4.7 Article

Catechol determination in compost bioremediation using a laccase sensor and artificial neural networks

期刊

ANALYTICAL AND BIOANALYTICAL CHEMISTRY
卷 391, 期 2, 页码 679-685

出版社

SPRINGER HEIDELBERG
DOI: 10.1007/s00216-008-2049-1

关键词

catechol; compost bioremediation; laccase sensor; artificial neural networks; electrochemical determination

向作者/读者索取更多资源

An electrochemical biosensor based on the immobilization of laccase on magnetic core-shell ( Fe3O4-SiO2) nanoparticles was combined with artificial neural networks ( ANNs) for the determination of catechol concentration in compost bioremediation of municipal solid waste. The immobilization matrix provided a good microenvironment for retaining laccase bioactivity, and the combination with ANNs offered a good chemometric tool for data analysis in respect to the dynamic, nonlinear, and uncertain characteristics of the complex composting system. Catechol concentrations in compost samples were determined by using both the laccase sensor and HPLC for calibration. The detection range varied from 7.5 x 10(-7) to 4.4 x 10(-4) M, and the amperometric response current reached 95% of the steady-state current within about 70 s. The performance of the ANN model was compared with the linear regression model in respect to simulation accuracy, adaptability to uncertainty, etc. All the results showed that the combination of amperometric enzyme sensor and artificial neural networks

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Optics

Realizing the Switching of Optoelectronic Memory and Ultrafast Detector in Functionalized-Black Phosphorus/MoS2 Heterojunction

Chang Liu, Shuimei Ding, Qianlei Tian, Xitong Hong, Wanhan Su, Lin Tang, Liming Wang, Mingliang Zhang, Xingqiang Liu, Yawei Lv, Johnny C. Ho, Lei Liao, Xuming Zou

Summary: This study proposes a new device that combines optoelectronic memory and a detector, allowing for switchable functions. The device has long storage time, high on/off ratio, and excellent multi-bit storage in the memory mode. In the detector mode, it exhibits fast response, impressive responsivity, and self-driven broadband detection. Additionally, the device has the ability to quickly resolve polarization in the near-infrared range.

LASER & PHOTONICS REVIEWS (2023)

Review Engineering, Environmental

Bacteria inactivation by sulfate radical: progress and non-negligible disinfection by-products

Xin Zhou, Xiaoya Ren, Yu Chen, Haopeng Feng, Jiangfang Yu, Kang Peng, Yuying Zhang, Wenhao Chen, Jing Tang, Jiajia Wang, Lin Tang

Summary: Sulfate radicals have been increasingly used for water disinfection due to their strong redox ability and high selectivity. However, there is a lack of reviews on sulfate radicals inactivating pathogenic microorganisms, and less attention has been paid to disinfection by-products. This paper provides an overview of sulfate radicals' properties, summarizes the progress in water disinfection, and discusses the disinfection by-products. Specific solutions and future research directions are also proposed.

FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING (2023)

Article Engineering, Environmental

Thin-walled vesicular Triazole-CN-PDI with electronic n?p* excitation and directional movement for enhanced atrazine photodegradation

Rongdi Tang, Hao Zeng, Daoxin Gong, Yaocheng Deng, Sheng Xiong, Ling Li, Zhanpeng Zhou, Jiajia Wang, Chengyang Feng, Lin Tang

Summary: In this study, triazole and pyromellitic diimide were used to modify polymeric carbon nitride (PCN) and fabricate TA-CN-PDI, a catalyst that promotes the photodegradation of atrazine. The vesicular morphology and the donor-pi-acceptor electronic structure synergistically enhance the photoactivity of the catalyst.

CHEMICAL ENGINEERING JOURNAL (2023)

Review Engineering, Environmental

Disinfection byproducts formation from emerging organic micropollutants during chlorine-based disinfection processes

Binbin Shao, Leyuan Shen, Zhifeng Liu, Lin Tang, Xiaofei Tan, Dongbo Wang, Weimin Zeng, Ting Wu, Yuan Pan, Xiansheng Zhang, Lin Ge, Miao He

Summary: This review discusses the formation of disinfection byproducts (DBPs) from emerging organic micropollutants (EOMPs) during chlorine-based disinfection processes (Cl-DPs). The typical Cl-DPs and their mechanisms are introduced, and the formation pathways, mechanisms, and influencing factors of DBPs in the presence of different EOMPs are discussed. The review also summarizes and discusses the detection and control methods of DBPs, and proposes future research directions and challenges in controlling their formation during disinfection processes.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Environmental

Adjusting charge kinetics of conjugated polymers via integration of LSPR effect with homojunction

Mingjuan Zhang, Lin Tang, Abing Duan, Yi Zhang, Fengjiao Xiao, Yuan Zhu, Jiajia Wang, Chengyang Feng, Nian Yin

