期刊
ANALYTICAL CHEMISTRY
卷 81, 期 21, 页码 8892-8899出版社
AMER CHEMICAL SOC
DOI: 10.1021/ac901486c
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资金
- Technology New Zealand
- FRST
The rate coefficients and branching ratios of 15 chemical warfare agent precursor and surrogate compounds reacting with H3O+, NO+, and O-2(+) have been measured in the laboratory using the selected ion flow tube (SIFT) technique. Measurement of the relevant kinetic parameters for these agents has enabled quantitative monitoring using the SIFT-MS analytical technique. Thirteen of the 15 compounds studied were found to have real-time detection limits in the parts-per-trillion-by-volume concentration range when measured on a standard commercial Voice 100 instrument, with specific compounds having detection limits below 100 parts-per-trillion-by-volume.
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