Review
Chemistry, Analytical
Karina Lotz Soares, Sergiane Caldas Barbosa, Ednei Gilberto Primel, Gilberto Fillmann, M. Silvia Diaz-Cruz
Summary: This paper summarizes sample preparation procedures and chromatographic methods for the analysis of ABBs in environmental samples, discussing the development of techniques from traditional extraction methods to novel miniaturized and micro-extraction methods. Despite the development of numerous ABB determination methods, the lack of standardization among methods is highlighted as an ongoing issue that needs further improvement.
TRENDS IN ENVIRONMENTAL ANALYTICAL CHEMISTRY
(2021)
Review
Chemistry, Analytical
Laura Martin-Pozo, Maria del Carmen Gomez-Regalado, Inmaculada Moscoso-Ruiz, Alberto Zafra-Gomez
Summary: Personal care products and cosmetics may contain endocrine disruptors, which can be harmful to health, so the development of accurate detection methods is important.
Review
Environmental Sciences
Subha Sasi, Manoj P. Rayaroth, Charuvila T. Aravindakumar, Usha K. Aravind
Summary: This review provides a detailed overview of the various aspects of the anionic surfactant AES, including its toxicity, fate in the ecosystem, technical advancements, occurrence and distribution in different environmental compartments, and potential removal strategies.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Biochemical Research Methods
Yong Lu, Yu He, Xinran Wang, Haiyan Wang, Qianqian Qiu, Baojin Wu, Xianfu Wu
Summary: Recently, new types of illegal cosmetic additives have emerged in the market. These additives are often new drugs or analogues with similar structures to prohibited additives, making them difficult to identify solely by LC-MS. To address this, a new strategy combining chromatographic separation with NMR structural identification is proposed. Suspected samples were screened using UPLC-Q-TOF-MS, followed by purification and extraction through silica-gel column chromatography and preparative HPLC. The extracts were then identified using NMR as bimatoprost and latanoprost, which were found to be new illegal additives in eyelash serums in China. Furthermore, bimatoprost and latanoprost were quantified using HPLC-QQQ-MS/MS, demonstrating good linearity, accuracy, precision, and reproducibility.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2023)
Review
Environmental Sciences
Bahriye Eryildiz, Hale Ozgun, Mustafa Evren Ersahin, Ismail Koyuncu
Summary: In recent years, antiviral drugs against influenza have become emerging contaminants due to their environmental toxicity even at low concentrations and their resistance to conventional treatment methods. This study presents an assessment of different treatment methods and techniques for the degradation/removal of these drugs from water and wastewater, with a focus on ozonation, photolysis, and photocatalysis. The study concludes that combined methods, particularly those utilizing renewable energy and waste materials, offer the most effective approach for treating effluents containing antiviral drugs against influenza.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2022)
Review
Chemistry, Analytical
Parvaneh Hajeb, Argelia Castano, Enrique Cequier, Adrian Covaci, Marta Esteban Lopez, Ana Gonzalez Antuna, Line Smastuen Haug, Luis Alberto Henriquez-Hernandez, Lisa Melymuk, Octavio Perez Luzardo, Cathrine Thomsen, Katrin Vorkamp
Summary: Human biomonitoring is an important method for assessing exposure to environmental pollutants, and this article reviews studies on the chemical analysis of flame retardants (FRs) in human samples. The article discusses the different analytical methods used for FR biomarkers and highlights the challenges in analyzing low concentrations of FRs and limited sample materials. The development of universal analytical methods is also mentioned.
ANALYTICA CHIMICA ACTA
(2022)
Review
Biochemistry & Molecular Biology
Ningjie Zhong, Lili Li, Xiaofan Yang, Yonggang Zhao
Summary: This paper summarizes the separation and measurement methods for ultra-trace determination of Sr-90, Pu-239, and Pu-240 in the environment, and discusses the future development trends of radionuclide measurement.
Review
Chemistry, Analytical
Ozge Selcuk, Yeliz Demir, Cem Erkmen, Sercan Yildirim, Bengi Uslu
Summary: Viruses are the main pathogenic substances causing severe diseases in humans and other living things, leading to the emergence of antiviral drugs for prevention and treatment. This review provides an overview of the analysis of currently used antiviral drugs from 2010 to 2021, focusing on chromatographic, spectrometric, and electrochemical methods.
CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY
(2022)
Review
Chemistry, Analytical
Akriti Ashesh, Shreya Singh, Ningombam Linthoingambi Devi, Ishwar Chandra Yadav
Summary: This review examines the distribution, occurrence, and trends of organochlorine pesticides (OCPs) in India's multi-ecological conditions and biota. It also discusses the analytical techniques used for measuring OCPs and highlights the need for more sensitive methods. The review emphasizes the high contamination level of OCPs in the Indian environment and calls for increased awareness and training for farmers and stakeholders.
MICROCHEMICAL JOURNAL
(2022)
Review
Biochemistry & Molecular Biology
Izabela Narloch, Grazyna Wejnerowska
Summary: UV filters are compounds used in cosmetic products to absorb UV radiation, but some of them can be absorbed through the skin and cause negative health effects. Analytical methods are necessary to determine these compounds in order to ensure user safety.
Review
Chemistry, Analytical
Francisco Pena-Pereira, Carlos Bendicho, Dragana Mutavdzic Pavlovic, Antonio Martin-Esteban, Myriam Diaz-Alvarez, Yuwei Pan, Jon Cooper, Zhugen Yang, Ivo Safarik, Kristyna Pospiskova, Marcela A. Segundo, Elefteria Psillakis
Summary: This paper reviews miniaturized analytical methods for the determination of contaminants of emerging concern (CECs) in environmental samples, covering the importance of monitoring CECs, downsized sample preparation methods, microextraction techniques, and miniaturized analytical flow techniques.
ANALYTICA CHIMICA ACTA
(2021)
Article
Food Science & Technology
Minh Kim Nguyen, Eun Seon Jeong, Kyung Tae Kim, Yong Seok Choi, Dong-Kyu Lee, Sang Beom Han, Jong Seong Kang, Hyung Min Kim
Summary: Organophosphate flame retardants (OPFRs) have been widely used in various consumer items, leading to widespread contamination of environmental systems and detection of their presence in various food items globally. Human exposure to OPFRs through consumption of contaminated food poses potential health risks to both humans and wildlife. However, the analysis of OPFRs in food is challenging due to various factors, including the diverse nature of food matrices and the risk of laboratory contamination. This review discusses the current status of analytical methods used to detect OPFRs in aquatic, agricultural, and livestock-derived food, emphasizing the importance of developing efficient screening methods for these emerging contaminants.
Review
Chemistry, Analytical
Marina Arenas, Julia Martin, Juan Luis Santos, Irene Aparicio, Esteban Alonso
Summary: Chirality is an important topic in the pharmaceutical, food, and agrochemical fields due to the potential differences in properties of enantiomers despite their similar physical-chemical properties. Determining enantiomers poses an analytical challenge due to their identical properties except for light rotation. This review provides an overview of recent analytical methods for determining chiral pollutants and discusses future trends and challenges in this area.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2021)
Review
Biochemistry & Molecular Biology
Ana B. Moldes, Lorena Rodriguez-Lopez, Myriam Rincon-Fontan, Alejandro Lopez-Prieto, Xanel Vecino, Jose M. Cruz
Summary: This article reviews the classification, uses, and side effects of surfactants in the cosmetic, personal care, and pharmaceutical industries, dividing them into synthetic, bio-based, and microbial biosurfactants. It suggests that industries should consider microbial biosurfactants as a separate category due to their biocompatibility, eco-friendliness, and potential for less toxicity compared to chemical surfactants.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2021)
Article
Engineering, Environmental
Almendra Reyes-Calderon, Samantha Perez-Uribe, Ana Gabriela Ramos-Delgado, Sathishkumar Ramalingam, Goldie Oza, Roberto Parra-Saldivar, Ricardo A. Ramirez-Mendoza, Hafiz M. N. Iqbal, Ashutosh Sharma
Summary: The widespread occurrence and bioaccumulation of toxic substances, such as pesticides and toxic elements, have raised serious social, ecological, and human health concerns, but effective monitoring and mitigation methods are still lacking.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Analytical
Maria Vergara-Barberan, Maria Jesus Lerma-Garcia, Ernesto F. Simo-Alfonso, Marta Garcia-Hernandez, M. Elena Martin, Ana Garcia-Sacristan, Victor M. Gonzalez, Jose Manuel Herrero-Martinez
Summary: In this study, DNA aptamers with high binding affinity to the major allergen of olive pollen, Ole e 1, were selected using SELEX method. The binding of the aptamers was confirmed by ELONA and aptaprecipitation assays. Aptamer-modified capillary chromatography demonstrated the selective recognition of Ole e 1 against non-target proteins. The stability and reproducibility of the aptamer-modified monolithic column were suitable for practical applications.
