margarita Romero-Avila, Roberto Carlos Canas-Alonso, Marcos Flores-Alamo, Martha V. Escarcega-Bobadilla

Summary: We synthesized and characterized a new Cu-Salphen compound, which acted as a Lewis acid to host guest anions in two different forms: a) free molecule, and b) copolymerized with protective co-monomers. Higher amounts of Cu-Salphen resulted in larger and more homogeneous polymer sizes. The polymer size, along with other factors such as glass transitions, heat capacity, thermal degradation, and host-guest species distribution, explained significant enhancements in the host's binding site.

CHEMPLUSCHEM (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enhanced Host-Guest Association and Fluorescence in Copolymers from Copper Salphen Complexes by Supramolecular Internalization of Anions

Paulina Hernandez-Pacheco, Gustavo A. Zelada-Guillen, Margarita Romero-Avila, Roberto Carlos Canas-Alonso, Marcos Flores-Alamo, Martha Escarcega-Bobadilla

Summary: In this study, the synthesis and crystallographic characterization of a new Cu-Salphen compound and its use as a Lewis acid against guest anions were described. It was found that higher contents of Cu-Salphen resulted in larger and more homogeneous polymer sizes. The growth of the host's binding site was explained by factors such as polymer size, glass transitions, heat capacity, thermal degradation, guest-saturation degrees, and host-guest species distribution profiles. Spectrofluorimetry measurements showed that Cu-Salphen had larger blue-shifted luminescence in the polymers compared to the non-polymerized counterpart, and enhanced fluorescence upon guest association. A cooperative incorporation of the guests into the internally protected binding site pockets in the random coil polymer conformations was proposed.

CHEMPLUSCHEM (2023)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Phosphinic acids as building units in materials chemistry

Matous Kloda, Sona Ondrusova, Kamil Lang, Jan Demel

Summary: This review summarizes the synthesis methods and functions of diaryl and dialkyl phosphinic acids as ligands in materials chemistry, highlighting their unique properties and diverse applications. Recent developments and future research directions in the field are also emphasized.

COORDINATION CHEMISTRY REVIEWS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Machine-Learning-Assisted Selective Synthesis of a Semiconductive Silver Thiolate Coordination Polymer with Segregated Paths for Holes and Electrons

Takuma Wakiya, Yoshinobu Kamakura, Hiroki Shibahara, Kazuyoshi Ogasawara, Akinori Saeki, Ryosuke Nishikubo, Akihiro Inokuchi, Hirofumi Yoshikawa, Daisuke Tanaka

Summary: The study optimized the synthesis of semiconductor coordination polymers based on trithiocyanuric acid using machine learning, and identified a CP with excellent photoconductivity in its structure.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Nucleophilic addition reactions to nitrilium derivatives [B12H11NCCH3]- and [B12H11NCCH2CH3]-. Synthesis and structures of closo-dodecaborate-based iminols, amides and amidines

Julia Laskova, Ivan Ananiev, Irina Kosenko, Alexander Serdyukov, Marina Stogniy, Igor Sivaev, Mikhail Grin, Andrey Semioshkin, Vladimir Bregadze

Summary: The synthesis of acetonitrilium and propionitrilium derivatives of closo-dodecaborate [B12H12](2-) was discussed. Nucleophilic addition reactions of water, alcohols, and secondary amines to the activated triple bond of the nitrilium derivatives yielded corresponding iminols, imidates, and amidines. The obtained results were supported by X-ray diffraction studies and DFT calculations.

DALTON TRANSACTIONS (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Using Postsynthetic X-Type Ligand Exchange to Enhance CO2 Adsorption in Metal-Organic Frameworks with Kuratowski-Type Building Units

Caitlin E. Bien, Zhongzheng Cai, Casey R. Wade

Summary: Postsynthetic modification methods, particularly PXLE, have been shown to be effective in introducing new functional groups to metal-organic frameworks, improving properties such as CO2 adsorption.

INORGANIC CHEMISTRY (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Biofunctionality with a twist: the importance of molecular organisation, handedness and configuration in synthetic biomaterial design

Simone I. S. Hendrikse, Rafael Contreras-Montoya, Amanda Ellis, Pall Thordarson, Jonathan W. Steed

Summary: The fundamental building blocks of life, such as nucleotides, amino acids, and saccharides, form various components and hierarchical structures in nature. Mimicking these biological systems and incorporating order and handedness into biomaterial design is necessary, with computational simulations playing a key role in improving biomaterial designs.

CHEMICAL SOCIETY REVIEWS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

The Magic Linker: Highly Effective Gelation from Sterically Awkward Packing

James P. Smith, Dmitry S. Yufit, James F. McCabe, Jonathan W. Steed

Summary: The single crystal structure of a bis(urea) based on the 4,4'-MDEP spacer is reported in this study, indicating its effectiveness as a high-efficiency low molecular weight gelator. The compound exhibits various conformations, which are closely related to its gelation behavior.

CRYSTAL GROWTH & DESIGN (2022)

添加到收藏夹

Article Biochemistry & Molecular Biology

Anion-Responsive Fluorescent Supramolecular Gels

Giacomo Picci, Matthew T. Mulvee, Claudia Caltagirone, Vito Lippolis, Antonio Frontera, Rosa M. Gomila, Jonathan W. Steed

Summary: This article reports on three novel bis-urea fluorescent low-molecular-weight gelators that can form gels in different solvents. The study also shows the impact of anions on gel formation.

