期刊
ANALYTICAL METHODS
卷 5, 期 3, 页码 660-665出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ay26010g
关键词
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资金
- National Natural Science Foundation of China [21072024, 21272030, 20872012]
- Fundamental Research Funds for the Central Universities [DUT11LK21]
- State Key Laboratory of Bioelectronics, Southeast University
- State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology
- Key Laboratory of ECO-Textiles (Jiangnan University), Ministry of Education [KLET1102]
- China Postdoctoral Science Foundation [20100471434]
Electrochemiluminescence (ECL) of Ru(bpy)(3)(2+) and bimetallic ruthenium tris-bipyridyl complex [(bpy)(2)Ru(bpy)(CH2)(8)(bpy)Ru(bpy)(2)](4+) (1) at a gold electrode has been employed for the determination of malachite green (MG) in this paper. For Ru(bpy)(3)(2+), a linear response (R-2 = 0.9992) was obtained over a MG concentration range of 1.0 x 10(-8) to 1.0 x 10(-5) M, with a remarkable detection limit of 1.0 x 10(-8) M in a pH 10 borate buffer. The detection limit was further decreased to 1.0 x 10(-12) M for the bimetallic ruthenium complex 1. Meanwhile, leucomalachite green (LMG) was detected and the same detection limit was reached. Which is much lower compared to the other detection methods. To check its applicability, the proposed method was employed in the determination of MG/LMG added into a fishpond water sample, and good reproducibility and stability were achieved. These results show that it will be possible to develop an ECL detection method for MG/LMG.
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