ANALYTICA CHIMICA ACTA
(2022)
Article
Biochemical Research Methods
Joan Carles Nadal, Monica Catala-Icardo, Francesc Borrull, Jose Manuel Herrero-Martinez, Rosa Maria Marce, Nuria Fontanals
Summary: In this study, a novel support material based on PTFE magnet coated with WAX monolith was developed for SBSE. The material showed good stability and reusability, enabling selective extraction of acidic compounds in environmental water samples. The optimized SBSE conditions led to recoveries ranging from 37 to 75% for target compounds, with values of% matrix effect from 17 to -13% when determined by LC-MS/MS.
JOURNAL OF CHROMATOGRAPHY A
(2022)
Article
Biochemical Research Methods
Enric Pellicer-Castell, Carolina Belenguer-Sapina, Pedro Amoros, Jamal El Haskouri, Jose Manuel Herrero-Martinez, Adela R. Mauri-Aucejo
Summary: A novel sorbent based on UVM-7 mesoporous silica doped with gold has been proposed for the extraction of organochlorine pesticides. The sorbent showed good recovery rates for most analytes and comparable sensitivity with other methods, allowing for the determination of compounds according to European legislation. This environmentally friendly and cost-effective solid-phase extraction method has proven to be an alternative for pesticide enrichment in water samples.
JOURNAL OF CHROMATOGRAPHY A
(2022)
Article
Chemistry, Applied
Elizabeth Goya-Jorge, Osmary Fernandez Exposito, Jose Manuel Herrero-Martinez, Ernesto F. Simo-Alfonso, Idelfonso Castaneda-Noa, Maria Elisa Jorge Rodriguez
Summary: This study analyzed the composition of the essential oil of Mosiera bullata for the first time, identifying nineteen components with 1,8-cineole and eugenol as the major compounds. A fingerprint of the volatile composition of Mosiera bullata leaves was proposed using GC/FID chromatograms, with chemometric methods ensuring the reliability of the chromatographic fingerprinting.
JOURNAL OF ESSENTIAL OIL RESEARCH
(2022)
Article
Chemistry, Analytical
S. Zatrochova, H. Martinez-Perez-Cejuela, M. Catala-Icardo, E. F. Simo-Alfonso, I Lhotska, D. Satinsky, J. M. Herrero-Martinez
Summary: A novel coating based on hybrid monolith with metal-organic framework (MOF) was developed for conventional Teflon-coated magnetic stir bars. The resulting hybrid monolith was evaluated as a sorbent for stir bar sorptive extraction (SBSE) of estrogens from water and urine samples. The method achieved satisfactory limits of detection, recovery results, and precision values.
Article
Biochemical Research Methods
Enric Pellicer-Castell, Carolina Belenguer-Sapina, Pedro Amoros, Jamal El Haskouri, Jose Manuel Herrero-Martinez, Adela R. Mauri-Aucejo
Summary: A method for the determination of parabens and bisphenol A in urine samples was developed using a novel hierarchical mesoporous silica doped with beta-cyclodextrin as a sorbent. The method showed good analytical features and was successfully applied to the determination of parabens and bisphenol A in real urine samples.
JOURNAL OF CHROMATOGRAPHY A
(2022)
Review
Biochemical Research Methods
Hector Martinez-Perez-Cejuela, Enrique Javier Carrasco-Correa, Ancuta Moga, Maria Vergara-Barberan, Miriam Beneito-Cambra, Maria Jesus Lerma-Garcia, Ernesto Francisco Simo-Alfonso, Jose Manuel Herrero-Martinez
Summary: In recent years, there have been significant efforts in miniaturization, with the emergence of formats such as chips, 3D-printed objects, and paper-based devices. These systems have been utilized in biological and chemical processes, leveraging their advantages of waste reduction, low cost, and portability. However, there is a need to further develop more user-friendly devices with improved performance to address current analytical challenges. This review aims to address this research gap by highlighting the recent contributions of reticular porous materials, such as metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs), in these miniaturized and emerging formats.
