Article
Chemistry, Analytical
Yang-Yang Hou, Jing Xu, Fu-Ting Wang, Zhong Dong, Xuecai Tan, Ke-Jing Huang, Jia-Qiang Li, Chun-Yang Zuo, Si-Qi Zhang
Summary: A novel self-powered biosensing platform was developed for detecting miRNA, utilizing an EBFC-based biosensor with a matching capacitor. By improving the EBFC performance with catalytic hairpin assembly and hybrid chain reaction, along with using a matching capacitor for signal amplification, the sensitivity was significantly increased.
ANALYTICAL CHEMISTRY
(2021)
Article
Nanoscience & Nanotechnology
Ying Du, Shujun Wang, Jianfeng Luan, Meilin Zhang, Baoan Chen, Yanfei Shen
Summary: In this study, HMMD@PG nanoparticles were prepared by camouflaging HMMD with GOx-functionalized platelet membranes. The nanoparticles showed remarkable tumor suppression through starvation treatment, photothermal treatment, and chemotherapy.
INTERNATIONAL JOURNAL OF NANOMEDICINE
(2022)
Article
Nanoscience & Nanotechnology
Guiqiang Qi, Guangyue Shi, Shengchao Wang, Haifeng Hu, Zhichen Zhang, Qiangqiang Yin, Zhongtao Li, Liguo Hao
Summary: This study developed a pancreatic cancer targeted drug delivery system that responds to changes in acidity. The system effectively inhibited tumor growth and induced apoptosis in both in vitro and in vivo experiments, providing a new strategy for combination therapy.
INTERNATIONAL JOURNAL OF NANOMEDICINE
(2023)
Article
Environmental Sciences
Zefeng Li, Meng Li, Bin Tan, Ning Du, Qian Zhang, Chengwei Li, Yibo Zhang, Jiawei Li, Jiayi Li
Summary: This study established an adaptable biological Fenton-like system for the efficient degradation of organic contaminants. By optimizing the pH range, selecting suitable oxidizing species, and enhancing glucose conversion, effective degradation of 3,4-dimethylaniline was achieved.
ENVIRONMENTAL RESEARCH
(2022)
Article
Engineering, Chemical
Sara Barricella, Jordi M. Fuertes, Kevin H. Putera, Aubrey E. Quigley, Victoria Haritos, Benny D. Freeman, Gil Garnier
Summary: In this study, a robust multi-enzymatic cascade system with spatial compartmentalization was reported. The membrane served as a porous scaffold facilitating enzyme immobilization and recyclability, improving stability and catalytic efficiency. The spatially defined cascade system exhibited superior catalytic activity.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Medicine, Research & Experimental
Lifeng Hang, Tao Zhang, Hua Wen, Meng Li, Lianbao Liang, Xinfeng Tang, Chunze Zhou, JunZhang Tian, Xiaofen Ma, Guihua Jiang
Summary: The study introduced an intelligent nanoreactor with high enzyme loading capacity and good biocompatibility, which spatially isolates the enzyme from glucose in a physiological environment to reduce systemic toxicity, achieving multimodal synergistic therapy and tumor metastasis suppression.
Article
Environmental Sciences
Majid Masteri-Farahani, Nazanin Mosleh
Summary: CdS quantum dots synthesized within the mesopores of MCM-41 and interlayers of montmorillonite without capping agents showed high efficiency for the photodegradation of rhodamine-B under UV-Vis illumination. Characterization of CdS-QDs@MCM-41 and CdS-QDs/MMT was conducted using various spectroscopic techniques.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Engineering, Multidisciplinary
Wiktoria Lipinska, Jacek Ryl, Pawel Slepski, Katarzyna Siuzdak, Katarzyna Grochowska
Summary: The study proposes a novel protocol utilizing dynamic electrochemical impedance spectroscopy to verify sensor performance, focusing on the response of Ti-Au nanotextured electrode to changes in glucose concentration. Results show visible increase in electrode electric heterogeneity above 1.9 mM of glucose and gold nanoparticles' oxidation above 3.8 mM, both impacting electrode kinetics.