Summary: This study investigates the adjustment of charge kinetics in semiconductors using the integration of LSPR effect with homojunction. A novel composite material is designed for this purpose. The results indicate the potential application value of this approach in adjusting charge kinetics and enhance the understanding of thermodynamic reactions.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Environmental

An S-scheme CdS/K2Ta2O6 heterojunction photocatalyst for production of H2O2 from water and air

Cui Lai, Mengyi Xu, Fuhang Xu, Bisheng Li, Dengsheng Ma, Yixia Li, Ling Li, Mingming Zhang, Danlian Huang, Lin Tang, Shiyu Liu, Huchuan Yan, Xuerong Zhou, Yukui Fu, Huan Yi

Summary: The production of hydrogen peroxide using solar energy is important for the chemical industry and environmental remediation. Researchers have successfully designed an S-scheme heterojunction photocatalyst with promoted charge separation and migration, achieving outstanding hydrogen peroxide production rate without sacrificial agents and additional oxygen. Experimental and theoretical studies suggest that the S-scheme heterojunction between CdS and KTO plays a crucial role in efficiently separating photogenerated electron-hole pairs, providing insights for the charge transfer mechanism and offering an innovative strategy for green, energy-saving, and sustainable hydrogen peroxide production.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Environmental Sciences

Advancing charge carriers separation and transformation by nitrogen self-doped hollow nanotubes g-C3N4 for enhancing photocatalytic degradation of organic pollutants

Xinlan Zhen, Changzheng Fan, Lin Tang, Jun Luo, Linrui Zhong, Yuying Gao, Mingjuan Zhang, Jangfu Zheng

Summary: A nitrogen self-doped hollow nanotubes g-C3N4 (N-PCN) was synthesized and exhibited excellent efficiency in the photocatalytic degradation of TC by reducing oxygen to superoxide radicals. The N-PCN also suppressed the recombination of photogenerated charge carriers and facilitated the adsorption of oxygen molecules, resulting in the generation of more superoxide radicals and singlet oxygen through the oxygen activation process.

CHEMOSPHERE (2023)

Article Nanoscience & Nanotechnology

Thin-Film Nanocomposite Membranes with Nature-Inspired MOFs Incorporated for Removing Fluoroquinolone Antibiotics

Si-Yuan Fang, Ji-Lai Gong, Lin Tang, Juan Li, Meng Qin, Huai-Yang Zhou, Liang-Xiu Tang, Jun Zhao

Summary: Researchers have developed a nanofiltration membrane functionalized with metal-organic frameworks (MOFs) to enhance micropollutant removal and wastewater reclamation. The nature-inspired MOF-based thin-film nanocomposite (TFN-CU) membrane showed high water permeance, exceptional rejection for antibiotics, and excellent long-term stability. It also demonstrated superior antifouling capability in protein filtration after fouling cycles. These findings provide valuable insights for the design of antifouling membranes in antibiotic wastewater reclamation.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Chemistry, Multidisciplinary

Ultrahigh Performance H2O2 Generation by Single-Atom Fe Catalysts with N/O Bidentate Ligand via Oxalic Acid and Oxygen Molecules Activation

Mingming Zhang, Cui Lai, Fuhang Xu, Danlian Huang, Tianjue Hu, Bisheng Li, Dengsheng Ma, Shiyu Liu, Yukui Fu, Ling Li, Lin Tang, Liang Chen

Summary: In this study, single Fe atoms were successfully immobilized on Fe-SA/CN, which exhibited high efficiency in generating hydrogen peroxide (H2O2) through oxalic acid and O2 activation. Under visible light, the H2O2 concentration generated by Fe-SA/CN reached 40.19 mM g(-1) h(-1), which was 10.44 times higher than that of g-C3N4. This enhancement can be attributed to the formation of metal-organic complexes and rapid electron transfer. Furthermore, the O2 activation capacity of Fe-SA/CN was found to be higher than that of g-C3N4, facilitating H2O2 formation. Density functional theory calculations revealed that O2 was chemically adsorbed on Fe atomic sites, promoting O2 adsorption and activation. The photocatalytic mechanism of SACs-catalyzed H2O2 generation was also elucidated, providing a deeper understanding of this process.
Article Chemistry, Multidisciplinary

Twisty C-TiO2/PCN S-Scheme Heterojunction with Enhanced n?p* Electronic Excitation for Promoted Piezo-Photocatalytic Effect

Rongdi Tang, Hao Zeng, Chengyang Feng, Sheng Xiong, Ling Li, Zhanpeng Zhou, Daoxin Gong, Lin Tang, Yaocheng Deng