JOURNAL OF CHROMATOGRAPHY A
(2022)
Article
Chemistry, Analytical
Enrique Javier Carrasco-Correa, Jose Manuel Herrero-Martinez, Ernesto Francisco Simo-Alfonso, Dietmar Knopp, Manuel Miro
Summary: This article reports on the current research efforts in designing microscale extraction methods using 3D printing technology. The use of a spinning cup-based platform and modified surface materials allows for the immobilization of antibodies and extraction of emerging contaminants at the microscale. The study demonstrates the feasibility and efficacy of the antibody-laden device in handling complex samples, with high recovery rates.
Article
Chemistry, Analytical
Susana Meseguer-Lloret, Sagrario Torres-Cartas, Carmen Gomez-Benito, Jose Manuel Herrero-Martinez
Summary: In this study, a selective magnetic molecularly imprinted polymer (MMIP) was successfully synthesized and applied as sorbent in magnetic molecularly imprinted solid-phase extraction (MMISPE) for the selective extraction of a mixture of five herbicides. The optimized MMISPE method combined with HPLC-DAD showed low detection and quantification limits, as well as good accuracy and precision. The MMIP sorbent demonstrated remarkable reusability without loss in extraction capacity.
Article
Chemistry, Analytical
P. Garcia-Atienza, F. A. Esteve-Turrillas, S. Armenta, J. M. Herrero-Martinez
Summary: Drug abuse can be easily identified through oral fluid analysis. A selective and sensitive methodology using a molecularly imprinted polymer (MIP) as a solid phase extraction sorbent, followed by ion mobility spectrometry, has been proposed for the fast identification of drug abuse in oral samples.
MICROCHEMICAL JOURNAL
(2022)
Article
Nanoscience & Nanotechnology
Cristina Negro, Hector Martinez Perez-Cejuela, Ernesto Francisco Simo-Alfonso, Waseem Iqbal, Jose Manuel Herrero-Martinez, Donatella Armentano, Jesus Ferrando-Soria, Emilio Pardo
Summary: The contamination of aquatic environments by pharmaceuticals used by modern societies, especially antibiotics, poses a serious threat to humans due to the potential for creating drug-resistant bacteria. This study reports a family of three isoreticular MOFs derived from natural amino acids that show high efficiency in removing a mixture of different families of antibiotics. A specific MOF, called MTV-MOF, prepared using equal percentages of L-serine and L-methionine, not only exhibits outstanding recyclability but also outperforms activated carbon. The successful removal performance of MTV-MOF is explained by single-crystal X-ray diffraction, highlighting the potential of MOFs as a promising alternative for capturing antibiotics from wastewater streams.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Analytical
Hector Martinez-Perez-Cejuela, Denise Gregucci, Maria Maddalena Calabretta, Ernesto Francisco Simo-Alfonso, Jose Manuel Herrero-Martinez, Elisa Michelini
Summary: The identification of new strategies to improve protein stability is crucial for various applications. Metal-organic frameworks (MOFs) have been found to be versatile host platforms for protein immobilization, providing protection in harsh conditions. In this study, a thermostable luciferase mutant was used as a model to investigate the suitability of MOFs to enhance stability and enable real-world applications such as ATP detection in portable systems. The results demonstrated that the use of MOF significantly improved the stability of luciferase under adverse conditions, and the biocomposite outperformed the free enzyme in terms of ATP detection sensitivity.
