4.4 Article

Electrochemical Determination of Pentachlorophenol Using a Glassy Carbon Electrode Modified with a Film of CuS Nanocomposite-Chitosan

期刊

ANALYTICAL LETTERS
卷 46, 期 7, 页码 1108-1116

出版社

TAYLOR & FRANCIS INC
DOI: 10.1080/00032719.2012.749483

关键词

CuS nanocomposite; Cyclic voltammetry; Modified electrode; Pentachlorophenol

资金

  1. Nature Science Foundation of China (NSFC) [21077037, 21075096]
  2. Scientific Research Key Project of Hubei Provincial Department of Education [D20121503]

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A new electrochemical sensor was fabricated by modifying the glass carbon electrode surface with CuS nanocomposites and chitosan for the determination of pentachlorophenol. CuS nanocomposites obtained by a solvothermal method were composed primarily of CuS with hexagonal phase and Cu2Cl(OH)3 with a tetragonal phase. The results indicated that CuS nanocomposites possessed good electrochemical activity. After optimizing the experimental conditions, the linear dependence of current vs. pentachlorophenol concentration was reached in a range from 1.88x1067.50x105mol/L pentachlorophenol, and the detection limit was 6.25x107mol/L. The electrode displayed a high degree of stability and reproducibility. A new, simple, rapid, and highly sensitive electrochemical detection method of pentachlorophenol was established.

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