Article
Chemistry, Analytical
Ayman Chmayssem, Ibrahim Shalayel, Stephane Marinesco, Abdelkader Zebda
Summary: In this study, a new biosensing membrane was designed for the development of an electrochemical glucose biosensor. The biosensor utilized a chitosan-based hydrogel that encapsulated glucose oxidase enzyme (GOx) and was crosslinked using glutaraldehyde. The stability of the biosensors was investigated under different storage conditions and it was found that they maintained stability for over six months in certain specific conditions. Catalase was also included to protect the biosensing membranes from enzymatic reaction by-products, thereby enhancing the lifetime of the biosensor.
Article
Materials Science, Ceramics
Lorena Garcia-Uriostegui, H. Ivan Melendez-Ortiz, Jose M. Mata-Padilla, Guillermo Toriz
Summary: This study reports the synthesis of mesoporous MCM-41 nanoparticles using microwave radiation. Silica nanoparticles with large surface area and suitable chemical composition were obtained at low power and short time. The particle size was close to 100 nm with a spherical morphology. The microwave radiation power and heating time affected particle size and aggregation. The MCM-41 synthesized under low microwave radiation power had a high surface area and expanded pore diameters compared to hydrothermal synthesis. The sample labeled as MCM400W10 showed a significant number of free silanol groups on the surface.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Applied
Vicente Candela-Noguera, Maria Alfonso, Pedro Amoros, Elena Aznar, Maria Dolores Marcos, Ramon Martinez-Manez
Summary: This study comprehensively investigates the factors affecting the formation of MCM-41 type mesoporous silica nanoparticles (MSN). The hydrolysis and condensation rates are found to play a central role in nanoparticle formation, and disregarded parameters such as stirring strength and surfactant addition rate are shown to modulate nucleation and growth. Furthermore, the aging and evolution of MSN are studied through the analysis of silica framework consolidation over time, providing insights into obtaining reproducible, homogeneous, and tailored-made MCM-41 type MSN.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Engineering, Chemical
Katarzyna Jankowska, Sigyn Bjork Sigurdardottir, Jakub Zdarta, Manuel Pinelo
Summary: This study presents a novel approach for enzyme compartmentalization using polyelectrolyte layers, which improves enzyme stability and catalytic efficiency. Enzymes immobilized by compartmentalization showed higher conversion efficiency and minimal negative effects from hydrogen peroxide compared to free enzymes. Moreover, the compartmentalized enzymes exhibited high efficiency and low enzyme elution during repeated use.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Construction & Building Technology
Rafal Panek, Maciej Szelag, Wojciech Franus
Summary: The paper discusses the impact of MCM-41 mesoporous silica on the properties of cement matrix. It was found that the optimal content of MCM-41 is between 0.5% and 1%, as excess silica may disrupt the proper hydration process. The research indicates a high application potential of MCM-41 as an additive in cement.
JOURNAL OF BUILDING ENGINEERING
(2021)
Article
Chemistry, Physical
Satvir Singh, Meenu Kaur, B. S. Bajwa, Inderpreet Kaur
Summary: Water sources with high uranium prevalence pose potential health risks. The development of efficient uranium scavenging water treatment techniques is of great importance. NH2-MCM-41(MCM-a) was synthesized and grafted using salicylaldehyde (MCM-s) and 3-hydroxybenzoic acid (MCM-hb). The results showed that MCM-s had the highest adsorption capacity under the optimum conditions. The thermodynamic parameters indicated the feasibility of the adsorption process. MCMs exhibit rapid adsorption rate, high adsorption efficiency, and regeneration ability, making them promising for uranium removal in water treatment.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Engineering, Chemical
Peide An, Defeng Hu, Yide Han, Hao Meng, Xia Zhang
Summary: Based on the structural advantages of MOFs in enzyme mimics and enzyme immobilization, this study constructed Hemin@PCN-222(Mn) through an in-situ hydrothermal route. The resulting Hemin@PCN-222(Mn) showed excellent peroxidase-like activities compared to single Hemin and PCN-222(Mn). After optimizing the immobilization conditions, the resulting GOx@hemin@PCN-222(Mn) exhibited high efficiency and stability in the cascade reaction of glucose oxidation and biosensing.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)