Summary: In this study, a twisty C-TiO2/PCN (CNT) S-scheme heterojunction was fabricated and utilized for the degradation of ciprofloxacin (CIP) through ultrasonic vibration and visible light irradiation. The nitrogen-rich twisty polymeric carbon nitride (PCN) not only induced a non-centrosymmetric structure with enhanced polarity for better piezoelectric effect, but also provided abundant lone pair electrons for promoting n -> pi * transition during photocatalysis. The hybridization with C-TiO2 particles enabled the construction of S-scheme heterojunction in CNT. Under the synergistic effect of ultrasonic vibration and visible light irradiation, the reaction rate constant of CIP degradation by CNT was significantly increased, demonstrating its potential as an efficient and stable approach for environmental remediation.
Article Engineering, Environmental

Synergistic effect of intercalation and EDLC electrosorption of 2D/3D interconnected architectures to boost capacitive deionization for water desalination via MoSe2/mesoporous carbon hollow spheres

Jiaxin Du, Wenle Xing, Jiaqi Yu, Jing Feng, Lin Tang, Wangwang Tang

Summary: This study explores the application of two-dimensional molybdenum disulfide in hybrid capacitive deionization and successfully synthesizes a MoSe2/MCHS composite material. The composite material exhibits unique 2D/3D interconnected architectures and shows excellent salt adsorption and desalination performance. The research demonstrates the potential application of selenides in CDI and provides new insights for the rational design of high-performance composite electrode materials.

WATER RESEARCH (2023)

Article Environmental Sciences

Simultaneous Recovery of NH3-N and Removal of Heavy Metals from Manganese Residue Leachate Using an Electrodialysis System

Yuyang Yi, Haopeng Feng, Jiajia Wang, Jing Tang, Yangfeng Wu, Xiangmin Liang, Yuyao Guo, Lin Tang

Summary: In this study, a novel electrodialysis system with a self-growing titanium dioxide nanowire (TiO2 NW) electrode is proposed to recover NH3-N and remove heavy metals from manganese residue leachate (MRL), which can seriously affect the environment. Plant growth experiments and ecotoxicity studies are conducted to evaluate the ecological risks of the reuse of recovered NH3-N. The results show that the electrodialysis system can achieve high removal rates of heavy metals and recovery of NH3-N from MRL, and the recovered NH3-N can promote plant growth and optimize soil fertility.

ACS ES&T WATER (2023)

Article Environmental Sciences

Porous Fe/CeO2 Nanozyme-Based Hydrogel Colorimetric Platform for on-Site Detection of Kanamycin

Li Chen, Xu Zhu, Jing Tang, Xilian Ouyang, Yibo Liao, Yating Lu, Jiajia Wang, Zimin Wei, Beidou Xi, Lin Tang

Summary: A portable and sensitive hydrogel-based colorimetric sensor was developed for on-site detection of antibiotic residues. It plays a crucial role in protecting the ecosystem and human health by designing a portable and sensitive sensor for on-site analysis.

ACS ES&T WATER (2023)

Article Chemistry, Physical

Dual modulation on peroxymonosulfate activation site and photocarrier separation in carbon nitride for efficient photocatalytic organics degradation: Efficacy and mechanism evaluation

Rongdi Tang, Hao Zeng, Yaocheng Deng, Sheng Xiong, Ling Li, Zhanpeng Zhou, Jiajia Wang, Lin Tang

Summary: In this study, sulfur and sodium co-doped cyano-rich polymeric carbon nitride (NaCNS) was designed to enhance the photocatalytic degradation of atrazine (ATZ) with peroxymonosulfate (PMS) assistance. NaCNS was synthesized through a two-step thermal condensation method with the presence of sodium chloride and cysteine. Batch experiments showed that the reaction rate constant of NaCNS was significantly increased by nearly sixfold compared to pristine carbon nitride. The enhanced photocatalytic performance was attributed to the dual modulation of NaCNS, with sodium acting as a PMS activation site and the cyano and sulfur forming an electronic push-pull system for improved photocarrier separation.

APPLIED CATALYSIS B-ENVIRONMENTAL (2023)

Article Environmental Sciences

Effects of Heterogeneous Metals on the Generation of Persistent Free Radicals as Critical Redox Sites in Iron-Containing Biochar for Persulfate Activation

Cheng Huang, Fanzhi Qin, Chen Zhang, Danlian Huang, Lin Tang, Biao Song, Ming Yan, Wenjun Wang, Deyu Qin, Yin Zhou, Hanzhuo Luo, Guoge Fang

Summary: Metal components have significant impacts on the generation of persistent free radicals (PFRs) in biochar. This study investigates the effect of interactions among metal components on the formation of PFRs during biomass pyrolysis. The results show that the coupling of Fe with Co and Ni increases the abundance of PFRs in iron-containing biochars (IBCs), while Zn inhibits PFRs generation. Persulfate activation experiments confirm that PFRs are critical redox sites. NiFeO/BC is identified as a more efficient catalyst for PFRs activation. This study provides new methods for regulating PFRs in biochar and advances the understanding of metal-containing biomass pyrolysis processes.

ACS ES&T WATER (2023)

暂无数据