Review
Chemistry, Analytical
Foad Mashayekhi Suzaei, Alex D. Batista, Boris Mizaikoff, Sima Rahimi, Seyed Mosayeb Daryanavard, Mohamed Abdel-Rehim
Summary: In recent years, there have been significant efforts to develop methods for early diagnosis, treatment, and monitoring of cancers using molecularly imprinted technology. These methods have demonstrated high selectivity, accuracy, and low limits of detection, making them important tools for early diagnosis and treatment monitoring.
Article
Polymer Science
Ali Doostmohammadi, Khaled Youssef, Shiva Akhtarian, Ehsan Tabesh, Garrett Kraft, Satinder Kaur Brar, Pouya Rezai
Summary: This article introduces a method for synthesizing MIP shells for molecular imprinting in microorganisms. Experimental results demonstrate that MIP shells have a high affinity for bacteria, and provide a new fabrication method for bioseparation and point-of-care sensing.
Article
Biochemistry & Molecular Biology
Wiebke Derz, Melita Fleischmann, Paul W. Elsinghorst
Summary: This study demonstrates the use of pharmacophore modeling to guide MIP design for the extraction of citrinin from cereals using MISPE, resulting in a promising MIP derived from rhodizonic acid. The developed protocol was compared to immunoaffinity chromatography for clean-up efficiency and recovery.
Review
Chemistry, Analytical
Mokhtar Mabrouk, Sherin F. Hammad, Aya A. Abdella, Fotouh R. Mansour
Summary: Molecularly imprinted polymers (MIPs) are a well-known class of materials with various applications. This review focuses on the critical steps during MIP preparation and characterization that affect imprinting efficiency. The selection of suitable monomers, the formation of a stable complex with the template, polymerization, and extraction techniques are discussed.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Analytical
Vilma Ratautaite, Ernestas Brazys, Almira Ramanaviciene, Arunas Ramanavicius
Summary: The aim of this study was to compare the application of two different conducting polymers, polypyrrole and polyaniline, in the design of molecularly imprinted polymers (MIPs). The results showed that polypyrrole had a higher affinity for L-tryptophan and was more suitable for the design of MIP-based sensors for the detection of L-tryptophan.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2022)
Review
Chemistry, Analytical
Weiyingxue Yang, Yaxing Ma, Hui Sun, Chuixiu Huang, Xiantao Shen
Summary: Molecularly imprinted polymers (MIPs) based optical fiber (OF) sensors are gaining attention worldwide due to their high specificity and flexible sensing ability. The design of efficient MIPs based OF sensors has become a timely research topic, with advancements in simply combined MIP/OF sensors and directly integrated MIP@OF sensors. These sensors utilize MIPs as solid phase extraction materials and binding films, with emphasis on various detection methods such as fluorescence, surface plasmon resonance, and interferometry.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2022)
Review
Cardiac & Cardiovascular Systems
Heba M. Kalbouneh, Ahmad A. Toubasi, Farah H. Albustanji, Yazan Y. Obaid, Layla M. Al-Harasis
Summary: The study found that SSRIs are effective in preventing and treating depression, improving anxiety, motor function, cognitive function, and dependence in post-stroke patients. However, treating with SSRIs increased the risk of seizures.
JOURNAL OF THE AMERICAN HEART ASSOCIATION
(2022)
Article
Polymer Science
Weida Rodrigues Silva, William Oliveira Sote, Joao Flavio Da Silveira Petruci, Alex Domingues Batista, Moacyr Comar Junior
Summary: Molecularly imprinted polymers (MIPs) are an advanced sample preparation technique that provides inherent functionalized cavities with high binding capacity, resulting in significant selectivity improvement for the desired target. This study used molecular dynamics methodology to select the most suitable functional monomer for imprinting scopolamine, and experimental results confirmed the theoretical predictions.
EUROPEAN POLYMER JOURNAL
(2022)
Review
Chemistry, Analytical
Kshitij R. B. Singh, Arunadevi Natarajan
Summary: This review focuses on the formation mechanism of molecularly imprinted polymers (MIPs), the role of co-monomers and porogen, and the performance of optical sensors. The use of MIPs in microorganism detection and cancer diagnosis is also discussed, along with the challenges faced in their application.
