期刊
ANALYTICAL METHODS
卷 6, 期 19, 页码 7956-7966出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ay01823k
关键词
-
资金
- Fundacao para a Ciencia e Tecnologia
- FSE (Quadro Comunitario de Apoio) [SFRH/BD/70444/2010]
- European Union (FEDER funds through COMPETE)
- National Funds (FCT, Fundacao para a Ciencia e Tecnologia) [Pest-C/EQB/LA0006/2013]
- European Union (FEDER funds) under the framework of QREN [NORTE-07-0124-FEDER-000067]
In this study an automated flow-based methodology for the fluorometric determination of sulphide was reported. It relies on the utilization of CdTe nanocrystals as photoluminescent probes, which upon reaction with S2- are subject to a noteworthy concentration-related photoluminescence decrease. For lower S2- concentrations the photoluminescence quenching was based on dynamic processes while for higher concentrations the quenching mechanism was ascribed to the depassivation of the surface ligands, replaced by S2-, resulting in the aggregation of QDs. The developed approach was automated by resorting to a pulsed stream multi-pumping flow system guaranteeing a high versatility in terms of sample and reagent manipulation and reaction zone formation. The selectivity was ensured by means of the utilization of a gas-diffusion unit relying on a hydrophobic PTFE membrane that facilitated sulphide isolation from sample matrix interferences. Under optimal conditions, a good linear relationship between the photoluminescence quenching magnitude (Delta F) and the logarithmic of the S2- concentration within the range of 0.25-5.0 mmol L-1 were verified (R = 0.998, n = 5). The limit of detection (LOD) was found to be 0.19 mmol L-1. The sampling rate was of about 13 h(-1).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据