MOLECULES (2022)

添加到收藏夹

Editorial Material Chemistry, Multidisciplinary

Crystallizing the Role of Solid-State Form in Drug Delivery

Lynne S. Taylor, Doris E. Braun, Lidia Tajber, Jonathan W. Steed

CRYSTAL GROWTH & DESIGN (2022)

添加到收藏夹

Article Medicine, Research & Experimental

Prediction and Preparation of Coamorphous Phases of a Bislactam

Luke Chambers, Osama M. Musa, Jonathan W. Steed

Summary: The effectiveness of a partial least squares-discriminant analysis coamorphous prediction model was tested using coamorphous screening data. The model showed a prediction accuracy of 71% for coamorphous systems and 85% for experimental coamorphous screening. The model also performed well with small-molecule coformers.

MOLECULAR PHARMACEUTICS (2022)

添加到收藏夹

Editorial Material Medicine, Research & Experimental

Crystallizing the Role of Solid-State Form in Drug Delivery

Lynne S. Taylor, Doris E. Braun, Lidia Tajber, Jonathan W. Steed

MOLECULAR PHARMACEUTICS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Understanding the Interaction of Gluconamides and Gluconates with Amino Acids in Hair Care

Luke I. Chambers, Dmitry S. Yufit, Osama M. Musa, Jonathan W. Steed

Summary: This research investigates the mechanism by which a hair care mixture strengthens hair fibers through studying the different forms of the target gluconamide and the interactions between the gluconate-derived mixture and hair fibers. The study reveals that the gluconamide can aggregate and become a supramolecular gelator in aniline and benzyl alcohol solution.

CRYSTAL GROWTH & DESIGN (2022)

添加到收藏夹

Editorial Material Chemistry, Multidisciplinary

Emerging Investigators in Crystal Growth & Design 2022

Jonathan W. Steed

CRYSTAL GROWTH & DESIGN (2022)

添加到收藏夹

Editorial Material Chemistry, Multidisciplinary

Listening to fathers in STEM

Jennifer S. Leigh, David K. Smith, Barry A. Blight, Gareth O. Lloyd, Charlie T. McTernan, Emily R. Draper

Summary: Emily Draper and Jennifer Leigh from the International Women in Supramolecular Chemistry (WISC) network collaborated with David Smith to interview fathers in the field of supramolecular chemistry about their experiences with parental leave.

NATURE REVIEWS CHEMISTRY (2023)

添加到收藏夹

Editorial Material Chemistry, Multidisciplinary

Women Researchers at the Forefront of Crystal Engineering

Sonja Krane, Jennifer Hiscock, Kathryn Preuss, Jonathan W. Steed

CRYSTAL GROWTH & DESIGN (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Vapor Sorption and Halogen-Bond-Induced Solid-Form Rearrangement of a Porous Pharmaceutical

Jessica L. Andrews, Dmitry S. Yufit, James F. McCabe, Mark A. Fox, Jonathan W. Steed

Summary: This example demonstrates that vapor sorption is a potentially valuable yet underutilized tool for modifying pharmaceutical solid forms as part of a solid form screening protocol.

CRYSTAL GROWTH & DESIGN (2023)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Metal-based gels: Synthesis, properties, and applications

Giacomo Picci, Claudia Caltagirone, Alessandra Garau, Vito Lippolis, Jessica Milia, Jonathan W. Steed

Summary: This review discusses recent advancements in the design, synthesis, and characterization of metallogels and coordination complex-based gels. It emphasizes systems that possess recognition and sensing properties towards various analytes.

COORDINATION CHEMISTRY REVIEWS (2023)

添加到收藏夹

Editorial Material Chemistry, Inorganic & Nuclear

We Glow Together: A Dialogue on Luminescent Compounds

Stefanie Dehnen, Jonathan W. Steed, Kenneth Lo, Katja Heinze, Oliver S. Wenger, Shalini Singh, Hai-Bo Yang, Shuang-Quan Zang

INORGANIC CHEMISTRY (2023)

添加到收藏夹

Article Chemistry, Organic

The Photochemical Mediated Ring Contraction of 4H-1,2,6-Thiadiazines To Afford 1,2,5-Thiadiazol-3(2H)-one 1-Oxides

Emmanouil Broumidis, Christopher G. Thomson, Brendan Gallagher, Lia Sotorrios, Kenneth G. Mckendrick, Stuart A. Macgregor, Martin J. Paterson, Janet E. Lovett, Gareth O. Lloyd, Georgina M. Rosair, Andreas S. Kalogirou, Panayiotis A. Koutentis, Filipe Vilela

Summary: This study discovered that 1,2,6-thiadiazines can be converted into 1,2,5-thiadiazole 1-oxides using visible light and oxygen under ambient conditions, which was previously difficult to achieve. Experimental and theoretical studies revealed that 1,2,6-thiadiazines act as triplet photosensitizers and undergo a selective cycloaddition reaction to form an endoperoxide.

ORGANIC LETTERS (2023)

添加到收藏夹

Article Polymer Science

Highly Thermally Resistant Bisamide Gelators as Pharmaceutical Crystallization Media

Ivan Torres-Moya, Abelardo Sanchez, Basanta Saikia, Dmitry S. Yufit, Pilar Prieto, Jose Ramon Carrillo, Jonathan W. Steed

Summary: Three bisamide derivatives were synthesized and their gel behavior was tested. Only G1 provided satisfactory gels due to the hindered hydrogen bonding in G2 and G3. G1 exhibited thermally and mechanically stable gels, pH responsiveness, and was able to induce the formation of thermodynamically stable form III in drug crystallization.

GELS (2023)

添加到收藏夹

暂无数据

© Peeref 2019-2024. All rights reserved.