Article
Chemistry, Analytical
Zinat Alimohammadi, Shabnam Pourmoslemi
Summary: This study developed a method for determination of zolpidem in human plasma using molecularly imprinted polymer-solid phase extraction. The validated HPLC-fluorescence detector method showed a linear range and good recovery rate for zolpidem analysis. The developed method successfully constructed the plasma concentration profile of zolpidem after oral administration in a volunteer.
MICROCHEMICAL JOURNAL
(2021)
Article
Chemistry, Analytical
Aitor Sorribes-Soriano, Francesc Albert Esteve-Turrillas, Sergio Armenta, Jose Manuel Herrero-Martinez
Summary: In this study, a molecularly imprinted polymer (MIP)-coated stir bar for recognizing diazepam was prepared. The MIP was synthesized using methacrylic acid as a functional monomer, diazepam as a template, ethylene glycol dimethacrylate as a crosslinker, and azobisisobutyronitrile as an initiator. The resulting polymer-modified stir bar was characterized and used in a stir-bar-sorptive-extraction (SBSE) method in combination with ion mobility spectrometry (IMS) or ultra-high performance liquid chromatography coupled to mass spectrometry (UHPLC-MS/MS). The MIP-SBSE coupled with UHPLC-MS/MS showed satisfactory results in quantifying traces of diazepam in water samples, while the MIP-SBSE using IMS exhibited high sensitivity for rapid screening of the compound in different matrices.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Analytical
Yangguang Li, Yifan Feng, Shenyan Chen, Renjie Li, Yue Yang, Jing Jing Guan, Bang-Ce Ye
Summary: A stable ratiometric electrochemical sensor was introduced for the selective detection of carbendazim. By using a bimetallic nanomaterial as the electrode substrate and in situ fabricating a MIP layer, the excellent selectivity detection of carbendazim was achieved.
Article
Public, Environmental & Occupational Health
Avital Fischer, Hedy S. Rennert, Gad Rennert
Summary: The study found that the use of SSRIs before and after breast cancer diagnosis is associated with increased mortality in breast cancer patients. Research is needed to further understand the mechanisms behind this association.
INTERNATIONAL JOURNAL OF EPIDEMIOLOGY
(2022)
Article
Biochemical Research Methods
Fanny Varenne, Porkodi Kadhirvel, Pauline Bosman, Loic Renault, Audrey Combes, Valerie Pichon
Summary: This study focused on the development and characterization of molecularly imprinted polymers (MIPs) for the selective solid-phase extraction of oxazepam from environmental water and human urine samples. By optimizing the extraction procedure, high enrichment factors were achieved, leading to good extraction recoveries.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2022)
Article
Chemistry, Analytical
Guo-yong Jiang, Lin Liu, Yu-qi Wan, Jing-kun Li, Fu-wei Pi
Summary: In this study, molecularly imprinted polymers (MIPs) were combined with surface-enhanced Raman scattering (SERS) to selectively and sensitively detect sulfamethazine (SMZ). The MIP@AgNPs composites showed high selectivity and excellent sensitivity as SERS substrates, with a good linear correlation (R-2 = 0.996) between the Raman signal and SMZ concentration. The method exhibited good stability and reproducibility, and was successfully applied to the analysis of lake water samples.
Correction
Green & Sustainable Science & Technology
Daniel Gonzalez-Fernandez, Andres Cozar, Georg Hanke, Josue Viejo, Carmen Morales-Caselles, Rigers Bakiu, Damia Barcelo, Filipa Bessa, Antoine Bruge, Maria Cabrera, Javier Castro-Jimenez, Mel Constant, Roberto Crosti, Yuri Galletti, Ahmet E. Kideys, Nino Machitadze, Joana Pereira de Brito, Maria Pogojeva, Nuno Ratola, Julia Rigueira, Elisa Rojo-Nieto, Oksana Savenko, Rosanna I. Schoneich-Argent, Grzegorz Siedlewicz, Giuseppe Suaria, Myrto Tourgeli
NATURE SUSTAINABILITY
(2023)
Article
Environmental Sciences
Ebrahem M. M. Eid, Ahmed A. A. Hussain, Saad A. M. Alamri, Sulaiman A. A. Alrumman, Kamal H. H. Shaltout, Nasser Sewelam, Salma K. K. Shaltout, Ahmed F. F. El-Bebany, Mohamed T. T. Ahmed, Dhafer A. A. Al-Bakre, Ahmed H. H. Alfarhan, Yolanda Pico, Damia Barcelo
Summary: Predictive models were generated to assess the absorption of nine metals by the different parts of forage sorghum in growing media mixed with poultry manure. The roots exhibited the highest metal contents. Bioaccumulation factor (BAF) values were < 1 for some metals and > 1 for others. Translocation factor values were < 1 for all metals except for Co, Cr, and Ni. The predictive models showed a high level of data precision and can be used to ensure the safety of growing forage sorghum in media fortified with poultry manure.
BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY
(2023)
Article
Engineering, Environmental
Abraao Tiago Batista Guimaraes, Italo Nascimento Freitas, Nabisab Mujawar Mubarak, Md Mostafizur Rahman, Fernando Postalli Rodrigues, Aline Sueli de Lima Rodrigues, Damia Barcelo, Abu Reza Md Towfiqul Islam, Guilherme Malafaia
Summary: This study evaluated the impact of exposure to poly-styrene nanoparticles (PS NPs) on the behavior, brain antioxidant activity, and DNA damage in male Swiss mice. It was found that mice exposed to PS NPs exhibited anxiolytic-like behavior and altered defensive response when confronted with a predator. Additionally, the exposure to PS NPs led to reduced brain antioxidant activity and increased DNA damage. These findings highlight the potential impact of PS NPs on mammals and underscore the ecotoxicological risks associated with their dispersion in natural environments.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Environmental Sciences
Marius Kalinauskas, Katazyna Bogdzevic, Eduardo Gomes, Miguel Inacio, Damia Barcelo, Wenwu Zhao, Paulo Pereira
Summary: This study aims to map and assess the supply and demand of recreational culture ecosystem services (CES) in Vilnius. The results showed that natural recreational CES supply was highest in protected areas, while cultural recreational CES supply had the highest scores in the city centre. The demand for recreational CES was highest in the areas near the city centre. There was a mismatch between the supply and demand of natural recreational CES, but a match between the supply and demand of cultural recreational CES. Overall, it is important to preserve areas with high natural recreation CES supply and limit urban expansion, as well as improve public transport accessibility to reduce pollution and its impact on cultural heritage sites.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Environmental Sciences
John P. Sumpter, Tamsin J. Runnalls, Andrew C. Johnson, Damia Barcelo
Summary: It is uncommon for scientists to acknowledge the limitations of their research because of the pressure to publish. This has resulted in a crisis of reproducibility in published research. To address this, including a 'Limitations' section in scientific papers is suggested, as it promotes honesty and transparency. This recommendation applies to all scientific disciplines.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Engineering, Environmental
Yanting Zhou, Xiuna Ren, To-Hung Tsui, Damia Barcelo, Quan Wang, Zengqiang Zhang, Yongzhen Ding
Summary: Microplastics (MPs) have been widely found in aquatic, terrestrial, and atmospheric ecosystems as an emerging pollutant. Recently, it has been discovered that solid organic waste is also an important source of MPs and has significant impacts on ecosystems. This study reviews the occurrence and characteristics of MPs in solid organic waste and organic fertilizers, as well as their influence on biological treatments and degradation characteristics.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Engineering, Environmental
Bin Wang, Liping Heng, Qian Sui, Zheng Peng, Xuezhi Xiao, Minghui Zheng, Jianxin Hu, Heidelore Fiedler, Damia Barcelo, Gang Yu
Summary: This paper analyzes the combustion of vinyl chloride (VC) in the train derailment accident in Ohio, USA in 2023. It discusses the appropriateness of VC combustion in the emergency response, the concept of controlled combustion, the potential environmental risks of VC and combustion by-products, and the follow-up work. The accident has caused environmental and health risks, necessitating a comprehensive environmental risk assessment, remediation of affected areas, and proper treatment of hazardous waste. The accident also highlights the need to bridge the gap between chemical safety management and environmental risk management.
FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING
(2023)
Editorial Material
Engineering, Environmental
Manish Kumar, Rahul Silori, Payal Mazumder, Vikalp Shrivastava, Frank Loge, Damia Barcelo, Jurgen Mahlknecht
ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS
(2023)
Review
Biodiversity Conservation
Raffaele Bruschi, Paolo Pastorino, Damia Barceld, Monia Renzi
Summary: Lagoons play a crucial role in ecological services, providing habitats and filtering water quality. However, there is a lack of data on microplastic pollution in Italian lagoon systems, highlighting the need for monitoring and assessment.