ANALYTICAL CHEMISTRY
(2022)
Article
Chemistry, Analytical
Aitor Sorribes-Soriano, Francesc Albert Esteve-Turrillas, Sergio Armenta, Jose Manuel Herrero-Martinez
Summary: In this study, a molecularly imprinted polymer (MIP)-coated stir bar for recognizing diazepam was prepared. The MIP was synthesized using methacrylic acid as a functional monomer, diazepam as a template, ethylene glycol dimethacrylate as a crosslinker, and azobisisobutyronitrile as an initiator. The resulting polymer-modified stir bar was characterized and used in a stir-bar-sorptive-extraction (SBSE) method in combination with ion mobility spectrometry (IMS) or ultra-high performance liquid chromatography coupled to mass spectrometry (UHPLC-MS/MS). The MIP-SBSE coupled with UHPLC-MS/MS showed satisfactory results in quantifying traces of diazepam in water samples, while the MIP-SBSE using IMS exhibited high sensitivity for rapid screening of the compound in different matrices.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Analytical
Maria Vergara-Barberan, Monica Catala-Icardo, Ernesto F. Simo-Alfonso, Fernando Benavente, Jose Manuel Herrero-Martinez
Summary: This study describes the development of an aptamer-functionalized stir bar sorptive extraction (SBSE) coating for selective isolation and preconcentration of an allergenic food protein, concavanalin A (Con A), followed by matrix-assisted laser desorption/ionization mass spectrometry (MALDI-TOF-MS) determination. The aptamer-functionalized stir bar exhibited high selectivity for Con A and was successfully applied to the determination of Con A in various food matrices. The developed method showed good recoveries and stability, indicating its potential for the extraction of proteins and peptides from complex samples.
Article
Chemistry, Analytical
Gang Qu, Yuxin Zhao, Qiaoli Zhang, Jina Wu, Xiaosen Li, Yang Yang, Shilei Liu
Summary: In this study, magnetic mesoporous materials combined with real-time in situ mass spectrometry were used for the high-throughput detection of hydrolyzed products of organophosphorus nerve agents. The method showed good linearity, low limits of detection and quantification, and high extraction recoveries. The magnetic preparation method used was quick, cost-effective, rugged, and safe. The results demonstrated the potential of this method for rapid and efficient determination of the target analytes in environmental samples.
ANALYTICAL METHODS
(2024)
Article
Chemistry, Analytical
Anna Hildebrand, Mariam Merchant, Danny O'Hare
Summary: Substandard and falsified artemisinin derivatives in antimalarials have caused significant deaths and economic losses. This study evaluates the feasibility of voltammetric methods for identifying and quantifying artemether. The findings suggest that electrochemical analysis shows promise as a method for artemether identification and quantification.
ANALYTICAL METHODS
(2024)
Article
Chemistry, Analytical
Marx Osorio Araujo Pereira, Alvaro Ferreira Junior, Edson Silvio Batista Rodrigues, Helena Mulser, Giovanna Nascimento de Mello e Silva, Wallans Torres Pio dos Santos, Eric de Souza Gil
Summary: Brazilian spotted fever (BSF) is a serious and rapidly evolving disease. A new impedimetric immunosensor was developed for rapid diagnosis by measuring specific antibodies in plasma. The sensor demonstrated selectivity and accuracy, and has potential for important applications in diagnostic testing.
ANALYTICAL METHODS
(2024)
Article
Chemistry, Analytical
Kathrin Schilling, Ronald A. Glabonjat, Olgica Balac, Marta Galvez-Fernandez, Arce Domingo-Relloso, Vesna Slavkovich, Jeff Goldsmith, Miranda R. Jones, Tiffany R. Sanchez, Ana Navas-Acien
Summary: Analysis of trace elements in urine is an important tool for assessing exposures, diagnosing nutritional status, and guiding public health and healthcare intervention. This study provides a sensitive method for analyzing 18 elements in urine samples, using only 100 μL. The results show good accuracy and sensitivity of the method.
ANALYTICAL METHODS
(2024)
Article
Chemistry, Analytical
Mengya Li, Shijie Liu, Shiliang Guo, Dong Liang, Miaoyun Li, Yaodi Zhu, Lijun Zhao, Jong-Hoon Lee, Gaiming Zhao, Yangyang Ma, Yanxia Liu
Summary: In this study, a magnetic flow device was developed to purify spores in a culture medium system. The device used magnetic nanoparticles to absorb vegetative cells, separating them from the spores. The achieved purity of the collected spores was over 95%. The study also demonstrated a rapid quantitative detection method using Raman spectroscopy.
ANALYTICAL METHODS
(2024)
Article
Chemistry, Analytical
Wanqiong Liu, Zixuan Wu, Jianwei Peng, Zebin Xu, Yong Liang
Summary: Metal-organic frameworks (MOFs) are effective carriers for molecular imprinting, but their poor dispersibility in aqueous solution is a significant drawback. In this study, we have applied amphiphilic block copolymers and molecularly imprinted technology on MOFs to improve the hydrophilicity of molecularly imprinted fluorescent materials.
ANALYTICAL METHODS
(2024)