ECOLOGICAL INDICATORS
(2023)
Article
Environmental Sciences
Zhen Wang, Yanhong Li, Yuting Tan, Rui Li, Liangliang Zhou, Zongzhe He, Damia Barcelo, Haiyan Shi, Minghua Wang
Summary: In this study, the uptake, translocation, and biotransformation of the fungicide PYD by wheat were investigated at a chiral level. The results showed that the residue concentration of R-PYD in wheat was higher than that of S-PYD, and R-PYD was more easily accumulating in roots and translocating to shoots. Additionally, 9 metabolites of PYD were detected qualitatively in wheat roots or shoots.
ENVIRONMENT INTERNATIONAL
(2023)
Article
Environmental Sciences
Rahul Silori, Manish Kumar, Durga Madhab Mahapatra, Pinakshi Biswas, Bhanu Prakash Vellanki, Jurgen Mahlknecht, Syed Mohammad Tauseef, Damia Barcelo
Summary: This study investigates the occurrences and seasonal variations of endocrine disrupting chemicals (EDCs) in wastewater treatment plants (WWTPs) in Dehradun, India. The results show higher concentrations of estrone compared to triclosan in the influent waters of the WWTPs. The study highlights the limitation of WWTPs in treating and assimilating EDCs, leading to their accumulation in effluents and posing a significant threat to nearby aquatic ecosystems, human health, and the ecological balance of the region.
ENVIRONMENTAL RESEARCH
(2023)
Article
Environmental Sciences
J. M. Castano-Ortiza, R. Gil-Solsonaa, N. Ospina-Alvarez, M. M. Garcia-Pimentel, V. M. Leon, L. H. M. L. M. Santos, D. Barcelo, S. Rodriguez-Mozaz
Summary: This study investigated the seasonal occurrence of pharmaceutical residues in the Mar Menor coastal lagoon in south-eastern Spain during 2018-2019. The results showed a decrease in pharmaceutical residues in seawater and sediments compared to a previous study in 2010-2011, but a notable accumulation in fish and molluscs. The flash flood event in 2019 led to increased concentrations of pharmaceutical residues in the lagoon. Therefore, the impacts of extreme climate events, such as floods, should be considered when assessing the risks of pharmaceutical contaminants in coastal ecosystems.
ENVIRONMENTAL RESEARCH
(2023)
Review
Environmental Sciences
Saul Antonio Hernandez Martinez, Elda M. Melchor-Martinez, Reyna Berenice Gonzalez-Gonzalez, Juan Eduardo Sosa-Hernandez, Rafael G. Araujo, Jesus Alfredo Rodriguez-Hernandez, Damia Barcelo, Roberto Parra-Saldivar, Hafiz M. N. Iqbal
Summary: The COVID-19 pandemic has led to an increase in the use of psychiatric drugs, which are difficult to degrade and pose potential ecological and toxicological risks. Biocatalysis-assisted techniques can efficiently remove these drugs from water. There are differences in waste management policies for the drug industry between high- and low-income countries.
ENVIRONMENTAL RESEARCH
(2023)
Article
Engineering, Environmental
J. M. Castano-Ortiz, F. Courant, E. Gomez, M. M. Garcia-Pimentel, V. M. Leon, J. A. Campillo, L. H. M. L. M. Santos, D. Barcelo, S. Rodriguez-Mozaz
Summary: In this study, the bioaccumulation, metabolomic alterations, and potential recovery mechanisms of Mediterranean mussels exposed to polyethylene microplastics and pharmaceuticals were investigated. The presence of microplastics delayed the bioaccumulation of citalopram but had a limited effect on bezafibrate accumulation. Pharmaceuticals and microplastics both affected metabolic pathways in mussels, potentially leading to dysregulation of reproduction, energy metabolism, and immunity.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Biochemistry & Molecular Biology
Helena Rapp-Wright, Sara Rodriguez-Mozaz, Diana Alvarez-Munoz, Damia Barcelo, Fiona Regan, Leon P. Barron, Blanaid White
Summary: This study monitored a total of 26 endocrine-disrupting compounds (EDCs) in three major urbanized river catchments using a single analytical method. Results showed that the highest concentration of the flame retardant TCEP was found in the R. Thames in Central London. Geographical variations and potential risks were observed, and caffeine and BPA were identified as high-risk compounds in all three rivers. The study highlights the importance of prioritizing control measures for these compounds independently of location.